公开(公告)号：US09704612B2

公开(公告)日：2017-07-11

申请号：US14005099

申请日：2012-03-15

Applicant: Takayuki Iijima ,  Hideyuki Higashimura

Inventor： Takayuki Iijima ,  Hideyuki Higashimura

IPC: H01B1/00 ,  H01B1/12 ,  B22F1/00 ,  B22F1/02 ,  C22C5/06 ,  H01B1/22 ,  C08K3/08 ,  H01B1/02 ,  H01L51/00 ,  H01L51/50

CPC classification number: H01B1/121 ,  B22F1/0003 ,  B22F1/02 ,  C08G2261/91 ,  C08G2261/95 ,  C08K3/08 ,  C22C5/06 ,  H01B1/02 ,  H01B1/22 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/5076 ,  C08K5/098 ,  C08L65/00

Abstract: A composition of a silver-conjugated compound composite containing (1) a silver-conjugated compound composite containing a silver particle with a Feret diameter of 1,000 nm or less and a conjugated compound having a weight average molecular weight of 3.0×102 or more being adsorbed to the silver particles and (2) an ionic compound. The ionic compound may be a compound having a structure represented by the following Formula (hh-1): [Chem. 1] Mm′+aX′n′−b  (hh-1) wherein Mm′+ represents a metal cation, X′n′− represents an anion, a and b each independently represent an integer of 1 or more, and when Mm′+ and X′n′− are each plurally present, they may be the same as or different from each other.

公开(公告)号：US09184388B2

公开(公告)日：2015-11-10

申请号：US13812678

申请日：2011-07-29

Applicant: Arihiro Yashiro ,  Hideyuki Higashimura ,  Rui Ishikawa ,  Masanobu Tanaka

Inventor： Arihiro Yashiro ,  Hideyuki Higashimura ,  Rui Ishikawa ,  Masanobu Tanaka

IPC: H01L51/50 ,  H01L51/00 ,  C07C211/56 ,  C07C211/63 ,  C07F9/54 ,  C07F9/572 ,  C08G61/12 ,  C07D209/86 ,  C07F5/02

CPC classification number: H01L51/0035 ,  C07C211/56 ,  C07C211/63 ,  C07D209/86 ,  C07F5/025 ,  C07F9/5407 ,  C07F9/5442 ,  C07F9/5456 ,  C07F9/5728 ,  C08G61/12 ,  C08G2261/1424 ,  C08G2261/312 ,  C08G2261/3162 ,  C08G2261/411 ,  C08G2261/512 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/5056 ,  Y02E10/549 ,  Y02P70/521

Abstract: The present invention provides: a layered structure having a substrate and a hole injection and/or hole transport layer comprising an aromatic compound having, on a side chain, at least one type of group having a cationic center; an electronic device having the layered structure; an aromatic compound having, on a hydrocarbon side chain, at least one type of group having a cationic center; an aromatic compound having a leaving group on a hydrocarbon side chain; and a method for manufacturing the aromatic compound having, on a hydrocarbon side chain, at least one type of group having a cationic center, the method comprising reacting the aromatic compound having a leaving group on a hydrocarbon side chain with a specific nitrogen compound, phosphorus compound, sulfur compound, or a combination of two or more of these compounds, thereby converting the aromatic compound into an onium salt thereof. When used as an electronic device material, and particularly as a hole transport and/or hole injection material, the aromatic compound can achieve a higher current density at a given voltage.

Abstract translation: 本发明提供：具有基材和空穴注入和/或空穴传输层的层状结构，所述空穴注入和/或空穴传输层包含芳族化合物，所述芳族化合物在侧链上具有至少一种具有阳离子中心的基团; 具有层状结构的电子设备; 在烃侧链上具有至少一种具有阳离子中心的基团的芳族化合物; 在烃侧链上具有离去基团的芳族化合物; 以及在烃侧链具有至少一种具有阳离子中心的基团的芳香族化合物的制造方法，其特征在于，使烃侧链上具有离去基团的芳香族化合物与特定的氮化合物反应， 化合物，硫化合物或两种或更多种这些化合物的组合，从而将芳族化合物转化成其鎓盐。 当用作电子器件材料，特别是用作空穴传输和/或空穴注入材料时，芳族化合物可以在给定电压下实现更高的电流密度。

公开(公告)号：US08951646B2

公开(公告)日：2015-02-10

申请号：US12921108

申请日：2009-03-05

Applicant: Masanobu Tanaka ,  Kenta Tanaka ,  Shohgo Yamauchi ,  Hideyuki Higashimura

Inventor： Masanobu Tanaka ,  Kenta Tanaka ,  Shohgo Yamauchi ,  Hideyuki Higashimura

IPC: H01L51/54 ,  C09K11/06 ,  C08G63/00 ,  H01L51/00 ,  C08G61/02 ,  C08G61/12 ,  H01L51/50

CPC classification number: H01L51/0039 ,  C08G61/02 ,  C08G61/12 ,  C08G61/122 ,  C08G2261/124 ,  C08G2261/1426 ,  C08G2261/3142 ,  C08G2261/316 ,  C08G2261/3221 ,  C08G2261/5222 ,  C08G2261/80 ,  H01L51/5048 ,  Y02E10/549 ,  Y10S428/917

Abstract: A layered structure including a first electrode and a second electrode, a light-emitting layer or a charge separation layer between the first electrode and the second electrode, and a layer containing a conjugated polymer compound between the light-emitting layer or the charge separation layer and the first electrode, wherein the conjugated polymer compound contains a repeating unit selected from the group consisting of a repeating unit of formula (1).

Abstract translation: 包括第一电极和第二电极的层状结构，在第一电极和第二电极之间的发光层或电荷分离层，以及在发光层或电荷分离层之间含有共轭高分子化合物的层 和第一电极，其中共轭高分子化合物含有选自式（1）的重复单元的重复单元。

公开(公告)号：US20130099224A1

公开(公告)日：2013-04-25

申请号：US13807226

申请日：2011-06-24

Applicant: Takayuki Iljima ,  Kenta Tanaka ,  Masanobu Tanaka ,  Hideyuki Higashimura

Inventor： Takayuki Iljima ,  Kenta Tanaka ,  Masanobu Tanaka ,  Hideyuki Higashimura

IPC: H01L51/50 ,  H01L51/00 ,  H01L51/42

CPC classification number: H01L51/5012 ,  C07D471/04 ,  C08G61/02 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/149 ,  C08G2261/3142 ,  C08G2261/411 ,  C08G2261/412 ,  C08G2261/95 ,  H01L51/0002 ,  H01L51/0003 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/42 ,  H01L51/424 ,  H01L51/4253 ,  H01L51/5076 ,  H01L51/5092 ,  H05B33/22 ,  Y02E10/549 ,  Y02P70/521

Abstract: Provided are a light-emitting device and a photovoltaic cell having excellent characteristics. A light-emitting device (10) includes a cathode (34), an anode (32), a light-emitting layer (50) interposed between the cathode (34) and the anode (32), and an electron injection layer (44) provided between the cathode (34) and the light-emitting layer (50) and connected to the cathode (34), in which at least one of the anode (32) and the cathode (34) contains a conductive material having an aspect ratio of 1.5 or more, and the electron injection layer (44) contains an organic compound having at least one of an ionic group and a polar group.

Abstract translation: 提供了具有优异特性的发光器件和光伏电池。 发光装置（10）包括阴极（34），阳极（32），介于阴极（34）和阳极（32）之间的发光层（50）和电子注入层（44） ）设置在阴极（34）和发光层（50）之间并连接到阴极（34），其中阳极（32）和阴极（34）中的至少一个包含具有一方面的导电材料 比例为1.5以上，电子注入层（44）含有具有离子性基团和极性基团中的至少一种的有机化合物。

公开(公告)号：US20120168693A1

公开(公告)日：2012-07-05

申请号：US13496611

申请日：2010-09-17

Applicant: Takayuki Iijima ,  Masahiro Fujioka ,  Hideyuki Higashimura

Inventor： Takayuki Iijima ,  Masahiro Fujioka ,  Hideyuki Higashimura

IPC: H01B1/02 ,  C08G79/00 ,  C08G73/06

CPC classification number: H01B1/22 ,  B22F1/00 ,  B22F1/0062 ,  B22F1/02 ,  B22F9/00 ,  B22F9/24 ,  B22F2001/0092 ,  B82Y30/00 ,  C08G73/06 ,  C08G79/00 ,  C08G2261/1424 ,  C08G2261/1432 ,  C08G2261/148 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08G2261/514 ,  C08G2261/95 ,  C08K3/08 ,  C08L65/00 ,  H01B1/00

Abstract: A silver-(conjugated compound) composite comprising silver particles having a number-average Feret diameter of not more than 1,000 nm, and a conjugated compound having a weight-average molecular weight of not less than 3.0×102 adsorbed to the silver particles. The composite exhibits excellent conductivity and charge injection properties, and excellent dispersibility within non-polar solvents.

Abstract translation: 包含平均Feret直径不大于1000nm的银颗粒的银 - （共轭化合物）复合物和吸附在银颗粒上的重均分子量不小于3.0×102的共轭化合物。 该复合材料具有优异的导电性和电荷注入性能，并且在非极性溶剂中具有优异的分散性。

公开(公告)号：US20120032121A1

公开(公告)日：2012-02-09

申请号：US13263220

申请日：2010-04-06

Applicant: Hideyuki Higashimura ,  Takayuki Iijima ,  Masahiro Fujioka ,  Kenta Tanaka

Inventor： Hideyuki Higashimura ,  Takayuki Iijima ,  Masahiro Fujioka ,  Kenta Tanaka

IPC: H01B1/22 ,  C07D471/04 ,  H05B33/26 ,  H01J40/04 ,  B82Y30/00

CPC classification number: H01B1/128 ,  B22F1/00 ,  B22F1/0025 ,  B22F1/0062 ,  B22F1/02 ,  B22F9/00 ,  B22F9/24 ,  B22F2999/00 ,  B82B1/00 ,  B82Y30/00 ,  C07F5/025 ,  C08G61/02 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/143 ,  C08G2261/145 ,  C08G2261/149 ,  C08G2261/3142 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/95 ,  C08G2261/964 ,  C08K3/08 ,  C08K2201/016 ,  C08L65/00 ,  C09D5/24 ,  H01L21/28 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/009 ,  H05B33/28 ,  Y02E10/549 ,  Y02P70/521 ,  B22F2301/255

Abstract: A metallic composite in which a conjugated compound having a molecular weight of 200 or more is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, for example, a metallic composite in which a compound having a group represented by the formula (I) or a repeating unit represented by the formula (II) or both of them is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, is useful for electronic devices such as a light-emitting device, a solar cell and an organic transistor.

Abstract translation: 将分子量为200以上的共轭化合物吸附在纵横比为1.5以上的金属纳米结构体的金属复合体中，例如具有式（I）所示基团的化合物 ）或由式（II）表示的重复单元或它们两者都被吸收到纵横比为1.5以上的金属纳米结构体上，可用于发光元件，太阳能电池和有机物等电子器件 晶体管。

公开(公告)号：US08048982B2

公开(公告)日：2011-11-01

申请号：US11571280

申请日：2005-06-24

Applicant: Hideyuki Higashimura ,  Daisuke Fukushima ,  Kazuei Ohuchi

Inventor： Hideyuki Higashimura ,  Daisuke Fukushima ,  Kazuei Ohuchi

IPC: C08G65/00 ,  C08G65/34 ,  C07F9/00

CPC classification number: C08G61/12 ,  C07C49/92 ,  C07F9/005 ,  C08G61/02 ,  C08G61/10

Abstract: A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P=Af/Ai  (A) and Eo=(Epa+Epc)/2 [V]  (B).

Abstract translation: 一种芳族化合物聚合物的制造方法，其特征在于，在氧化剂的存在下，使直接与芳香环连接的2个以上的氢原子的一种以上的芳香族化合物氧化聚合， 的过渡金属络合物或由过渡金属络合物和活化剂制备的催化剂，所述催化剂具有下式（A）定义的参数P为0.50以上，以及由下式（B ）为0.50 [V]以上：P = Af / Ai（A），Eo =（Epa + Epc）/ 2 [V]（B）。

公开(公告)号：US07718757B2

公开(公告)日：2010-05-18

申请号：US11920168

申请日：2006-05-08

Applicant: Shigeki Habaue ,  Soichiro Murakami ,  Hideyuki Higashimura

Inventor： Shigeki Habaue ,  Soichiro Murakami ,  Hideyuki Higashimura

IPC: C08G65/38 ,  C08G63/00

CPC classification number: C08G61/10

Abstract: An aromatic polymer, containing a repeating unit represented by Formula (I), and having properties (A1) and (B1): (A1) the number average degree of polymerization of an acetylated product obtained by acetylation of the hydroxyl groups of the polymer is 3 or more, and (B1) at a wavelength where an absolute value of molar ellipticity (degree·cm−2·dmol−1) per mole of the repeating unit of the acetylated product in a circular dichroism spectrum of the acetylated product reaches maximum in a wavelength range of from 200 to 350 nm, the absolute value is 50,000 or more: wherein R represents a hydrocarbon, hydrocarbon-oxy, hydrocarbon-mercapto or hydrocarbon-amino group that may be substituted; the two R's may bind to each other to form a ring; and the repeating unit represented by Formula (I) has no symmetrical plane that has two binding sites and that is perpendicular for the benzene ring.

Abstract translation: 含有由式（I）表示的重复单元，具有（A1）和（B1）性质的芳族聚合物：（A1）通过聚合物的羟基乙酰化得到的乙酰化产物的数均聚合度为 3以上，并且在乙酰化产物的圆二色谱中每摩尔乙酰化产物的重复单元的绝对摩尔数椭圆率（度·cm-2·dmol-1）的波长的（B1）达到最大 在200〜350nm的波长范围内，绝对值为50,000以上：其中R表示可被取代的烃，烃 - 氧，烃 - 巯基或烃 - 氨基; 两个R可以彼此结合形成环; 并且由式（I）表示的重复单元没有对称平面，其具有两个结合位点，并且与苯环垂直。

公开(公告)号：US20090318681A1

公开(公告)日：2009-12-24

申请号：US12518396

申请日：2007-12-11

Applicant: Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

Inventor： Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

IPC: C07D257/10 ,  C07D487/18

CPC classification number: C07F13/005 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/2213 ,  B01J2531/0252 ,  B01J2531/845 ,  C07C251/24 ,  C07C2601/14 ,  C07D257/10 ,  C07F15/065

Abstract: Provided is a metal complex represented by the following formula (A-1) or (B-1) as a metal complex useful for a redox reaction catalyst or some other article that is excellent in heat resistance and acid resistance:

Abstract translation: 提供作为可用于氧化还原反应催化剂的金属络合物或其耐热性和耐酸性优异的其它制品的由下式（A-1）或（B-1）表示的金属络合物：

公开(公告)号：US20090306368A1

公开(公告)日：2009-12-10

申请号：US12515669

申请日：2007-11-26

Applicant: Hiroyasu Sugiyama ,  Hideyuki Higashimura ,  Nobuhiko Akino

Inventor： Hiroyasu Sugiyama ,  Hideyuki Higashimura ,  Nobuhiko Akino

IPC: C07D225/00

CPC classification number: C07F9/5045 ,  C07D471/22 ,  H01L51/009 ,  H01L51/0091 ,  H01L51/5012

Abstract: A polynuclear complex having two or more metal atoms and/or metal ions per one ligand of the general formula (I): (wherein, Q1 and Q2 represent each independently a divalent heterocyclic group optionally having a substituent. R1 and R2 represent each independently a direct bond or divalent hydrocarbon group, X represents a nitrogen atom or phosphorus atom, and R3 represents a monovalent organic group containing an atom selected from a nitrogen atom, oxygen atom, phosphorus atom and sulfur atom, or a hydrogen atom or hydrocarbon group

Abstract translation: 具有通式（I）的每个配体具有两个以上金属原子和/或金属离子的多核配合物：（其中，Q1和Q2各自独立地表示任选具有取代基的二价杂环基，R 1和R 2各自独立地表示 直接键或二价烃基，X表示氮原子或磷原子，R 3表示含有选自氮原子，氧原子，磷原子和硫原子的原子的一价有机基团，或氢原子或烃基