PZT thin films for ferroelectric capacitor and method for preparing the
same
    13.
    发明授权
    PZT thin films for ferroelectric capacitor and method for preparing the same 失效
    用于铁电电容器的PZT薄膜及其制备方法

    公开(公告)号:US5625529A

    公开(公告)日:1997-04-29

    申请号:US412043

    申请日:1995-03-28

    Abstract: PZT ferroelectric thin films for capacitors comprise a combination of a donor dopant and an acceptor dopant in a total amount of about 0.1 to 8 mole percent of PZT, or Sc alone in an amount of about 0.1 to 5 mole percent. Nb or Ta is employed as a donor dopant, while Sc, Mg or Zn can be used as an acceptor dopant. The presence of a single Sc acceptor dopant, or both an acceptor dopant and a donor dopant, results in increased endurance. Fatigue cycles are increased on the order of about 10.sup.5 relative to dopant-free films. Doping with a single Sc acceptor dopant, or both an acceptor dopant and a donor dopant, reduces coercive field, allowing PZT films to switch at relatively low voltages. PZT thin films of a pure perovskite phase are obtained in which a pyrochlore phase is completely excluded. Pt may be used as an electrode material. The leakage current of PZT films doped with both the acceptor and donor elements are similar to the leakage current level of pure PZT thin films.

    Abstract translation: 用于电容器的PZT铁电薄膜包括总量为约0.1至8摩尔%的PZT或Sc单独的施主掺杂剂和受主掺杂剂的组合,其量为约0.1至5摩尔%。 Nb或Ta用作施主掺杂剂,而Sc,Mg或Zn可用作受主掺杂剂。 单个Sc受体掺杂剂或受体掺杂剂和施主掺杂剂两者的存在导致耐久性增加。 相对于不含掺杂剂的膜,疲劳循环增加约为约105。 用单个Sc受体掺杂剂或受体掺杂剂和施主掺杂剂掺杂减少矫顽场,允许PZT膜在相对低的电压下切换。 获得纯钙钛矿相的PZT薄膜,其中完全排除了烧绿石相。 Pt可以用作电极材料。 掺杂受体和施主元素的PZT膜的漏电流类似于纯PZT薄膜的漏电流水平。

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