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11.
公开(公告)号:US20250002443A1
公开(公告)日:2025-01-02
申请号:US18698872
申请日:2022-10-05
Applicant: Rohm and Haas Company
Inventor: Kirk W. Limbach
Abstract: A process for producing methyl methacrylate by oxidative esterification is disclosed. The process comprises reacting methanol and methacrolein in a reactor system comprising an oxygen-containing gas and a heterogeneous noble metal-containing catalyst to produce methyl methacrylate. No Arrhenius base is added to the reactor system.
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公开(公告)号:US20240425630A1
公开(公告)日:2024-12-26
申请号:US18700855
申请日:2022-11-22
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Joseph B. Binder , Isabelle Uhl , Steve Pham , Vesna Daniloska
IPC: C08F220/18 , C08F2/26 , C08K5/25 , C09J5/04 , C09J133/24
Abstract: A waterborne precursor polymer dispersion composition comprising the reaction product obtained by free-radical emulsion polymerization of a monomer mixture comprising: (A) at least one alkyl (meth)acrylate; and (B) at least one ethylenically unsaturated compound comprising: (Bi) at least one first functional group; wherein the at least one first functional group comprises at least one ethylenically unsaturated group; and (Bii) at least one second functional group; wherein the at least one second functional group comprises at least one functional group different than the ethylenically unsaturated group; wherein the second functional group is capable of reacting with a crosslinker component; and wherein the crosslinker component is not reactive with component (A) in free-radical polymerization; in the presence of: (C) an aqueous medium; and (D) at least one acid surfactant salt with pKaH from 2.6 to 7; a waterborne contact adhesive polymer dispersion composition including a mixture of: (I) the above waterborne precursor polymer dispersion composition and (II) a crosslinker compound for crosslinking with the at least one second functional group, component (Bii); a bonded article including at least two substrates adhered together with the above waterborne contact adhesive polymer dispersion composition; a process for preparing the above waterborne precursor polymer dispersion composition; a process for preparing the above waterborne contact adhesive composition; and a process of bonding two substrates together using the above waterborne contact adhesive composition to form a bonded article.
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公开(公告)号:US20240400844A1
公开(公告)日:2024-12-05
申请号:US18689294
申请日:2022-10-04
Applicant: Rohm and Haas Company
Inventor: John J. Rabasco , John K. Riley
Abstract: The present invention relates to a composition comprising an aqueous solution of a branched HEUR, and a nonionic surfactant having an HLB in the range of 11 to 19. The composition of the present invention provides a rheology modifier that provides a formulator with independent control of viscosity across low-, mid-, and high-shear rate regimes.
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公开(公告)号:US12151015B2
公开(公告)日:2024-11-26
申请号:US17269574
申请日:2019-10-01
Inventor: Fanwen Zeng , Tian Lan , Xiaodong Lu , Isabelle Van Reeth , Helene Dihang , Marc Eeman , Inna Shulman
Abstract: A color cosmetic formulation is provided comprising: a color ingredient and a polymer blend, comprising: a single stage polymer and a silicone-grafted vinyl copolymer; wherein the single stage polymer comprises: structural units of a monoethylenically unsaturated non-ionic monomer; structural units of a monoethylenically unsaturated carboxylic acid monomer; and structural units of a multiethylenically unsaturated monomer having at least two ethylenically unsaturated groups per molecule; and wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl monomer; and structural units of a carbosiloxane dendrimer of formula (I).
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公开(公告)号:US20240384086A1
公开(公告)日:2024-11-21
申请号:US18692564
申请日:2022-11-01
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor: Ligeng Yin , Matthew Carter , Stephanie Barbon , Wen-Shiue Young , James Defelippis
IPC: C08L33/08 , C08F220/18
Abstract: The present invention relates to a composition comprising an aqueous solution of a copolymer of (meth)acrylic acid and a cyclic ketene acetal monomer. The copolymer is useful as a biodegradable dispersant.
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公开(公告)号:US12128125B2
公开(公告)日:2024-10-29
申请号:US17287394
申请日:2019-12-03
Inventor: Fanwen Zeng , Hilda G. Buss , Matthew Jeletic , Xiaodong Lu , Tian Lan , Isabelle Van Reeth , Helene Dihang , Marc Eeman , Bryan L. McCulloch , Jodi Mecca , Ralph C. Even , Inna Shulman , Michaeleen L. Pacholski
CPC classification number: A61K8/895 , A61K8/345 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/8147 , A61Q17/04 , A61K2800/544
Abstract: A polymer blend is provided comprising: (A) multistage polymer, comprising: acrylate rich stage comprising: structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I); and (B) silicone-grafted vinyl copolymer, wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl (B) monomer; and structural units of a carbosiloxane dendrimer of formula (V). Also provided are personal care formulations comprising the polymer blend.
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公开(公告)号:US20240352259A1
公开(公告)日:2024-10-24
申请号:US18685696
申请日:2022-09-27
Applicant: Rohm and Haas Company
Inventor: Erica A. Frankel , David M. Conner , Farhan Ansari
IPC: C09D5/02 , C09D7/61 , C09D7/65 , C09D133/08
CPC classification number: C09D5/024 , C09D7/61 , C09D7/65 , C09D133/08
Abstract: The present invention provides two-component instant-set aqueous coating compositions that provide coating films having good film quality despite a rapid film build and set. The compositions comprise, as Component I, a film-forming aqueous anionically stabilized polymer composition, such as an elastomeric acrylic or vinyl polymer, and one or more surfactants; and, as Component II, a polycation tolerant mixture of polycation, an aqueous polymer composition, such as a film-forming acrylic emulsion polymer, and a nonionic or ethoxylated anionic surfactant having an average of 7 or more or, preferably, 9 or more ethylene oxide groups per molecule. Component I can be an elastomeric roof coating composition. The compositions can be co-sprayed to form coatings, e.g. roof coatings.
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公开(公告)号:US12110394B2
公开(公告)日:2024-10-08
申请号:US17611696
申请日:2019-06-13
Inventor: Xiangting Dong , Ling Li , Zhihua Liu , Hui Liu , Wei Cui , Baoqing Zheng , Zhi Juan Gong , Yan Wu , Changkun Piao , Jia Tang , Dong Yun
IPC: C08L83/04 , C08F2/00 , C08F2/01 , C08F2/22 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/18 , C08F220/56 , C08F230/08 , C08G77/16 , C08G77/20 , C09D7/65
CPC classification number: C08L83/04 , C08F2/001 , C08F2/22 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/1804 , C08F220/1808 , C08F220/56 , C08F230/085 , C08G77/16 , C08G77/20 , C09D7/65 , C08G2150/00 , C08L2201/50 , C08L2205/02
Abstract: An aqueous dispersion comprising a multistage polymer comprising a first polymer and a second polymer that comprises structural units of an ethylenically unsaturated siloxane monomer, the multistage polymer comprising, by weight based on the weight of the multistage polymer, 4.5% or more of structural units of the ethylenically unsaturated siloxane monomer, and the coagulum content of the aqueous dispersion is less than 2,000 ppm after filtration through a 44 micron sieve.
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公开(公告)号:US20240327557A1
公开(公告)日:2024-10-03
申请号:US18699992
申请日:2022-11-02
Applicant: ROHM AND HAAS COMPANY
Inventor: Kylie Manning Kennedy , Laura j. Donkus , Michael A. Mallozzi , Himal H. Ray
IPC: C08F226/10 , C08F2/24 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/18 , C08F220/20 , C09J7/38 , C09J139/06
CPC classification number: C08F226/10 , C08F2/24 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/1804 , C08F220/1808 , C08F220/20 , C09J7/385 , C09J139/06 , C09J2203/334 , C09J2203/346 , C09J2203/354 , C09J2301/302 , C09J2433/00
Abstract: Provided is an aqueous composition comprising dispersed particles that comprise a polymer, wherein the polymer comprises, by weight based on the weight of the polymer, a) 60% to 99.95% polymerized units of one or more (meth)acrylate ester, b) 0.05% to 6% polymerized units of one or more N-vinyl lactam, c) 0% to 39.95% polymerized units of one or more other monomers. Also provided is a method of making that composition, a process for producing an article using that composition, and a method of bonding two substrates using that article.
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公开(公告)号:US12103990B2
公开(公告)日:2024-10-01
申请号:US17299006
申请日:2020-03-05
Inventor: Zachary Kean , Steven Swier , Arnold S. Brownell
IPC: C08F2/20 , C08F220/14 , C08K3/34 , C08K7/16 , C09D133/12
CPC classification number: C08F2/20 , C08F220/14 , C08K3/34 , C08K7/16 , C09D133/12
Abstract: An aqueous dispersion containing (meth)acrylate polymer particles and substituted silsesquioxane-based particles dispersed in an aqueous carrier, wherein: (a) the substituted silsesquioxane-based particles have an volume-average size of 5 nanometers or more and at the same time less than 500 nanometers as determined by dynamic light scattering; and (b) the substituted silsesquioxane-based particles are substituted only with one or more than one moiety selected from a group consisting of alkyl, aryl, hydroxyl, trace amounts of alkoxy and combinations thereof and contain 50 mole-percent or less hydroxyl substitution in the form silanol functionalities relative to moles of substituted silsesquioxane-based particle as determined by infrared spectroscopy.
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