Method for hydrogenating carboxylic acids in order to form alcohols

    公开(公告)号:US10450252B2

    公开(公告)日:2019-10-22

    申请号:US16089495

    申请日:2017-03-29

    Applicant: BASF SE

    Abstract: Process for the continuous hydrogenation of a carboxylic acid (I) to an alcohol (II) by means of hydrogen at a temperature of from 100 to 300° C. and a pressure of 10 to 33 MPa abs in a reactor tube through which axial flow occurs and which has a fixed-bed catalyst which is fixed therein and comprises at least one element from the group consisting of Re, Co and Cu, and in which the carboxylic acid (I) to be hydrogenated is present in a liquid mixture (III) comprising the carboxylic acid (I), water and alcohol (II), where the mixture (III) has an acid number of from 0.2 to 25 mg KOH/g and comprises at least 15% by weight of water and at least 20% by weight of alcohol (II) and the flow velocity of the flowing liquid calculated on the basis of the geometric cross-sectional area of the empty, catalyst-free reactor tube is from 10 to 50 m/h.

    Process to produce a mono vinyl ether

    公开(公告)号:US20210340090A1

    公开(公告)日:2021-11-04

    申请号:US17271419

    申请日:2019-08-19

    Applicant: BASF SE

    Abstract: A process produces a mono vinyl ether, R—O—CH═CH2. R represents an organic group with at least three carbon atoms. The process involves reacting a mono hydroxy compound. R—OH, with acetylene in presence of a catalyst to get a product mixture containing the mono vinyl ether, unconverted mono hydroxy compound, and the catalyst. To the product mixture, an ester is added that contains at least one ester group, X—O2C—. X is a hydrocarbon group containing less carbon atoms than R. The remaining mono hydroxy compound R—OH is reacted with the ester in the presence of the catalyst to get a transesterification product containing at least one ester group, R—O2C—, and an alcohol, X—OH. The mono vinyl ether is isolated from the product mixture obtained after the ester addition, optionally followed by purification of the mono vinyl ether by distillation.

    PROCESS FOR PURIFYING N-ALKYLPYRROLIDONES
    19.
    发明申请
    PROCESS FOR PURIFYING N-ALKYLPYRROLIDONES 有权
    净化N-烷基吡咯烷酮的方法

    公开(公告)号:US20160156022A1

    公开(公告)日:2016-06-02

    申请号:US15017864

    申请日:2016-02-08

    Applicant: BASF SE

    CPC classification number: H01M4/139 C07D207/263 C07D207/273 H01M4/04

    Abstract: Process for purifying N-alkylpyrrolidones which due to a previous use comprise at least one of the impurities of the formula I or II where R is hydrogen or a C1-C20-alkyl group, wherein a basic compound is added to the N-alkylpyrrolidone to be purified and the temperature of the mixture is at least 80° C. not more than 20 minutes after addition of the basic compound and N-alkylpyrrolidone is distiiied off from the mixture obtained.

    Abstract translation: 由于先前使用而提纯N-烷基吡咯烷酮的方法包括至少一种式I或II的杂质,其中R是氢或C1-C20烷基,其中将碱性化合物加到N-烷基吡咯烷酮中 纯化,混合物的温度至少为80℃,加入碱性化合物后不超过20分钟,从得到的混合物中分离出N-烷基吡咯烷酮。

    PROCESS FOR PRODUCING HIGH-PERFORMANCE THERMOPLASTICS WITH IMPROVED INTRINSIC COLOR
    20.
    发明申请
    PROCESS FOR PRODUCING HIGH-PERFORMANCE THERMOPLASTICS WITH IMPROVED INTRINSIC COLOR 有权
    生产具有改进内在色彩的高性能热塑性材料的工艺

    公开(公告)号:US20130324648A1

    公开(公告)日:2013-12-05

    申请号:US13902236

    申请日:2013-05-24

    Applicant: BASF SE

    CPC classification number: C08L71/126 C08G65/48 C08G65/485

    Abstract: The present invention relates to a process for the work-up of polymer solutions comprising N-methyl-2-pyrrolidone and a polymer where the polymer solution is hydrogenated with hydrogen in the presence of a hydrogenation catalyst.The present invention also relates to the product obtainable from said process, and to its use for producing, in particular, polyarylene ether products.

    Abstract translation: 本发明涉及一种用于处理包含N-甲基-2-吡咯烷酮和聚合物的聚合物溶液的方法,其中聚合物溶液在氢化催化剂存在下用氢氢化。 本发明还涉及可从所述方法获得的产品及其用于生产特别是聚芳醚产品的用途。

Patent Agency Ranking