Preparation method of super absorbent polymer and super absorbent polymer therefrom

    公开(公告)号:US11891487B2

    公开(公告)日:2024-02-06

    申请号:US17051859

    申请日:2019-09-24

    Applicant: LG Chem, Ltd.

    Abstract: The present disclosure relates to a preparation method of a super absorbent polymer having excellent basic absorbency and liquid permeability at the same time by optimizing the degree of cross-linking of a base resin powder and a surface cross-linked layer, and a super absorbent polymer prepared therefrom. The preparation method of a super absorbent polymer includes: forming a hydrogel polymer by cross-linking and polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer having a degree of neutralization of less than 72 mol % and an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent; and further neutralizing the base resin powder by treating the base resin powder with a basic solution during or after forming a surface cross-linked layer.

    Super Absorbent Polymer and Preparation Method Thereof

    公开(公告)号:US20210309777A1

    公开(公告)日:2021-10-07

    申请号:US17271414

    申请日:2019-12-20

    Applicant: LG Chem, Ltd.

    Abstract: The present disclosure relates to a super absorbent polymer and a preparation method of the same, which not only has excellent basic absorption performance, but also exhibits an improved absorption rate, and the like. The super absorbent polymer includes a base resin powder containing a first cross-linked polymer of a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer containing a second cross-linked polymer in which the first cross-linked polymer is additionally cross-linked by a surface cross-linking agent on the base resin powder, wherein the super absorbent polymer contains less than 9.9% by number of super absorbent polymer particles having an aspect ratio, which is defined as shortest diameter/longest diameter of each super absorbent polymer particle, of less than 0.5, a vortex time is 5 to 55 seconds by a vortex method, and a surface tension is 50 to 80 mN/m.

    Preparation Method of Super Absorbent Polymer and Super Absorbent Polymer Therefrom

    公开(公告)号:US20210230376A1

    公开(公告)日:2021-07-29

    申请号:US17051859

    申请日:2019-09-24

    Applicant: LG Chem, Ltd.

    Abstract: The present disclosure relates to a preparation method of a super absorbent polymer having excellent basic absorbency and liquid permeability at the same time by optimizing the degree of cross-linking of a base resin powder and a surface cross-linked layer, and a super absorbent polymer prepared therefrom. The preparation method of a super absorbent polymer includes forming a hydrogel polymer by cross-linking and polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer having a degree of neutralization of less than 72 mol % and an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent and further neutralizing the base resin powder by treating the base resin powder with a basic solution during or after forming a surface cross-linked layer.

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