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公开(公告)号:US20190194367A1
公开(公告)日:2019-06-27
申请号:US16329980
申请日:2018-06-26
Applicant: LG Chem, Ltd.
Inventor: Yong Hun Lee , Tae Young Won , Jun Wye Lee , Kwangin Shin , Chang Hun Han
CPC classification number: C08F20/14 , C08J3/075 , C08J3/12 , C08J3/24 , C08J3/245 , C08J2333/04 , C08K3/00 , C08K3/011 , C08K5/00 , C08K5/0025 , C08K5/103 , C08K5/109
Abstract: Provided are a superabsorbent polymer having a high bulk density value and showing a reduction in unpleasant odors which may be caused by various additives included in a preparation process while basically maintaining excellent absorption performance and absorption rate, and a preparation method thereof.
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公开(公告)号:US20230347317A1
公开(公告)日:2023-11-02
申请号:US18026495
申请日:2021-12-17
Applicant: LG Chem, Ltd.
Inventor: Hyungki Yoon , Jin Hyuck Ju , Kwangin Shin , Taebin Ahn
IPC: B01J20/26 , C08F220/06 , C08F222/10 , C08K5/098 , C08K5/1515 , C08K3/26 , C08J3/075 , C08J3/12 , C08J3/24 , C08F2/26 , C08F2/30 , C08J9/08
CPC classification number: B01J20/261 , B01J20/267 , C08F220/06 , C08F222/102 , C08K5/098 , C08K5/1515 , C08K3/26 , C08J3/075 , C08J3/12 , C08J3/24 , C08F2/26 , C08F2/30 , C08J9/08 , B01J2220/68 , C08K2201/003 , C08K2003/262 , C08J2201/026 , C08J2203/02 , C08J2207/12 , C08J2333/02
Abstract: The present disclosure relates to a method for preparing a super absorbent polymer. More specifically, the above method performs a polymerization reaction of a monomer in the presence of an aqueous dispersion of hydrophobic particles, and thus a super absorbent polymer having an improved absorption rate can be prepared without deterioration in absorption properties.
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公开(公告)号:US11718694B2
公开(公告)日:2023-08-08
申请号:US17271414
申请日:2019-12-20
Applicant: LG Chem, Ltd.
Inventor: Hyemin Lee , Tae Young Won , Jungmin Sohn , Junwye Lee , Seongbeom Heo , Kwangin Shin , Chang Hun Han
IPC: C08F220/06 , C08J3/075 , C08J3/12 , C08J3/24
CPC classification number: C08F220/06 , C08J3/075 , C08J3/122 , C08J3/245 , C08J2333/02
Abstract: The present disclosure relates to a super absorbent polymer and a preparation method of the same, which not only has excellent basic absorption performance, but also exhibits an improved absorption rate, and the like. The super absorbent polymer includes a base resin powder containing a first cross-linked polymer of a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer containing a second cross-linked polymer in which the first cross-linked polymer is additionally cross-linked by a surface cross-linking agent on the base resin powder, wherein the super absorbent polymer contains less than 9.9% by number of super absorbent polymer particles having an aspect ratio, which is defined as shortest diameter/longest diameter of each super absorbent polymer particle, of less than 0.5, a vortex time is 5 to 55 seconds by a vortex method, and a surface tension is 50 to 80 mN/m.
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公开(公告)号:US12030967B2
公开(公告)日:2024-07-09
申请号:US17057790
申请日:2019-10-01
Applicant: LG Chem, Ltd.
Inventor: Tae Young Won , Jungmin Sohn , Hyemin Lee , Junwye Lee , Seongbeom Heo , Kwangin Shin , Chang Hun Han
CPC classification number: C08F2/44 , B01J20/267 , B01J20/3064 , C08F2/01 , C08F220/06 , C08J3/245 , C08J9/08 , C08J9/36 , B01J2220/68 , C08J2201/026 , C08J2333/08
Abstract: The present disclosure relates to a preparation method of a super absorbent polymer capable of preparing a super absorbent polymer exhibiting an improved absorption rate while reducing an amount of a blowing agent used. The preparation method of a super absorbent polymer includes: preparing a monomer mixture including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; adjusting a dynamic pressure applied to the monomer mixture being transferred to 140 Pa or more by controlling a transfer rate while transferring the monomer mixture to a polymerization reactor; cross-linking and polymerizing the monomer mixture transferred to the polymerization reactor to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent to form a surface cross-linked layer.
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公开(公告)号:US20240139712A1
公开(公告)日:2024-05-02
申请号:US18276810
申请日:2022-11-21
Applicant: LG Chem, Ltd.
Inventor: Jin Hyuck Ju , Hyungki Yoon , Kwangin Shin , Taebin Ahn
CPC classification number: B01J20/267 , B01J20/3021 , B01J20/3085 , B01J20/321 , B01J20/3219 , B01J20/327 , C08F2810/20
Abstract: Provided is a method of preparing a superabsorbent polymer, more particularly, a method of preparing a superabsorbent polymer, in which a cationic polymer is included as a surface crosslinking agent, thereby achieving excellent general absorption-related properties. There is also provided a superabsorbent polymer including a base polymer powder including a crosslinked polymer of a water-soluble ethylenically unsaturated monomer having acidic groups, of which at least part is neutralized; and a surface-crosslinked layer which is formed on the base polymer powder by further crosslinking the crosslinked polymer via a surface crosslinking agent, wherein the surface-crosslinked layer includes a cationic polymer including quaternary ammonium ions in repeating units.
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公开(公告)号:US20210179790A1
公开(公告)日:2021-06-17
申请号:US16962947
申请日:2018-12-06
Applicant: LG Chem, Ltd.
Inventor: Junwye Lee , Chang Hun Lee , Kwangin Shin , Chang Hun Han , Sang Gi Lee
Abstract: The present disclosure relates to a super absorbent polymer having a high water content and a method for preparing the same. The super absorbent polymer according to the present disclosure has a relatively high water content compared to a conventional one but has no degradation in absorption-related physical properties, and thereby can be used in various fields.
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公开(公告)号:US20240110018A1
公开(公告)日:2024-04-04
申请号:US18539951
申请日:2023-12-14
Applicant: LG Chem, Ltd.
Inventor: Tae Young Won , Hyemin Lee , Junwye Lee , Seongbeom Heo , Kwangin Shin , Chang Hun Han
IPC: C08J3/075 , C08J3/12 , C08J3/24 , C08L101/14
CPC classification number: C08J3/075 , C08J3/12 , C08J3/24 , C08L101/14 , C08J2323/06 , C08L2312/00
Abstract: The present disclosure relates to a preparation method of a super absorbent polymer having excellent basic absorbency and liquid permeability at the same time by optimizing the degree of cross-linking of a base resin powder and a surface cross-linked layer, and a super absorbent polymer prepared therefrom. The preparation method of a super absorbent polymer includes the steps of: forming a hydrogel polymer by cross-linking and polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent, wherein the water-soluble ethylene-based unsaturated monomer has a degree of neutralization of less than 70 mol % in the step of forming a hydrogel polymer, and the preparation method further includes a step of further neutralizing the base resin powder by treating the base resin powder with a basic solution during the step of forming a surface cross-linked layer or after the step of forming a surface cross-linked layer.
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公开(公告)号:US20240018321A1
公开(公告)日:2024-01-18
申请号:US18028295
申请日:2021-12-17
Applicant: LG Chem, Ltd.
Inventor: Kwangin Shin , Jin Hyuck Ju , Hyungki Yoon , Taebin Ahn , Dong Hoon Park
CPC classification number: C08J9/0052 , C08J3/075 , C08J3/12 , C08J3/245 , C08J2333/02 , C08J9/16 , C08J2203/14 , C08J2203/22 , C08J9/141
Abstract: The present disclosure relates to a method for preparing a super absorbent polymer. More specifically, the above method performs a polymerization reaction of a monomer in the presence of an aqueous dispersion of hydrophobic particles, and thus a super absorbent polymer having an improved absorption rate can be prepared without deterioration in absorption properties.
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公开(公告)号:US20210230316A1
公开(公告)日:2021-07-29
申请号:US17057790
申请日:2019-10-01
Applicant: LG Chem, Ltd.
Inventor: Tae Young Won , Jungmin Sohn , Hyemin Lee , Junwye Lee , Seongbeom Heo , Kwangin Shin , Chang Hun Han
Abstract: The present disclosure relates to a preparation method of a super absorbent polymer capable of preparing a super absorbent polymer exhibiting an improved absorption rate while reducing an amount of a blowing agent used. The preparation method of a super absorbent polymer includes: preparing a monomer mixture including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; adjusting a dynamic pressure applied to the monomer mixture being transferred to 140 Pa or more by controlling a transfer rate while transferring the monomer mixture to a polymerization reactor; cross-linking and polymerizing the monomer mixture transferred to the polymerization reactor to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent to form a surface cross-linked layer.
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公开(公告)号:US20250161910A1
公开(公告)日:2025-05-22
申请号:US18837693
申请日:2023-11-06
Applicant: LG Chem, Ltd.
Inventor: Hyungki Yoon , Jin Hyuck Ju , Kwangin Shin , Taebin Ahn
Abstract: A super absorbent polymer having excellent properties including centrifuge retention capacity, absorption under pressure, vortex time, 1 min tap water free absorbency, and rewet properties. Thus, the super absorbent polymer can exhibit high absorption performance and excellent use feel when used in hygiene products such as diapers, and the like. A method for preparing the same is also provided.
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