公开(公告)号：US20160264740A1

公开(公告)日：2016-09-15

申请号：US15032713

申请日：2014-10-24

Applicant: TORAY INDUSTRIES INC.

Inventor： Naokichi Imai ,  Keisuke Inose ,  Kentaro Sano ,  Atsuki Tsuchiya

IPC: C08J5/06

CPC classification number: C08J5/06 ,  C08J2381/02 ,  C08J2381/04 ,  C08K5/29 ,  C08K7/06 ,  C08K9/04 ,  C08L81/02

Abstract: A fiber-reinforced resin composition includes a polyarylene sulfide (A), a carbodiimide compound (B) and carbon fibers (C) in specific blending amounts and in which the carbon fibers (C) are surface-treated with a sizing agent (D), the carbodiimide compound (B) is an aliphatic carbodiimide compound, and the sizing agent (D) is a compound having three or more specific functional groups in one molecule; and a fiber-reinforced composite material includes a thermoplastic resin (A′), an adhesive compound (B′) and reinforcing fibers (C′) and in which the adhesive compound (B′) is a compound having two or more specific structures in one molecule, the thermoplastic resin (A′) is a thermoplastic resin containing an element other than carbon in a repeating unit structure of a main chain, and an abundance ratio Rb of the adhesive compound (B′) is 1.2 or more.

Abstract translation: 纤维增强树脂组合物包括特定配合量的聚芳硫醚（A），碳二亚胺化合物（B）和碳纤维（C），其中碳纤维（C）用施胶剂（D）进行表面处理， ，碳二亚胺化合物（B）为脂肪族碳二亚胺化合物，上浆剂（D）为1分子中具有3个以上特定官能团的化合物; 纤维增强复合材料包括热塑性树脂（A'），粘合剂化合物（B'）和增强纤维（C'），并且其中粘合剂化合物（B'）是具有两个或多个特定结构的化合物 一个分子，热塑性树脂（A'）是在主链的重复单元结构中含有碳以外的元素的热塑性树脂，粘合剂（B'）的丰度比Rb为1.2以上。

公开(公告)号：US20140322504A1

公开(公告)日：2014-10-30

申请号：US14368746

申请日：2012-12-20

Applicant: Toray Industries, Inc.

Inventor： Kaori Narimatsu ,  Noriyuki Hirano ,  Masato Honma ,  Atsuki Tsuchiya ,  Akihiko Kitano

IPC: B32B5/26 ,  B32B5/02 ,  B32B7/02

CPC classification number: B32B5/26 ,  B32B5/022 ,  B32B5/024 ,  B32B5/028 ,  B32B7/02 ,  B32B2250/20 ,  B32B2260/023 ,  B32B2260/046 ,  B32B2262/106 ,  B32B2307/202 ,  B32B2307/558 ,  B32B2605/18 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/02 ,  C08J2463/10 ,  Y10T428/24942 ,  Y10T442/3065

Abstract: A carbon fiber base which comprises a continuous-carbon-fiber layer constituted of continuous carbon fibers and, disposed on one or each surface of the continuous-carbon-fiber layer, a carbon short-fiber web in which short carbon fibers having an average fiber length of 2-12 mm have been dispersed in the shape of single fibers; a prepreg which comprises the carbon fiber base and a matrix resin infiltrated into the carbon fiber base; and a carbon-fiber-reinforced composite material which comprises the carbon fiber base and a matrix resin infiltrated into the carbon fiber base and cured.

Abstract translation: 一种碳纤维基材，其由连续碳纤维构成的连续碳纤维层构成，并且在连续碳纤维层的一面或各表面上设置碳短纤维网，在该短纤维网中，具有平均纤维 2-12mm的长度分散成单纤维的形状; 预浸料坯，其包含碳纤维基材和渗透到碳纤维基材中的基体树脂; 以及碳纤维增强复合材料，其包含碳纤维基材和渗透到碳纤维基材中并固化的基质树脂。

公开(公告)号：US10584218B2

公开(公告)日：2020-03-10

申请号：US15770132

申请日：2016-10-21

Applicant: Toray Industries, Inc.

Inventor： Yuki Mitsutsuji ,  Shin Hirata ,  Atsuki Tsuchiya

IPC: B29B9/06 ,  C08J5/04 ,  C08K7/06 ,  C08L101/00 ,  C08J5/06 ,  C08L23/12 ,  C08K7/02 ,  B29B15/14 ,  B29K101/12 ,  B29K307/04

Abstract: A fiber reinforced thermoplastic resin molded article includes 5 to 45 parts by weight of carbon fibers (A), 1 to 45 parts by weight of organic fibers (B), and 10 to 94 parts by weight of a thermoplastic resin (C), based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C). The carbon fibers (A) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LA) of 0.3 to 3 mm. The organic fibers (B) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LB) of 0.5 to 5 mm, and a number average fiber diameter (dB) of 35 to 300 μm. The fiber reinforced thermoplastic resin molded article is excellent in impact strength and surface appearance.

公开(公告)号：US20180362760A1

公开(公告)日：2018-12-20

申请号：US16008926

申请日：2018-06-14

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Atsuki Tsuchiya ,  Masato Honma ,  Kohei Yamashita ,  Shunsuke Horiuchi ,  Koji Yamauchi

IPC: C08L71/08 ,  B29B15/12 ,  B29C70/48 ,  B29C70/52 ,  B29C70/30 ,  B29C70/40 ,  C08J5/04

Abstract: Provided is a molding material which includes a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly(phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.

公开(公告)号：US20180305507A1

公开(公告)日：2018-10-25

申请号：US15768671

申请日：2016-10-21

Applicant: Toray Industries, Inc.

Inventor： Yuki Mitsutsuji ,  Shin Hirata ,  Atsuki Tsuchiya

IPC: C08J5/04

CPC classification number: C08J5/042 ,  B29B15/14 ,  C08J5/04 ,  C08J5/046 ,  C08J2300/22 ,  C08J2467/00 ,  C08J2477/00 ,  C08J2481/04 ,  C08K7/06 ,  C08L101/00

Abstract: A fiber reinforced thermoplastic resin molded article includes 5 to 45 parts by weight of carbon fibers (A), 1 to 45 parts by weight of organic fibers (B), and 10 to 94 parts by weight of a thermoplastic resin (C), based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C). The carbon fibers (A) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LA) of 0.3 to 3 mm. The organic fibers (B) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LB) of 0.5 to 5 mm, and a number average fiber diameter (dB) of 1 to 10 μm. The fiber reinforced thermoplastic resin molded article excellent in impact strength.

公开(公告)号：US20150266260A1

公开(公告)日：2015-09-24

申请号：US14440815

申请日：2013-12-11

Applicant: TORAY INDUSTRIES, INC.

Inventor： Takashi Fujioka ,  Atsuki Tsuchiya

IPC: B32B3/12 ,  B32B27/08 ,  B29C43/02

CPC classification number: B32B3/12 ,  B29C43/02 ,  B29C43/021 ,  B29C70/081 ,  B29C70/202 ,  B29D99/0089 ,  B29K2105/12 ,  B29L2022/007 ,  B29L2031/3481 ,  B29L2031/608 ,  B32B3/00 ,  B32B3/14 ,  B32B3/20 ,  B32B3/26 ,  B32B3/28 ,  B32B3/30 ,  B32B5/00 ,  B32B5/02 ,  B32B5/022 ,  B32B5/024 ,  B32B5/026 ,  B32B5/06 ,  B32B5/08 ,  B32B5/10 ,  B32B5/12 ,  B32B5/14 ,  B32B5/28 ,  B32B7/00 ,  B32B7/02 ,  B32B7/04 ,  B32B7/08 ,  B32B7/10 ,  B32B19/00 ,  B32B19/02 ,  B32B19/04 ,  B32B19/06 ,  B32B27/00 ,  B32B27/04 ,  B32B27/06 ,  B32B27/08 ,  B32B27/12 ,  B32B27/20 ,  B32B27/22 ,  B32B27/28 ,  B32B27/285 ,  B32B27/286 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B27/42 ,  B32B2250/00 ,  B32B2260/021 ,  B32B2262/00 ,  B32B2262/0253 ,  B32B2262/0269 ,  B32B2262/101 ,  B32B2262/105 ,  B32B2262/106 ,  B32B2305/08 ,  B32B2307/3065 ,  B32B2307/546 ,  B32B2307/558 ,  B32B2307/714 ,  B32B2307/7145 ,  B32B2307/718 ,  B32B2307/732 ,  B32B2307/734 ,  B32B2419/00 ,  B32B2457/00 ,  B32B2535/00 ,  B32B2605/00 ,  B32B2605/08 ,  B32B2605/18 ,  Y10T428/24149 ,  Y10T428/24165

Abstract: A molded product and a unified molded product that are lightweight and also high in rigidity to meet the requirements from the market can be produced from a molded product comprising: a first member (I) containing a planar surface layer part and a protruding core part, and a second member (II) unified therewith, the first member (I) being of a fiber-reinforced resin (A) formed mainly of a reinforcing fiber (a1) and a matrix resin (a2), part of the threads of the reinforcing fiber (a1) extending penetratingly between the surface layer part and the core part, the part of the threads of the reinforcing fiber (a1) extending penetratingly at a rate of 400 threads/mm2 or more through the boundary surface between the surface layer part and the core part, the reinforcing fiber (a1) having a number-average fiber length Ln of 1 mm or more, and the core part forming a hollow structure.

Abstract translation: 可以通过模制产品来制造轻质且刚度高的模制产品和统一的模制产品，其包括：包含平坦表面层部分和突出芯部分的第一部件（I） 和与第一构件（II）一体化的第一构件（I），第一构件（I）由主要由增强纤维（a1）和基体树脂（a2）形成的纤维增强树脂（A），增强部分 纤维（a1）穿透表面层部分和芯部之间延伸，增强纤维（a1）的螺纹部分以400线/ mm2以上的速度穿过表面层部分和 核心部分，数均纤维长度Ln为1mm以上的增强纤维（a1）和形成中空结构的芯部。

公开(公告)号：US12109766B2

公开(公告)日：2024-10-08

申请号：US17796730

申请日：2020-02-21

Applicant: Toray Industries, Inc.

Inventor： Chiasa Kitani ,  Satoshi Matsumoto ,  Shigeru Kawashima ,  Atsuki Tsuchiya

IPC: B29C70/48 ,  B29C33/64 ,  B29K101/10 ,  B29K307/04

CPC classification number: B29C70/48 ,  B29C33/64 ,  B29K2101/10 ,  B29K2307/04

Abstract: Provided are a fiber-reinforced composite molded article prepared by heat-curing, as a molding material of a fiber-reinforced resin material, a resin composition to which an internal mold release agent is added, the fiber-reinforced composite molded article being capable of effectively producing mold releasability even with a small amount of the mold release agent added, and being capable of achieving high productivity, and a method of forming the fiber-reinforced composite molded article. A fiber-reinforced composite molded article prepared by curing reinforcing fibers and a resin composition, the resin composition including an internal mold release agent, wherein the value obtained by normalizing a Poisson-corrected ion intensity derived from the internal mold release agent detected on the surface of the fiber-reinforced composite molded article, by the Poisson-corrected gross positive secondary ion intensity detected in the predetermined area is higher than 0.1, and a molding method therefor.

公开(公告)号：US11015047B1

公开(公告)日：2021-05-25

申请号：US16638573

申请日：2018-09-03

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kazuki Yoshihiro ,  Yuki Mitsutsuji ,  Atsuki Tsuchiya

IPC: C08L23/12

Abstract: To provide a fiber reinforced thermoplastic resin molded article having excellent impact strength and flexural strength, provided is a fiber reinforced thermoplastic resin molded article, including: a carbon fiber (A), an organic fiber (B) having a strand strength of 1500 MPa or more and, a thermoplastic resin (C), wherein the fiber reinforced thermoplastic resin molded article contains 5 to 45 parts by weight of the carbon fiber (A), 1 to 45 parts by weight of the organic fiber (B), and 20 to 94 parts by weight of the thermoplastic resin (C) with respect to 100 parts by weight of the total of the carbon fiber (A), the organic fiber (B), and the thermoplastic resin (C), wherein a ratio (Lco/lno) of the critical fiber length Lco of the organic fiber (B) to the number average fiber length lno of the organic fiber (B) is 0.9 or more and 2.0 or less, and wherein an interfacial shear strength between the organic fiber (B) and the thermoplastic resin (C) is 3.0 MPa or more and 50 MPa or less.

公开(公告)号：US10385174B2

公开(公告)日：2019-08-20

申请号：US15329864

申请日：2015-07-30

Applicant: Toray Industries, Inc.

Inventor： Shin Hirata ,  Yuki Mitsutsuji ,  Sora Bang ,  Atsuki Tsuchiya

IPC: C08K7/02 ,  C08K7/04 ,  C08J5/04 ,  C08J5/06 ,  C08J5/10 ,  C08J5/24

Abstract: A fiber reinforced thermoplastic resin molding material includes a thermoplastic resin; a resin impregnated reinforcing fiber filament obtained by impregnating reinforcing fibers with a resin having a melt viscosity at 200° C. lower than a melt viscosity of the thermoplastic resin; and a reinforcing fiber modifier having a melt viscosity at 200° C. lower than the melt viscosity of the thermoplastic resin and a difference in solubility parameter value from the thermoplastic resin equal to or larger than 1.0, the molding material including 50 to 98.9 parts by weight of the thermoplastic resin; 1 to 40 parts by weight of the reinforcing fiber; 0.1 to 10 parts by weight of the reinforcing fiber modifier; and 0.2 to 12 parts by weight of the resin relative to total 100 parts by weight of the thermoplastic resin, the reinforcing fiber, and the reinforcing fiber modifier.

公开(公告)号：US10308775B2

公开(公告)日：2019-06-04

申请号：US15032713

申请日：2014-10-24

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Keisuke Inose ,  Kentaro Sano ,  Atsuki Tsuchiya

IPC: C08K9/04 ,  C08K5/29 ,  C08J5/06 ,  C08K7/06

Abstract: A fiber-reinforced resin composition includes a polyarylene sulfide (A), a carbodiimide compound (B) and carbon fibers (C) in specific blending amounts and in which the carbon fibers (C) are surface-treated with a sizing agent (D), the carbodiimide compound (B) is an aliphatic carbodiimide compound, and the sizing agent (D) is a compound having three or more specific functional groups in one molecule; and a fiber-reinforced composite material includes a thermoplastic resin (A′), an adhesive compound (B′) and reinforcing fibers (C′) and in which the adhesive compound (B′) is a compound having two or more specific structures in one molecule, the thermoplastic resin (A′) is a thermoplastic resin containing an element other than carbon in a repeating unit structure of a main chain, and an abundance ratio Rb of the adhesive compound (B′) is 1.2 or more.