Cyanoacrylate adhesives utilizing quinoid compound polymer stabilizer
    22.
    发明授权
    Cyanoacrylate adhesives utilizing quinoid compound polymer stabilizer 失效
    使用醌型复合聚合物稳定剂的氰基丙烯酸酯粘合剂

    公开(公告)号:US5306752A

    公开(公告)日:1994-04-26

    申请号:US959323

    申请日:1992-10-09

    CPC classification number: C09J4/00

    Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a compound of the formula: ##STR1## where R is C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2 ; R.sup.a, R.sup.b, R.sup.c and R.sup.d are independently H, monovalent hydrocarbon, halogen or strong electron withdrawing groups; or two of R.sup.a, R.sup.b, R.sup.c and R.sup.d combined form a fused hydrocarbon ring; R.sup.1 is C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2, or R.sup.1 and R.sup.b combined form a fused ring having a C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2 group in conjugation with R; R.sup.e is alkyl and Ph is phenyl orR and R.sup.1 are both O; and R.sup.a, R.sup.b, R.sup.c and R.sup.d are independently H, monovalent hydrocarbon, halogen, hydroxyl, alkoxyl or strong electron withdrawing groups, or two of R.sup.a, R.sup.b, R.sup.c and R.sup.d combined form a fused hydrocarbon ring, provided that at least two of R.sup.a, R.sup.b, R.sup.c and R.sup.d are halogen or strong electron withdrawing groups, orR is is O; R.sup.1 is C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or a diphenylmethylene group, the phenyl groups of which may be optionally substituted with one or more halo, hydroxyl, alkoxyl, hydrocarbon, nitro, acyloxy or cyano groups; and R.sup.a, R.sup.b, R.sup.c and R.sup.d are independently H, monovalent hydrocarbon, halogen or strong electron withdrawing groups, or two of R.sup.a, R.sup.b, R.sup.c and R.sup.d combined form a fused hydrocarbon ring.

    Abstract translation: 一种氰基丙烯酸酯单体粘合剂制剂,其具有改善的热性能,其由配方中包含的有效量提高下式化合物的固化聚合物的热阻:(*化学结构*),其中R是C(CN) 2,C(CO 2 Re)2,C(SO 2 Re)2或C(Ph)2; Ra,Rb,Rc和Rd独立地为H,一价烃,卤素或强吸电子基团; 或两个Ra,Rb,Rc和Rd组合形成稠合烃环; R1是C(CN)2,C(CO2Re)2,C(SO2Re)2或C(Ph)2,或者R1和Rb组合形成具有C(CN)2,C(CO 2 RE)2,C (SO2Re)2或C(Ph)2基团; Re为烷基,Ph为苯基或R和R1都为O; 并且R a,R b,R c和R d独立地为H,一价烃,卤素,羟基,烷氧基或强吸电子基团,或者R a,R b,R c和R 2中的两个组合形成稠合烃环,条件是至少两个Ra ,Rb,Rc和Rd为卤素或强吸电子基团,或R为O; R1是C(CN)2,C(CO2Re)2,C(SO2Re)2或二苯基亚甲基,其苯基可以任选被一个或多个卤素,羟基,烷氧基,烃,硝基,酰氧基或氰基取代 团体 并且Ra,Rb,Rc和Rd独立地为H,单价烃,卤素或强吸电子基团,或者R 1,R b,R c和R 2中的两个组合形成稠合烃环。

    CYANOACRYLATE COMPOSITIONS IN NON-FLOWABLE FORMS
    27.
    发明申请
    CYANOACRYLATE COMPOSITIONS IN NON-FLOWABLE FORMS 有权
    氰基丙烯酸酯组合物在不可流动的形式

    公开(公告)号:US20110170939A1

    公开(公告)日:2011-07-14

    申请号:US13051400

    申请日:2011-03-18

    CPC classification number: C09J4/06 B43M11/06 C08K5/103 C08L33/14 C09J9/005

    Abstract: The present invention relates to cyanoacrylate compositions in non-flowable and gel forms. More particularly, the present invention relates to non-flowable cyanoacrylate compositions which can be packaged in a convenient pocket-sized applicator dispenser for use in spreading the cyanoacrylate compositions onto substrates.

    Abstract translation: 本发明涉及不可流动和凝胶形式的氰基丙烯酸酯组合物。 更具体地说,本发明涉及不可流动的氰基丙烯酸酯组合物,其可以包装在方便的袋式涂布器分配器中,用于将氰基丙烯酸酯组合物铺展到基材上。

    Rapid curing anaerobic compositions
    30.
    发明申请
    Rapid curing anaerobic compositions 失效
    快速固化厌氧组合物

    公开(公告)号:US20050239952A1

    公开(公告)日:2005-10-27

    申请号:US10432199

    申请日:2001-09-21

    Abstract: A curable composition having enhanced cure speed which includes a curable component, a cure system and an additive for enhancing cure speed. The additive includes an alkali metal halide salt and the reaction product of: (a) a polyfunctional isocyanate and a member selected from the group consisting of an hydroxy and an amine; or (b) a phosgene or phosgene derivative, and a compound having 3 to 7 polyethylene glycol ether units terminated at one end with an ether group and at the other end with a reactive functional group selected from the group consisting of an amine, an amide, a thiol and an alcohol; or (c) a monohydroxy compound, a diisocyanate and a polyamine. Alternatively, in place of or in combination with the cure speed enhancing additive, an aromatic substituted (meth)acryl functionalized component may be incorporated into the curable component to achieve enhanced cure speed.

    Abstract translation: 具有增强的固化速度的可固化组合物,其包括可固化组分,固化体系和用于增强固化速度的添加剂。 添加剂包括碱金属卤化物盐和下列反应产物:(a)多官能异氰酸酯和选自羟基和胺的成员; 或(b)光气或光气衍生物,以及一端具有醚基的3-7个聚乙二醇醚单元的化合物,另一端具有选自胺,酰胺的反应性官能团 ,硫醇和酒精; 或(c)单羟基化合物,二异氰酸酯和多胺。 或者,代替或与固化速度增强添加剂组合,可以将芳族取代的(甲基)丙烯酰基官能化组分并入可固化组分中以实现增强的固化速度。

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