公开(公告)号：US20180238628A1

公开(公告)日：2018-08-23

申请号：US15514961

申请日：2015-10-05

Applicant: Haldor Topsoe A/S

Inventor： Per Juul Dahl

IPC: F28D7/16 ,  F28F9/22 ,  F28F9/26

Abstract: A heat exchanger has a pass baffle which is formed as an enclosure with two openings, one opening for connection to a shell-side fluid opening and one opening for passing heat exchanger tubes.

公开(公告)号：US09789470B2

公开(公告)日：2017-10-17

申请号：US14428268

申请日：2013-09-11

Applicant: Haldor Topsoe A/S

Inventor： Joachim Harteg Jacobsen ,  Charlotte Vinding Ovesen ,  Christian Daugaard

IPC: B01J23/755 ,  B01J37/08 ,  B01J37/02 ,  B01J37/00 ,  B01J35/00 ,  B01J35/10 ,  B01J23/04 ,  C01B3/40

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J21/10 ,  B01J23/005 ,  B01J23/04 ,  B01J23/78 ,  B01J23/83 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1033 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/0063 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0209 ,  B01J37/024 ,  B01J37/08 ,  B01J37/088 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1058 ,  C01B2203/1235 ,  C01B2203/1241 ,  Y02P20/52

Abstract: The invention provides a method for the production of a supported nickel catalyst, in which an aqueous mixture comprising an alkali metal salt plus other metal salts is sintered to form a support material. A supported nickel catalyst comprising potassium β-alumina is also provided.

公开(公告)号：US20170274322A1

公开(公告)日：2017-09-28

申请号：US15125502

申请日：2014-10-15

Applicant: Haldor Topsoe A/S

Inventor： Ton V.W. Janssens ,  Peter N. R. Vennestrom

IPC: B01D53/94 ,  B01J29/46 ,  B01J29/14 ,  B01J29/76 ,  B01J29/06 ,  B01J29/85

CPC classification number: B01D53/9418 ,  B01D2251/2062 ,  B01D2251/208 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2257/404 ,  B01J29/061 ,  B01J29/072 ,  B01J29/14 ,  B01J29/146 ,  B01J29/24 ,  B01J29/46 ,  B01J29/68 ,  B01J29/76 ,  B01J29/7607 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/80 ,  B01J29/85 ,  B01J37/0036 ,  B01J37/0238 ,  B01J37/04 ,  B01J37/08 ,  B01J38/08 ,  B01J2229/186 ,  B01J2229/38 ,  B01J2229/40

Abstract: A method is disclosed for the preparation of a metal exchanged microporous materials, e.g. metal exchanged silicoaluminophosphates or metal exchanged zeolites, or mixtures of metal exchanged microporous materials, comprising the steps of providing a dry mixture of a) one or more microporous materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia and one or more oxides of nitrogen to a temperature and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the microporous material; and obtaining the metal-exchanged microporous material.

公开(公告)号：US09464237B2

公开(公告)日：2016-10-11

申请号：US14424829

申请日：2013-08-15

Applicant: Haldor Topsoe A/S

Inventor： Per Juul Dahl ,  Stefan Andersen

IPC: C07C27/00 ,  C10G2/00 ,  C01B3/50

CPC classification number: C10G2/30 ,  C01B3/382 ,  C01B3/386 ,  C01B3/50 ,  C01B3/501 ,  C01B3/56 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/04 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/062 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/147 ,  C01B2203/148 ,  C01B2203/1604 ,  C10G2/32 ,  C10G2300/4031 ,  Y02P20/129

Abstract: The invention relates to a process for starting up a gas-to-liquid process including the production of synthesis gas and a downstream GTL process. The synthesis gas is produced by the use of autothermal reforming (ATR) or catalytic partial oxidation (CPO) and during the starting period the effluent gas from the ATR or CPO is significantly changed to form an off-gas recycle which is fed to the ATR or CPO. When the downstream GTL process is running, the recycle to ATR or CPO is shifted to its off-gas.

Abstract translation: 本发明涉及一种启动包括合成气生产和下游GTL工艺在内的气 - 液工艺的方法。 通过使用自热重整（ATR）或催化部分氧化（CPO）生产合成气，并且在起始阶段，来自ATR或CPO的流出气体被显着改变以形成进料到ATR的废气再循环 或CPO。 当下游GTL工艺运行时，对ATR或CPO的再循环转移到废气。

公开(公告)号：US20160046488A1

公开(公告)日：2016-02-18

申请号：US14832701

申请日：2015-08-21

Applicant: Haldor Topsoe A/S

Inventor： Kim Aasberg-Petersen ,  Peter Seier Christensen ,  Thomas Sandahl Christensen

IPC: C01B3/38 ,  C10K3/02 ,  C01B3/34 ,  C10G2/00

CPC classification number: C10K3/02 ,  B01D53/72 ,  C01B3/24 ,  C01B3/34 ,  C01B3/36 ,  C01B3/38 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/1276 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/148 ,  C07C1/0485 ,  C10G2/30 ,  C10G2/31 ,  C10G2/32 ,  C10G2300/4075

Abstract: A process for the production of synthesis gas by the use of autothermal reforming in which tail gas from downstream Fischer-Tropsh synthesis is hydrogenated and then added to the autothermal reforming stage.

公开(公告)号：US20160045861A1

公开(公告)日：2016-02-18

申请号：US14832733

申请日：2015-08-21

Applicant: Haldor Topsoe A/S

Inventor： Kim Aasberg-Petersen ,  Peter Seier Christensen ,  Thomas Sandahl Christensen

IPC: B01D53/72 ,  C01B3/38 ,  C10K3/02

CPC classification number: C10K3/02 ,  B01D53/72 ,  C01B3/24 ,  C01B3/34 ,  C01B3/36 ,  C01B3/38 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/1276 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/148 ,  C07C1/0485 ,  C10G2/30 ,  C10G2/31 ,  C10G2/32 ,  C10G2300/4075

Abstract: A process for the production of synthesis gas by the use of autothermal reforming in which tail gas from downstream Fischer-Tropsh synthesis is hydrogenated and then added to the autothermal reforming stage.

Abstract translation: 通过使用自热重整制造合成气的方法，其中来自下游费 - 托罗普合成的尾气被氢化，然后加入到自热重整阶段。

公开(公告)号：US20150232401A1

公开(公告)日：2015-08-20

申请号：US14424522

申请日：2013-08-14

Applicant: Haldor Topsoe A/S

Inventor： Finn Joensen ,  Jorgen Madsen ,  Poul Erik Højlund Nielsen

IPC: C07C41/09 ,  C07C41/42

CPC classification number: C07C41/09 ,  C07C29/1518 ,  C07C41/34 ,  C07C41/42 ,  Y02P20/52 ,  C07C31/04 ,  C07C43/043

Abstract: Process for the preparation of dimethyl ether product by catalytic conversion of synthesis gas to dimethyl ether comprising the steps of contacting a stream of synthesis gas comprising carbon dioxide in a dimethyl ether synthesis step in one or more reactors and with one or more catalysts active in the formation of methanol and dehydration of methanol to dimethyl ether and forming a product mixture comprising dimethyl ether, carbon dioxide and unconverted synthesis gas; cooling and separating the product mixture into a first liquid phase comprising dimethyl ether and carbon dioxide being dissolved in the formed dimethyl ether, and into a first gaseous phase comprising unconverted synthesis gas containing carbon monoxide and carbon dioxide; passing the first liquid phase to a scrubbing zone and contacting the phase with a liquid sorbent being effective in absorption of carbon dioxide; and withdrawing a dimethyl ether product being depleted in carbon dioxide from the scrubbing zone.

Abstract translation: 通过将合成气催化转化成二甲醚来制备二甲醚产物的方法，包括以下步骤：在一个或多个反应器中的二甲醚合成步骤中将包含二氧化碳的合成气流与一种或多种在 形成甲醇并将甲醇脱水成二甲醚，形成包含二甲醚，二氧化碳和未转化的合成气的产物混合物; 冷却并将产物混合物分离成包含溶解在形成的二甲醚中的二甲醚和二氧化碳的第一液相，并进入含有一氧化碳和二氧化碳的未转化的合成气的第一气相; 将第一液相通入洗涤区并使该相与吸收二氧化碳有效的液体吸附剂接触; 并从洗涤区抽出二氧化碳贫二氧化乙醚产物。

公开(公告)号：US20150175416A1

公开(公告)日：2015-06-25

申请号：US14636989

申请日：2015-03-03

Applicant: Haldor Topsoe A/S

Inventor： Martin F. Jensen ,  Claus F. Hansen ,  Søren G. Thomsen

IPC: C01B3/34 ,  B01J19/02

CPC classification number: C01B3/34 ,  B01J8/008 ,  B01J8/025 ,  B01J8/0257 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/062 ,  B01J8/067 ,  B01J2208/00212 ,  B01J2219/00006 ,  B01J2219/00038 ,  B01J2219/0004 ,  C01B3/382 ,  C01B2203/0205 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0805 ,  C01B2203/0816 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1258 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  Y10T29/4935

Abstract: The invention provides a Heat Exchange Reformer (HER) arranged to be part of a synthesis gas production unit and comprising at least a first and a second metal in order to minimise metal dusting. The invention moreover relates to a method for improved thermal control in a Heat Exchange Reformer (HER) and a computer readable storage medium. The invention provides improved thermal control and reduced metal dusting of the Heat Exchange Reformer.

Abstract translation: 本发明提供了一种布置成合成气生产单元的一部分并且包括至少第一和第二金属的热交换重整器（HER），以最小化金属粉尘。 本发明还涉及一种用于改进热交换重整器（HER）和计算机可读存储介质中的热控制的方法。 本发明提供了改进的热控制和减少热交换重整器的金属粉尘。

公开(公告)号：US20020038057A1

公开(公告)日：2002-03-28

申请号：US09961019

申请日：2001-09-21

Applicant: Haldor Topsoe A/S

Inventor： Iver Schmidt ,  Michael Brorson ,  Claus J.H. Jacobsen

IPC: C07C045/28 ,  C07C029/48

CPC classification number: C07D301/12 ,  C07B41/00 ,  Y10S977/775 ,  Y10S977/835 ,  Y10S977/881 ,  Y10S977/896

Abstract: Processes applying mesoporous titanium containing zeolite based catalysts for selective oxidation or epoxidation of hydrocarbons by peroxides.

公开(公告)号：US20010055560A1

公开(公告)日：2001-12-27

申请号：US09840438

申请日：2001-04-23

Applicant: Haldor Topsoe A/S

Inventor： Niels C. Schiodt ,  Poul E. Nielsen ,  Peter Lehrmann ,  Kim Aasberg-Petersen

IPC: C01B003/12 ,  C01B003/16

CPC classification number: B01J23/005 ,  C01B3/16 ,  Y02P20/52

Abstract: Process for the production of a hydrogen rich gas without formation of hydrocarbons comprising water gas shift conversion of a gas containing carbon monoxide and steam at a temperature of between 400null C. and 850null C. in the presence of a catalyst, which catalyst comprises one or more of the elements Mg, Mn, Al, Zr, La, Ce, Pr, and Nd, being able to form basic oxides, and mixtures thereof.

Abstract translation: 在不形成烃的情况下生产富氢气体的方法，包括在催化剂存在下，在400℃和850℃之间的温度下含有一氧化碳和蒸汽的气体的水煤气变换转化，所述催化剂包括 元素Mg，Mn，Al，Zr，La，Ce，Pr和Nd中的一种或多种能够形成碱性氧化物及其混合物。