公开(公告)号：US11230494B2

公开(公告)日：2022-01-25

申请号：US17011499

申请日：2020-09-03

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross

IPC: C03C3/091 ,  C03C21/00 ,  C03C3/097 ,  C03C10/00

Abstract: An article comprising an ion-exchanged glass material that prevents sharp contact flaws from entering a central region of the material that is under central tension and thus causing failure of the material. The glass material may be a glass or glass ceramic having a surface layer under compression. In some embodiments, the depth of the compressive layer is greater than about 75 μm. The greater depth of layer prevents flaws from penetrating the compressive layer to the region under tension.

公开(公告)号：US20210387898A1

公开(公告)日：2021-12-16

申请号：US17461071

申请日：2021-08-30

Applicant: Corning Incorporated

Inventor： Timothy Michael Gross

IPC: C03C3/097 ,  B32B17/06 ,  B32B9/04 ,  B32B7/12 ,  C03C21/00 ,  B32B27/36

Abstract: Embodiments of alkali aluminosilicate glass articles that may be chemically strengthened to achieve a maximum surface compressive stress that exceeds compressive stresses that have been achieved in similar glasses are disclosed. In one or more embodiments, the fictive temperature of these glass articles may be equal to the 1011 poise (P) viscosity temperature of the glass article. In some embodiments, the strengthened alkali aluminosilicate glass articles described herein may exhibit a maximum compressive stress of at least about 400 MPa, 800 MPa, 930 MPa or 1050 MPa. In some embodiments, the strengthened alkali aluminosilicate glass articles described herein may exhibit a compressive stress layer extending to a depth of layer of at least about 40 μm (in samples having a thickness of 1 mm). In still other embodiments, these strengthened alkali aluminosilicate glass articles exhibit a parabolic or near-parabolic tensile stress profile in the central region of the glass articles.

公开(公告)号：US20210323857A1

公开(公告)日：2021-10-21

申请号：US17271051

申请日：2019-08-23

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Lisa Anne Tietz Moore

IPC: C03C3/085 ,  C03C21/00

Abstract: Disclosed herein are embodiments of a glass article having a glass composition. The glass composition includes SiO2 in an amount of from 63 mol % to 75 mol %, Al2O3 in an amount of from 7 mol % to 13 mol %, R2O in an amount of from 13 mol % to 24 mol %, P2O5 in an amount of from 0.1 mol % to 1.2 mol %, and a water content β-OH of 0.1 abs/mm to 0.5 abs/mm. Further, the glass composition includes at least one of MgO or ZnO. MgO is present in a range from 0 mol % to 7 mol %, and ZnO is present in a range from 0 mol % to 7 mol %. The glass article has an anneal point and a softening point, and the relationship of (anneal point+softening point)/2 is less than 685° C.

公开(公告)号：US11111173B2

公开(公告)日：2021-09-07

申请号：US15799122

申请日：2017-10-31

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Xiaoju Guo ,  Charlene Marie Smith

IPC: C03C3/091 ,  C03C21/00 ,  C03C3/097 ,  H05K5/03 ,  H05K5/00 ,  C03C3/085 ,  G02F1/1333

Abstract: A glass article including, on an oxide basis, from 60 mol % to 74 mol % SiO2, from 7 mol % to 18 mol % Al2O3, from 3 mol % to 16 mol % B2O3, from 0 mol % to 6 mol % Na2O, from 0 mol % to 5 mol % P2O5, from 5 mol % to 11 mol % Li2O, less than or equal to 0.2 mol % SnO2, and from 0.5 mol % to 6.5 mol % divalent cation oxides. The glass article has a molar ratio of Al2O3:(R2O+RO) greater than or equal to 0.9, where R2O is a sum of alkali metal oxides in mol % and RO is a sum of divalent cation oxides in mol %.

公开(公告)号：US20210267213A1

公开(公告)日：2021-09-02

申请号：US17321905

申请日：2021-05-17

Applicant: CORNING INCORPORATED

Inventor： Dana Craig Bookbinder ,  Gary Stephen Calabrese ,  Timothy Michael Gross ,  Dayue Jiang ,  Jianguo Wang

IPC: A01N59/20 ,  C03C3/091 ,  C03C3/064 ,  A01N59/00 ,  A01N25/00 ,  C03C3/093 ,  C03C4/00 ,  C03B19/10 ,  A01N25/10 ,  C03B37/01 ,  C03C10/00 ,  C03C3/083 ,  C03C3/066 ,  A01N59/06 ,  A01N59/16 ,  A01N59/26 ,  A01N59/14 ,  C03C3/097 ,  C03C3/085 ,  A01N59/08 ,  C03C3/062 ,  C03C12/00 ,  C03C3/089 ,  A01N25/08 ,  A01N25/34 ,  C03C4/02

Abstract: Embodiments of the present invention pertain to antimicrobial glass compositions, glasses and articles. The articles include a glass, which may include a glass phase and a cuprite phase. In other embodiments, the glasses include as plurality of Cu1+ ions, a degradable phase including B2O3, P2O5 and K2O and a durable phase including SiO2. Other embodiments include glasses having a plurality of Cu1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The article may also include a polymer. The glasses and articles disclosed herein exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

公开(公告)号：US20210206145A1

公开(公告)日：2021-07-08

申请号：US17212533

申请日：2021-03-25

Applicant: CORNING INCORPORATED

Inventor： Polly Wanda CHU ,  Michael Patrick Donovan ,  Timothy Michael Gross ,  Louis Mattos, JR. ,  Prakash Chandra Panda ,  Robert Lee Smith, III

IPC: B32B17/06 ,  G06F1/16 ,  H01L51/00 ,  B32B7/12 ,  B32B17/10 ,  G09F9/30 ,  G02F1/1333 ,  B32B3/16

Abstract: A cover element for a foldable electronic device that includes a foldable glass element, first and second primary surfaces, and a compressive stress region extending from the first primary surface to a first depth that is defined by a stress σI of at least about 100 MPa in compression at the first primary surface. The device also includes a polymeric layer disposed over the first primary surface. The glass element has a stress profile such that when the glass element is bent to a target bend radius of from 1 mm to 20 mm, to induce a bending stress σB at the first primary surface in tension, σI+σB

公开(公告)号：US20210179472A1

公开(公告)日：2021-06-17

申请号：US17270759

申请日：2019-08-21

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Jeffrey Todd Kohli

IPC: C03B23/025 ,  C03C21/00 ,  C03C3/083 ,  B32B17/10

Abstract: Embodiments of a method for pair bending glass articles is provided herein. In the method, a first glass article and a second glass article are stacked to form a stack. The first glass article includes a first surface, a second surface that opposes the first surface, and a first composition having first annealing and softening temperatures. The second glass article includes a third surface, a fourth surface that opposes the third surface, and a second composition having second annealing and softening temperatures. The annealing temperatures are within 35° C. of each other and are at least 550° C. The softening temperatures are within 35° C. of each other and are at least 750° C. In the method, the stack is placed on a mold, and the stack is heated to a sagging temperature such that a shaped stack is formed.

公开(公告)号：US11028007B2

公开(公告)日：2021-06-08

申请号：US16002276

申请日：2018-06-07

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross ,  Zhongzhi Tang ,  Lisa Anne Tietz Moore

IPC: C03C3/087 ,  C03C3/085 ,  C03C3/097 ,  B32B17/10 ,  C03C21/00

Abstract: Embodiments of glass articles comprising an anneal point (° C.) and a softening point (° C.), and the relationship of (anneal point+softening point)/2 in a range from about 625° C. to about 725° C. are disclosed. In one or more embodiments, the glass articles include a glass composition including SiO2 in an amount in a range from about 63 mol % to about 75 mol %; Al2O3 in an amount in a range from about 7 mol % to about 13 mol %; R2O in an amount from about 13 mol % to about 24 mol %; P2O5 in an amount in a range from about 0 mol % to about 3 mol %, and one or both of MgO and ZnO. Laminates including such glass articles, and methods for making such laminates are also disclosed.

公开(公告)号：US20210155532A1

公开(公告)日：2021-05-27

申请号：US17164060

申请日：2021-02-01

Applicant: Corning Incorporated

Inventor： Timothy Michael Gross ,  Xiaoju Guo ,  Peter Joseph Lezzi ,  Alexandra Lai Ching Kao Andrews Mitchell ,  Rostislav Vatchev Roussev

IPC: C03C3/097 ,  C03C3/085 ,  C03C3/091 ,  C03C3/083

Abstract: A glass composition includes from 55.0 mol % to 75.0 mol % SiO2; from 8.0 mol % to 20.0 mol % Al2O3; from 3.0 mol % to 15.0 mol % Li2O; from 5.0 mol % to 15.0 mol % Na2O; and less than or equal to 1.5 mol % K2O. The glass composition has the following relationships: Al2O3+Li2O is greater than 22.5 mol %, R2O+RO is greater than or equal to 18.0 mol %, R2O/Al2O3 is greater than or equal to 1.06, SiO2+Al2O3+B2O3+P2O5 is greater than or equal to 78.0 mol %, and (SiO2+Al2O3+B2O3+P2O5)/Li2O is greater than or equal to 8.0. The glass composition may be used in a glass article or a consumer electronic product.

公开(公告)号：US10941071B2

公开(公告)日：2021-03-09

申请号：US14331753

申请日：2014-07-15

Applicant: CORNING INCORPORATED

Inventor： Timothy Michael Gross

IPC: C03C3/097 ,  C03C3/087 ,  C03C4/18 ,  C03C21/00

Abstract: A glass article is provided having from greater than or equal to about 40 mol % to less than or equal to about 68 mol % SiO2, less than or equal to about 11 mol % Al2O3, an R2O:R′O molar ratio of from greater than or equal to about 1:1 to less than or equal to about 2:1, and an MgO:CaO molar ratio of from greater than or equal to about 0.6:1 to less than or equal to about 1.8:1. The class article may also include a compressive stress layer on at least one surface thereof, the compressive stress layer having a compressive stress that is greater than or equal to about 800 MPa, and a depth that is greater than or equal to about 20 μm.