Abstract:
This invention relates generally to a method for producing fullerene nanotube catalyst supports and compositions thereof. In one embodiment, fullerene nanotubes or fullerene nanotube structures can be employed as the support material. A transition metal catalyst is added to the fullerene nanotubes. In a preferred embodiment, the catalyst metal cluster is deposited on the open nanotube end by a docking process that insures optimum location for the subsequent growth reaction. The metal atoms may be subjected to reductive conditions.
Abstract:
This invention relates generally to a fullerene nanotube purification process and more particularly to a purification process that comprises heating the fullerene nanotube-containing felt under oxidizing conditions to remove the amorphous carbon deposits and other contaminating materials. In a preferred mode of this purification procedure, the felt is heated in an aqueous solution of an inorganic oxidant, such as nitric acid, a mixture of hydrogen peroxide and sulfuric acid, or a potassium permanganate. Preferably, fullerene nanotube-containing felts are refluxed in an aqueous solution of an oxidizing acid at a concentration high enough to etch away amorphous carbon deposits within a practical time frame, but not so high that the fullerene nanotube material will be etched to a significant degree. When material having a high proportion of fullerene nanotubes is purified, the preparation produced will be enriched in fullerene nanotubes, so that the fullerene nanotubes are substantially free of other material.
Abstract:
This invention relates generally to a fullerene nanotube purification process and more particularly to a purification process that comprises heating the fullerene nanotube-containing felt under oxidizing conditions to remove the amorphous carbon deposits and other contaminating materials. In a preferred mode of this purification procedure, the felt is heated in an aqueous solution of an inorganic oxidant, such as nitric acid, a mixture of hydrogen peroxide and sulfuric acid, or a potassium permanganate. Preferably, fullerene nanotube-containing felts are refluxed in an aqueous solution of an oxidizing acid at a concentration high enough to etch away amorphous carbon deposits within a practical time frame, but not so high that the fullerene nanotube material will be etched to a significant degree. When material having a high proportion of fullerene nanotubes is purified, the preparation produced will be enriched in fullerene nanotubes, so that the fullerene nanotubes are substantially free of other material.
Abstract:
This invention relates generally to membranes comprising an array of single-wall carbon nanotubes (SWNT) wherein the membrane is nanoporous. In one embodiment, the membrane comprises a substantially two-dimensional array of a homogeneous population of single-walled nanotubes aggregated in substantially parallel orientation to form a monolayer extending in directions substantially perpendicular to the orientation of the individual nanotubes. Using single-wall carbon nanotubes of the same type and structure provides a homogeneous array. By using different single-wall carbon nanotubes, either a random or ordered heterogeneous structure can be produced by employing successive reactions after removal of previously masked areas of a substrate. Other embodiments of the invention include batteries comprising a membrane comprising an array of single-wall carbon nanotubes or carbon fibers that are aggregates of single-wall carbon nanotubes, and wherein the plurality of single-wall carbon nanotubes are in a generally parallel orientation.
Abstract:
This invention relates generally to carbon fiber produced from fullerene nanotube arrays. In one embodiment, the present invention involves a macroscopic carbon fiber comprising at least 106 fullerene nanotubes in generally parallel orientation.
Abstract:
This invention relates generally to a method for producing composites of single-wall carbon nanotubes (SWNTs) and compositions thereof. In one embodiment, the present invention involves a method of producing a composite material that includes a matrix and a carbon nanotube material embedded within said matrix. In another embodiment, a method of producing a composite material containing carbon nanotube material is disclosed. This method includes the steps of preparing an assembly of a fibrous material; adding the carbon nanotube material to the fibrous material; and adding a matrix material precursor to the carbon nanotube material and the fibrous material.
Abstract:
This invention relates generally to cutting single-wall carbon nanotubes (SWNT). In one embodiment, the present invention provides for preparation of homogeneous populations of short carbon nanotube molecules by cutting and annealing (reclosing) the nanotube pieces followed by fractionation. The cutting and annealing processes may be carried out on a purified nanotube bucky paper, on felts prior to purification of nanotubes or on any material that contains single-wall nanotubes. In one embodiment, oxidative etching with concentrated nitric acid is employed to cut SWNTs into shorter lengths. The annealed nanotubes may be disbursed in an aqueous detergent solution or an organic solvent for the fractionation. Closed tubes can also be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the end caps.
Abstract:
This invention relates generally to a method for producing composites of single-wall carbon nanotubes (SWNTs) and compositions thereof. In one embodiment, the present invention involves a method of producing a composite material that includes a matrix and a carbon nanotube material embedded within said matrix. In another embodiment, a method of producing a composite material containing carbon nanotube material is disclosed. This method includes the steps of preparing an assembly of a fibrous material; adding the carbon nanotube material to the fibrous material; and adding a matrix material precursor to the carbon nanotube material and the fibrous material.
Abstract:
This invention relates generally to forming an array of single-wall carbon nanotubes (SWNT). In one embodiment, a macroscopic molecular array is provided comprising at least about 106 single-wall carbon nanotubes in generally parallel orientation and having substantially similar lengths in the range of from about 5 to about 500 nanometers.
Abstract:
This invention relates to apparatus and methods for the disinfection of fluids and, in particular, to the disinfection of industrial fluids with ultraviolet radiation. These fluids are typically used in manufacturing as coolants in both long and short assembly lines. They commonly accumulate contaminants from multiple and diverse sources including oil and microorganisms. Fluids can be disinfected by establishing a fluid flow rate sufficient to prevent occlusion of the walls of the ultraviolet transmissible portion by contaminants. Fluids may be so heavily contaminated so as to require removal of at least a minimum percentage of contaminants (MPC) prior to irradiation. Such fluids may be processed to remove the minimum percentage of contaminants according to the equation: MPC=102-(23.45.times.lnV). Subject to removal of the MPC, a flow rate can be established to prevent occlusion of ultraviolet-transmissible portions of the flow path and thereby successfully treat the fluid with a disinfecting amount of ultraviolet radiation. Using these methods, microorganism levels can be greatly reduced with a reduced need for biocides or other anti-bacterial or anti-fungal agents. The methods and apparatus of the invention also comprise a flattened-tube mechanism for increased exposure to UV radiation and a turbulence-generating system to increase effectiveness of radiation treatments. Turbulence-generating systems include means for creating pressure differentials or aeration in the fluid stream as well as various types of structures such as ribbons, paddles, cones, beads or vanes that can be placed within the lumen of the tubing system. These methods are highly effective at extending the useful life of fluids such as coolants and reducing or eliminating the risks posed to workers by heavily contaminated or biocide-treated coolants.