Abstract:
A catalyst component for olefin polymerization comprising an α-cyanosuccinate compound as an internal electron donor, a catalyst comprising the catalyst component, and use of the catalyst in olefin polymerization. When used in propylene polymerization, the catalyst can exhibit good catalytic activity and good hydrogen response, and the resulting polymer can have a good isotacticity and a good molecular weight distribution.
Abstract:
This invention relates to novel double metal cyanide (DMC) catalysts for the production of polyether polyols by polyaddition of alkylene oxides onto starter compound comprising active hydrogen atoms, wherein the catalyst contains a) double metal cyanide compounds, b) organic complex ligands other than c) and c) two or more complex-forming components from the classes of compounds comprising functionalised polymers, glycidyl ethers, glycosides, carboxylic acid esters of polyhydric alcohols, bile acids or the salts, esters or amides thereof, cyclodextrins, phosphorus compounds, α,β-unsaturated carboxylic acid esters or ionic surface- or interface-active compounds. The catalysts according to the invention exhibit greatly increased activity in polyether polyol production.
Abstract:
The invention relates to vanadium/phosphorus oxide catalyst precursors useful in preparing catalysts useful in the oxidation of hydrocarbons containing 4 carbon atoms to maleic anhydride.
Abstract:
A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO+H.sub.2) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.
Abstract translation:公开了一种在用于将反应气体或气体混合物如一氧化碳和氢气转化成烃(过渡金属反应)的过渡金属催化剂上引入表面集合体的方法,该方法包括向合成气中加入路易斯碱 CO + H2)混合物。 以这种方式形成表面集合限制了将被利用的反应路径的数量和类型,从而大大缩小了产物分布并最大限度地提高了费 - 托反应的效率。 类似地,胺也可以通过反应气体或气体如氮气,氢气或烃组分的转化而产生。
Abstract:
A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The method then involves separating the reaction mixture into an aqueous phase (Pa) containing 1,2-propanediol and formic acid and an organic phase (Po); recycling at least part of the separated organic phase (Po) to the reaction; contacting at least a part of the separated aqueous phase (Pa) with a palladium catalyst; and recovering 1,2 propanediol from the aqueous phase provided by the contacting. The contacting of at least a part of the separated aqueous phase (Pa) with the palladium catalyst reduces the content of formic acid.
Abstract:
This invention pertains to hydroformylation catalysts containing a mixture of isomeric forms of halo-phosphorus ligands. This invention also describes a procedure for preparing isomers of certain halophosphite ligands, which contain the phosphorus atom in a macrocyclic ring.
Abstract:
The invention relates to the following subject matters: a) phosphoramidites of the formula (I); b) transition metal-containing compounds of the formula Me(acac)(CO)L, wherein L is selected from the formula (I); c) catalytically active compositions in the hydroformylation, which contain the compounds listed in a) and b); d) method for hydroformylation of unsaturated compounds using the catalytically active composition listed under c); and e) multi-phase reaction mixture containing unsaturated compounds, gas mixture comprising carbon monoxide, hydrogen, aldehydes, and the catalytically active compositions described in c).
Abstract:
An oxygen reduction catalyst of an embodiment includes: a stack of single-layer graphenes; and a phosphorus compound, wherein some of carbon atoms of the graphenes are replaced by nitrogen atoms, and the phosphorus compound has a peak of phosphorus 2p orbital of 133.0 to 134.5 eV in X-ray photoelectron spectrum.
Abstract:
A catalyst component for olefin polymerization comprising an α-cyanosuccinate compound as an internal electron donor, a catalyst comprising the catalyst component, and use of the catalyst in olefin polymerization. When used in propylene polymerization, the catalyst can exhibit good catalytic activity and good hydrogen response, and the resulting polymer can have a good isotacticity and a good molecular weight distribution.
Abstract:
Disclosed herein are methods for recovering diphosphite-containing compounds from mixtures comprising organic mononitriles and organic dinitriles, using liquid-liquid extraction. Also disclosed are pre-treatments to enhance extractability of the diphosphite-containing compounds.