Method of inducing surface ensembles on a metal catalyst
    24.
    发明授权
    Method of inducing surface ensembles on a metal catalyst 失效
    在金属催化剂上诱导表面集合体的方法

    公开(公告)号:US4840931A

    公开(公告)日:1989-06-20

    申请号:US103866

    申请日:1987-10-02

    Inventor: Steven S. Miller

    Abstract: A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO+H.sub.2) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

    Abstract translation: 公开了一种在用于将反应气体或气体混合物如一氧化碳和氢气转化成烃(过渡金属反应)的过渡金属催化剂上引入表面集合体的方法,该方法包括向合成气中加入路易斯碱 CO + H2)混合物。 以这种方式形成表面集合限制了将被利用的反应路径的数量和类型,从而大大缩小了产物分布并最大限度地提高了费 - 托反应的效率。 类似地,胺也可以通过反应气体或气体如氮气,氢气或烃组分的转化而产生。

    A METHOD FOR THE PREPARATION OF 1,2-PROPANEDIOL

    公开(公告)号:US20230399279A1

    公开(公告)日:2023-12-14

    申请号:US18249825

    申请日:2021-10-07

    CPC classification number: C07C29/48 C07C29/80 B01D3/143 B01J31/0255 B01J23/42

    Abstract: A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The method then involves separating the reaction mixture into an aqueous phase (Pa) containing 1,2-propanediol and formic acid and an organic phase (Po); recycling at least part of the separated organic phase (Po) to the reaction; contacting at least a part of the separated aqueous phase (Pa) with a palladium catalyst; and recovering 1,2 propanediol from the aqueous phase provided by the contacting. The contacting of at least a part of the separated aqueous phase (Pa) with the palladium catalyst reduces the content of formic acid.

Patent Agency Ranking