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    Process for the preparation of polyether polyols
    5.
    发明申请
    Process for the preparation of polyether polyols 失效
    制备聚醚多元醇的方法

    公开(公告)号：US20010053866A1

    公开(公告)日：2001-12-20

    申请号：US09827655

    申请日：2001-04-06

    Inventor： Uwe Denninger ,  Jorg Hofmann ,  Pramod Gupta

    IPC: C07C043/13

    CPC classification number: C08G65/2654 ,  B01J31/0211 ,  B01J31/0227 ,  B01J31/0228 ,  B01J31/0252 ,  B01J31/0255 ,  B01J31/0257 ,  B01J2231/48 ,  C07F5/069

    Abstract: The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.

    Abstract translation: 本发明涉及在特定的路易斯酸金属化合物作为催化剂存在下，通过环氧烷和含有活性氢的化合物的反应来制备聚醚多元醇的方法，该化合物是周期的第13族的新型双（全氟烷基磺酸）化合物 表格，以及其制备方法及其作为环醚开环聚合的催化剂的用途。

    Adamantane derivative/surfactant catalyzed paraffin-olefin alkylation
    6.
    发明授权
    Adamantane derivative/surfactant catalyzed paraffin-olefin alkylation 失效
    金刚烷衍生物/表面活性剂催化的烷基 - 烯烃烷基化

    公开(公告)号：US4560825A

    公开(公告)日：1985-12-24

    申请号：US682787

    申请日：1984-12-18

    Applicant: George M. Kramer ,  Edwin R. Ernst

    Inventor： George M. Kramer ,  Edwin R. Ernst

    IPC: B01J31/02 ,  C07C2/62 ,  C07C2/58

    CPC classification number: B01J31/0247 ,  B01J31/0225 ,  B01J31/0255 ,  C07C2/62 ,  C07C2527/03 ,  C07C2527/054 ,  C07C2531/02 ,  C07C2531/025

    Abstract: Disclosed is an alkylation process comprising the step of contacting a paraffinic compound, capable of forming a carbonium ion under strong acid conditions, with an olefin in the presence of a strong acid system comprised of an acid component and a mixture comprised of: (a) one or more adamantane derivatives containing at least one unsubstituted bridgehead position and which is capable of being protonated, or hydrogen bonded to, or dissociated by an acid; and (b) one or more surfactants capable of stabilizing the one or more adamantane derivatives of (a) above at a hydrocarbon-acid interface.

    Abstract translation: 公开了一种烷基化方法，其包括使在强酸条件下能够形成碳鎓离子的链烷烃化合物与烯烃在由酸组分和由以下组成的混合物组成的强酸体系存在下接触的步骤：（a） 一种或多种金刚烷衍生物，其含有至少一个未取代的桥头位置，并且其能够被质子化，或与酸键合或分解; 和（b）能够在烃 - 酸界面稳定上述（a）的一种或多种金刚烷衍生物的一种或多种表面活性剂。

    TRANSITION METAL COMPLEXES FOR ENANTIOSELECTIVE CATALYSIS OF CARBON-CARBON, CARBON-HETEROATOM, AND CARBON-HYDROGEN BOND FORMING REACTIONS
    8.
    发明申请
    TRANSITION METAL COMPLEXES FOR ENANTIOSELECTIVE CATALYSIS OF CARBON-CARBON, CARBON-HETEROATOM, AND CARBON-HYDROGEN BOND FORMING REACTIONS 有权
    过渡金属络合物，用于碳碳，碳 - 杂交和碳氢键形成反应的选择性催化

    公开(公告)号：US20150165429A1

    公开(公告)日：2015-06-18

    申请号：US14417655

    申请日：2013-07-29

    Applicant: THE TEXAS A&M UNIVERSITY SYSTEM

    Inventor： Kyle G. Lewis ,  John A. Gladysz ,  Subrata K. Ghosh

    IPC: B01J31/22 ,  C07F5/02 ,  C07F15/06

    CPC classification number: C07F15/065 ,  B01J31/0255 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/22 ,  B01J31/2295 ,  B01J2231/32 ,  B01J2231/323 ,  B01J2231/341 ,  B01J2531/845 ,  C07B53/00 ,  C07C211/65 ,  C07F5/027

    Abstract: In some embodiments, the present disclosure pertains to a compound, comprising a transition metal complex having the formula Φ-[M(x,y)-L1(w,v)-L2(t,u)-L3]p+An−mZ−p—m. In an embodiment of the present disclosure Φ may be A. In another embodiment Φ may be Δ. In some embodiments of the present disclosure, M is a transition metal. In a related embodiment, p is an integer corresponding to the oxidation state of M. In some embodiments of the present disclosure, each of x, y, w, v, t, and u independently comprise R. In other embodiments, each of x, y, w, v, t, and u independently comprise S. In an embodiment of the present disclosure, each of L1, L2, and L3 independently is a ligand comprising a substituted diamine. In some embodiments, An″ comprises a lipophilic anion, where m is from 1 to 3, and where Z− comprises an optional second anion.

    Abstract translation: 在一些实施方案中，本公开涉及包含具有式Φ-[M（x，y）-L1（w，v）-L2（t，u）-L3] p + An- mZ-p-m。 在本公开的实施例中，Φ可以是A.在另一个实施例中，Φ可以是＆Dgr。 在本公开的一些实施方案中，M是过渡金属。 在相关实施方案中，p是对应于M的氧化态的整数。在本公开的一些实施方案中，x，y，w，v，t和u中的每一个独立地包含R.在其它实施方案中，x ，y，w，v，t和u独立地包括S.在本公开的实施方案中，L1，L2和L3中的每一个独立地是包含取代的二胺的配体。 在一些实施方案中，An“包含亲脂性阴离子，其中m为1至3，并且其中Z-包含任选的第二阴离子。

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