公开(公告)号：US20040087731A1

公开(公告)日：2004-05-06

申请号：US10695183

申请日：2003-10-28

Inventor： Walter H. Ohrbom ,  Paul J. Harris

IPC: C08F008/30

CPC classification number: C08G18/3823 ,  C07C271/12 ,  C08G71/04 ,  C09D201/025

Abstract: The invention thus provides a curable coating composition comprising (A) a polymer resin comprising active hydrogen-containing functional group other than carbamate, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive additive comprising at least one compound having a molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of straight chain alkyl groups of more than 10 carbons, branched alkyl groups of from 5 to 30 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C). The invention also provides a method of making a preferred embodiment of the reactive additive (C) and the reactive additive (C).

Abstract translation: 因此，本发明提供一种可固化涂料组合物，其包含（A）包含除氨基甲酸酯以外的含活性氢的官能团的聚合物树脂，（B）具有与（A）上的所述官能团反应的基团的固化剂，和（C） 包含至少一种分子量为131至2000的化合物和包含至少一个伯氨基甲酸酯基团和至少一种选自多于10个碳的直链烷基的烷基的反应性添加剂，支链烷基 （A）和（B）中的一个或两个包含与（C）的伯氨基甲酸酯基反应的基团。 本发明还提供了制备反应性添加剂（C）和反应性添加剂（C）的优选实施方案的方法。

公开(公告)号：US06696159B2

公开(公告)日：2004-02-24

申请号：US10348491

申请日：2003-01-21

Applicant: Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce Oermann

Inventor： Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce Oermann

IPC: B32B2700

CPC classification number: C08G18/8116 ,  C08F8/00 ,  C08F2800/20 ,  C08F2810/50 ,  C08G18/3823 ,  C09D201/025 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31645 ,  C08F2220/325 ,  C08F220/34 ,  C08F220/20 ,  C08F212/08

Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

公开(公告)号：US20030170393A1

公开(公告)日：2003-09-11

申请号：US10351079

申请日：2003-01-23

Inventor： Walter H. Ohrbom ,  John A. Gilbert ,  Patricia A. Herrel ,  Marvin L. Green ,  Joanne Casale ,  Thomas G. Savino

IPC: B05D003/02

CPC classification number: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C09D201/025

Abstract: The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.

Abstract translation: 本发明提供涂料组合物，其包含基本上不含任何杂原子的反应性组分（a），并且在室温下不是结晶固体，并且其包含（i）12至72个碳原子，和（ii）至少两个官能 基团，和（b）包含与化合物（a）的官能团（ⅱ）反应的多个官能团（ⅲ）的交联剂，其中选择官能团（ⅱ）和（ⅲ），使得其中的反应产生 热不可逆化学键。 本发明的涂料组合物在环境蚀刻，相对湿度，QCT，芯片电阻，耐热裂纹性，耐寒裂纹性方面保持理想和/或改进的性能特征，提供了改进的固体，耐芯片性，柔性和/ ，粘合等。

公开(公告)号：US06541594B2

公开(公告)日：2003-04-01

申请号：US09741511

申请日：2000-12-19

Applicant: Walter H. Ohrbom ,  John A. Gilbert ,  Patricia A. Herrel ,  Marvin L. Green ,  Joanne Casale ,  Thomas G. Savino

Inventor： Walter H. Ohrbom ,  John A. Gilbert ,  Patricia A. Herrel ,  Marvin L. Green ,  Joanne Casale ,  Thomas G. Savino

IPC: C08G1800

CPC classification number: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C09D201/025

Abstract: The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.

公开(公告)号：US06541577B2

公开(公告)日：2003-04-01

申请号：US09731328

申请日：2000-12-06

Applicant: Walter H Ohrbom ,  John W. Rehfuss

Inventor： Walter H Ohrbom ,  John W. Rehfuss

IPC: C08F830

CPC classification number: C08G18/285 ,  C09D201/025

Abstract: The instant invention provides carbamate functional polymers and/or oligomers and coating compositions containing such which have improved levels of nonvolatile solids yet demonstrate good sprayability and etch resistance. The carbamate functional polymers and/or oligomers of the invention comprise the polymerization reaction product of (a) a polymer or oligomer comprising a plurality of functional. groups reactive with an active hydrogen group, and (b) a monomeric compound of the formula: wherein at least one of Y and Z is an active hydrogen containing group and the other is a primary carbamate group, and R is of the formula: —(L)n—R′ wherein L is a linking group of one or more carbons containing heteratoms selected from the group consisting of O, N, and mixtures thereof, R′ is an alkyl group free of heteratoms and selected from the group consisting of branched alkyl groups having from 5 to 30 carbons, straight chain alkyl groups of more than 2 carbons, and mixtures thereof, and n is a number from 0 to 1.

Abstract translation: 本发明提供了含有这样的氨基甲酸酯官能聚合物和/或低聚物和涂料组合物，其具有改进的非挥发性固体含量，但表现出良好的喷涂性和耐蚀刻性。 本发明的氨基甲酸酯官能聚合物和/或低聚物包含（a）包含多个官能团的聚合物或低聚物的聚合反应产物。 与活性氢基反应的基团，和（b）下式的单体化合物：其中Y和Z中的至少一个是含活性氢的基团，另一个是伯氨基甲酸酯基团，R是下式的 - （L）nR'，其中L是含有选自O，N及其混合物的杂原子的一个或多个碳原子的连接基团，R'是不含杂原子的烷基，选自支链烷基 具有5至30个碳的基团，大于2个碳的直链烷基及其混合物，n是0至1的数。

公开(公告)号：US20030050432A1

公开(公告)日：2003-03-13

申请号：US10206418

申请日：2002-07-26

Inventor： Swaminathan Ramesh ,  Marvin L. Green

IPC: C08G063/00 ,  C08L077/00

CPC classification number: B01F17/005 ,  C01P2004/61 ,  C01P2006/22 ,  C08G63/42 ,  C08G63/58 ,  C08G63/664 ,  C08G63/6854 ,  C09B67/009 ,  C09C1/3676 ,  C09C3/08 ,  C09C3/10 ,  C09D167/04 ,  C09D201/005 ,  C09D201/025

Abstract: The present invention is directed to a polyester resin for use in a coating composition. The polyester resin is the reaction product of a first compound comprising a plurality of hydroxyl groups, a lactone compound, a carboxylic acid anhydride, an epoxy compound having at least one epoxy group, and a carbamate compound. The present invention is also directed to a coating composition including the polyester resin and to a method of preparing the resin.

Abstract translation: 本发明涉及一种用于涂料组合物的聚酯树脂。 聚酯树脂是包含多个羟基的第一化合物，内酯化合物，羧酸酐，具有至少一个环氧基的环氧化合物和氨基甲酸酯化合物的反应产物。 本发明还涉及包含聚酯树脂的涂料组合物和制备树脂的方法。

公开(公告)号：US06471843B2

公开(公告)日：2002-10-29

申请号：US09907208

申请日：2001-07-17

Applicant: Timothy S. December ,  Walter H Ohrbom

Inventor： Timothy S. December ,  Walter H Ohrbom

IPC: C25D1308

CPC classification number: C09D5/4488 ,  C09D5/4407 ,  C09D201/025

Abstract: The invention provides a cathodic electrocoat coating composition having (A) a polymer comprising at least one primary carbamate group and at least one cationic salting site, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive additive comprising at least one compound having a molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of branched alkyl groups of from 5 to 30 carbons, straight chain alkyl groups of more than 10 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C).

公开(公告)号：US20020103319A1

公开(公告)日：2002-08-01

申请号：US10042820

申请日：2002-01-09

Inventor： Walter H. Ohrbom ,  David J. Law ,  Patricia A. Herrel

IPC: C08F226/02

CPC classification number: C07C271/12 ,  C08F20/36 ,  C08G18/2815 ,  C08G18/3831 ,  C09D161/28 ,  C09D201/025 ,  Y10T428/31551 ,  Y10T428/31725 ,  Y10T428/31855

Abstract: The invention provides water-soluble, null-hydroxy carbamate-functional materials and coating compositions, especially waterborne coating compositions, containing the carbamate-functional materials. The invention further provide a coating prepared from the coating composition and a coated substrate, especially an automotive substrate, having the coating thereon.

Abstract translation: 本发明提供水溶性β-羟基氨基甲酸酯官能材料和包含氨基甲酸酯官能材料的涂料组合物，特别是水性涂料组合物。 本发明进一步提供由涂料组合物制备的涂料和涂覆基材，特别是汽车基材，其上具有涂层。

公开(公告)号：US06420472B1

公开(公告)日：2002-07-16

申请号：US09570479

申请日：2000-05-12

Applicant: John W. Rehfuss ,  Marvin L. Green ,  Bertrum Miller

Inventor： John W. Rehfuss ,  Marvin L. Green ,  Bertrum Miller

IPC: C08K308

CPC classification number: C08G59/1477 ,  C08G59/1494 ,  C09D201/025 ,  C08L2666/16

Abstract: There is described a curable coating composition having at least one effect pigment which, upon cure, exhibits substantially improved orientation of the effect pigment and a corresponding improvement in appearance. The composition comprises: (A) a carbamate-functional component having a hydrophobicity equivalent to or greater than that of a carbamate-functional compound (A′) which is the reaction product of: (1) a compound comprising a plurality of hydroxyl groups, at least one of which is the result of a ring-opening reaction between an epoxy group and an organic acid group, and (2) cyanic acid or a compound comprising a carbamate group, and (B) a component comprising a plurality of groups that are reactive with the carbamate functional groups on component (A), and (C) at least one effect pigment, the curable coating composition when cured having a substantially improved effect pigment orientation. Preferably, the composition further comprises particular rheology control agents.

Abstract translation: 描述了具有至少一种效果颜料的可固化涂料组合物，其在固化时表现出显着改善的效果颜料的取向和相应的外观改进。 该组合物包含：（A）具有等于或大于氨基甲酸酯官能化合物（A'）的疏水性的氨基甲酸酯官能组分，其是以下物质的反应产物：（1）包含多个羟基的化合物， 其中至少一个是环氧基和有机酸基之间的开环反应的结果，和（2）氰酸或包含氨基甲酸酯基的化合物，和（B）包含多个基团的组分， 与组分（A）上的氨基甲酸酯官能团反应，和（C）至少一种效果颜料，固化后的可固化涂料组合物具有显着改善的颜料取向效果。 优选地，组合物还包含特定的流变控制剂。

公开(公告)号：US20020002245A1

公开(公告)日：2002-01-03

申请号：US09907208

申请日：2001-07-17

Inventor： Timothy S. December ,  Walter H. Ohrbom

IPC: C08L031/00

CPC classification number: C09D5/4488 ,  C09D5/4407 ,  C09D201/025

Abstract: The invention provides a cathodic electrocoat coating composition having (A) a polymer comprising at least one primary carbamate group and at least one cationic salting site, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive additive comprising at least one compound having a molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of branched alkyl groups of from 5 to 30 carbons, straight chain alkyl groups of more than 10 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C).

Abstract translation: 本发明提供一种阴极电泳涂料组合物，其具有（A）包含至少一个伯氨基甲酸酯基团和至少一个阳离子盐析部位的聚合物，（B）具有与（A）上的所述官能团反应的基团的固化剂，和 （C）包含至少一种分子量为131至2000的化合物的反应性添加剂，其包含至少一种伯氨基甲酸酯基和至少一种选自5至30个碳的支链烷基的烷基， 大于10个碳原子的直链烷基及其混合物，其中（A）和（B）中的一个或两个包含与（C）的伯氨基甲酸酯基团反应的基团。