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    Dehydrogenation catalyst
    26.
    发明授权
    Dehydrogenation catalyst 失效
    脱氢催化剂

    公开(公告)号：US3909451A

    公开(公告)日：1975-09-30

    申请号：US43200174

    申请日：1974-01-09

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/62 ,  C10G35/09 ,  C10G47/14 ,  B01J11/78

    CPC classification number: C10G47/14 ,  B01J23/626 ,  C07C2521/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C10G35/09

    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, under dehydrogenation conditions, with a dehydrogenation catalyst comprising a combination of catalytically effective amounts of an alkali or alkaline earth component with a catalytic composite consisting essentially of a tin component in combination with a platinum component on a carrier material, wherein the catalytic composite is prepared by the method which comprises: (a) impregnating a high surface area porous carrier material with a solution of a complex chlorostannate (II) chloroplatinate anionic species, the solution being stabilized in contact with the carrier material with an aqueous halogen acid; and thereafter, (b) drying and calcining the impregnated carrier material. For the dehydrogenation of normal paraffin hydrocarbons, this dehydrogenation catalyst preferably contains, on an elemental basis, about 0.01 to about 2 wt. % platinum, about 0.01 to about 5 wt. % tin and about 0.01 to about 5 wt. % alkali or alkaline earth metal.

    Abstract translation: 可脱氢烃在脱氢条件下与脱氢催化剂脱氢催化脱氢，脱氢催化剂包含催化有效量的碱金属或碱土金属组分与催化复合材料，催化复合材料主要由锡组分与载体材料上的铂组分组合 其中所述催化复合材料通过以下方法制备：所述方法包括：（a）用氯化锡酸盐复合物（II）氯铂酸盐阴离子物质的溶液浸渍高表面积多孔载体材料，所述溶液与载体材料稳定地接触， 含水卤素酸; （b）干燥并煅烧浸渍的载体材料。 对于正烷烃的脱氢，该脱氢催化剂优选以元素计含有约0.01至约2重量％ ％铂，约0.01至约5wt。 ％锡和约0.01至约5wt。 ％碱金属或碱土金属。

    Catalyst for hydrocarbon conversion
    27.
    发明授权
    Catalyst for hydrocarbon conversion 失效
    烃转化催化剂

    公开(公告)号：US3898178A

    公开(公告)日：1975-08-05

    申请号：US31458672

    申请日：1972-12-13

    Applicant: CATALYSE SOC PROD FRANCAIS

    Inventor： DUHAUT PIERRE ,  MIQUEL JEAN

    IPC: B01J23/56 ,  B01J23/62 ,  B01J23/648 ,  C07B61/00 ,  C10G35/09 ,  B01J11/78

    CPC classification number: C10G35/09 ,  B01J23/56

    Abstract: Catalyst and process for hydrocarbon conversions, e.g., reforming. The catalyst contains an alumina carrier, platinum, iridium, at least one metal selected from uranium, vanadium and gallium, and optionally halogen in the form of metal halide of one of the aforesaid components.

    Abstract translation: 用于烃转化的催化剂和方法，例如重整。 催化剂含有氧化铝载体，铂，铱，至少一种选自铀，钒和镓的金属，以及任选的卤素，其为上述组分之一的金属卤化物。

    Catalyst composition and production of 2,2-dichloropropionic acid therewith
    28.
    发明授权
    Catalyst composition and production of 2,2-dichloropropionic acid therewith 失效
    催化剂组成和其中生成2,2-二氯丙酸

    公开(公告)号：US3882045A

    公开(公告)日：1975-05-06

    申请号：US44674574

    申请日：1974-02-28

    Applicant: FOOLADI MIKE MEHDI

    Inventor： FOOLADI MIKE MEHDI

    IPC: B01J27/06 ,  C07C51/363 ,  B01J11/74 ,  B01J11/78

    CPC classification number: B01J27/06 ,  C07C51/363 ,  C07C53/19

    Abstract: A catalyst composition, particularly adapted for use in the production of dichloropropionic acid is provided. The catalyst composition comprises elemental iodine, which may be combined with a phosphorous trihalide or with bis (dimethyl thio carbamoyl) disulfide or with both. The catalyst composition makes possible the production of 2,2-dichloropropionic acid by direct chlorination of propionic acid, with substantially higher yields not heretofore obtainable in the production of 2,2dichloropropionic acid by direct chlorination of propionic acid.

    Abstract translation: 提供了特别适用于制备二氯丙酸的催化剂组合物。 催化剂组合物包含元素碘，其可与三卤化磷或双（二甲基硫代氨基甲酰基）二硫化物或两者结合。 该催化剂组合物可以通过丙酸的直接氯化生产2,2-二氯丙酸，而在通过直接氯化丙酸生产2,2-二氯丙酸时，产率基本上更高。

    Reforming process using platinum-lead-third component catalyst and catalyst therefor
    29.
    发明授权
    Reforming process using platinum-lead-third component catalyst and catalyst therefor 失效
    使用铂 - 铅三元组分催化剂及其催化剂的改性方法

    公开(公告)号：US3875048A

    公开(公告)日：1975-04-01

    申请号：US26814072

    申请日：1972-06-30

    Applicant: ASAHI CHEMICAL IND

    Inventor： IWAISAKO TOSHYYUKI ,  OHKI KUSUO ,  KOMINAMI NAOYA ,  YOMOGIDA HISAO

    IPC: B01J23/56 ,  B01J23/62 ,  B01J35/00 ,  C10G35/09 ,  C10G35/06 ,  B01J11/78

    CPC classification number: C10G35/09 ,  B01J23/56 ,  B01J23/628 ,  B01J35/0006

    Abstract: A method for reforming hydrocarbons which gives various advantages such as higher yield of aromatics, higher concentration of aromatics during the reforming operation, products of higher octane value, lower catalyst cost, etc. is given by using a catalyst containing 0.01 - 2 percent by weight of platinum and 0.01 - 5 percent by weight of lead as essential components and 0.01 - 5 percent by weight of an optional third component, the weight ratio of lead to platinum in the catalyst being 0.1 - 3:1, and the preparation of the catalyst comprising impregnating a carrier with a hydrochloric acid solution of a platinum compound, a solution of a lead compound and a solution of a compound corresponding to the optional third component, in any order, and calcining the resulting impregnated mass at a temperature of 570* - 1470*F. Alternatively, said lead component or third component can be supported on a carrier by coprecipitating or co-gelating a compound corresponding to the component and a compound corresponding to the carrier.

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