公开(公告)号：US20230338919A1

公开(公告)日：2023-10-26

申请号：US17787134

申请日：2020-12-18

Applicant: E3 METALS CORP. ,  THE GOVERNORS OF THE UNIVERSITY OF ALBERTA

Inventor： Daniel ALESSI ,  Salman SAFARIMOHSEN-ABAD

IPC: B01J20/04 ,  C02F1/28 ,  B01J39/10

CPC classification number: B01J20/041 ,  C02F1/281 ,  B01J39/10 ,  C02F2103/08

Abstract: Compositions and methods of preparing sorbent compositions (SCs) and protonated sorbent compositions (PSCs) for use in concentrating lithium from native brines are described. In particular, SCs of the general formula Li1.3-1.6Mn1.6-1.7O4, methods of preparing the SCs and PSCs that have improved properties for lithium extraction and concentration over single and multiple cycles are described.

公开(公告)号：US20230278023A1

公开(公告)日：2023-09-07

申请号：US17688047

申请日：2022-03-07

Applicant: Pavel Kudryavtsev ,  Nikolai Kudriavtsev

Inventor： Pavel Kudryavtsev ,  Nikolai Kudriavtsev

IPC: B01J39/10 ,  C22B26/12 ,  C22B3/42

CPC classification number: B01J39/10 ,  C22B26/12 ,  C22B3/42 ,  B01J2523/56 ,  B01J2523/69

Abstract: The invention relates to lithium-selective inorganic ion exchangers for the extraction of lithium from lithium-containing natural and technological brines. More specifically, invention relates to a technology for recovering lithium in the presence of oxidizing or reducing agents. The inorganic ion-exchanger is present in the form of solid particles which are represented by a chemical non-stoichiometric compound in the form of an inorganic polymeric aqua-oxo-hydroxo complex intended for selective extraction of lithium from lithium-containing natural and industrial brines, the inorganic ion-exchanger being represented by the following general formula:


HaNbO(2.5+0.5·a)·bL2O·cWO3·dH2O;

wherein:



“a” is a number ranging from 0.5 to 2.0,
“b” is a number ranging from 0.01 to 0.5,
“c” is a number ranging from 0.01 to 0.2, and
“d” is a number ranging from 0.1 to 2.0.

公开(公告)号：US20210386920A1

公开(公告)日：2021-12-16

申请号：US17222560

申请日：2021-04-05

Applicant: Baxter International Inc.

Inventor： Sujatha Karoor ,  Brian Donovan ,  Ton That Hai ,  Mari Katada ,  Luis Lu ,  Leo Martis ,  Stavroula Morti ,  Salim Mujais ,  Paul J. Sanders ,  Paul J. Soltys ,  Rahul Tandon

IPC: A61M1/16 ,  B01D15/00 ,  B01J20/02 ,  B01J20/06 ,  B01J20/20 ,  B01J20/22 ,  B01J20/28 ,  B01J39/10 ,  B01J39/12 ,  B01J41/10 ,  A61M1/28

Abstract: Methods and devices for providing dialysis treatment are provided. The device comprises a cartridge for providing regenerative dialysis, the cartridge comprising: a body having an inlet and an outlet and defining an interior, the interior including at least a layer comprising urease, a layer comprising zirconium oxide, a layer comprising zirconium phosphate, and a layer comprising carbon, wherein at least two of the layers are blended together to provide a gradient of the two materials.

公开(公告)号：US10541060B2

公开(公告)日：2020-01-21

申请号：US15106089

申请日：2014-12-17

Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

Inventor： Jeremy Causse ,  Agnes Grandjean ,  Alexei Tokarev ,  Yves Barre

IPC: G21F9/12 ,  C04B38/00 ,  B01J39/02 ,  B01J39/10 ,  C02F1/42 ,  B01J39/09 ,  B01J47/018 ,  C04B111/00 ,  C02F101/00 ,  C02F103/34

Abstract: A material in the form of an alveolar monolith consisting of a matrix of an inorganic oxide with a hierarchical and opened porosity comprising macropores, mesopores and micropores, said macropores, mesopores and micropores being interconnected, and nanoparticles of at least one metal cation exchange inorganic solid material being distributed in said porosity.A method for preparing this material and a method for separating a metal cation notably a cation of a radioactive isotope of a metal such as cesium using this material.

公开(公告)号：US20190256987A1

公开(公告)日：2019-08-22

申请号：US16366697

申请日：2019-03-27

Applicant: Lilac Solutions, Inc.

Inventor： David Henry SNYDACKER ,  Alexander John GRANT ,  Ryan Ali ZARKESH

IPC: C25B1/46 ,  C25B9/10 ,  B01D15/36 ,  B01D9/00 ,  B01D61/42 ,  C01D15/02 ,  B01J39/09 ,  B01J39/10 ,  B01J39/02

Abstract: The present invention relates to the extraction of lithium from liquid resources, such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.

公开(公告)号：US20170298475A1

公开(公告)日：2017-10-19

申请号：US15099045

申请日：2016-04-14

Applicant: UT-Battelle, LLC ,  Simbol Materials

Inventor： Mariappan Parans PARANTHAMAN ,  Ramesh R. Bhave ,  Bruce A. Moyer ,  Stephen Harrison

IPC: C22B26/12 ,  C01B39/50 ,  B01J39/10 ,  C22B3/42 ,  B01J39/02

CPC classification number: C22B26/12 ,  B01J20/08 ,  B01J20/18 ,  B01J39/02 ,  B01J39/10 ,  B01J39/14 ,  C01B39/50 ,  C22B3/42 ,  C22B7/006 ,  Y02P10/234

Abstract: A solid particulate composition useful in extracting a lithium salt from aqueous solutions, the composition comprising lithium, metal atoms, oxygen atoms, and at least one anionic species (X) selected from halide, nitrate, sulfate, carbonate and bicarbonate, all in a framework structure, wherein said metal atoms are selected from at least one of oxophilic main group metal and oxophilic transition metal atoms, provided that, if the metal atoms comprise aluminum atoms, then at least 10 mol % of said aluminum atoms are substituted with at least one metal atom selected from said at least one oxophilic main group and oxophilic transition metal atoms, other than aluminum, and wherein said lithium is present in said composition in an amount less than a saturated amount in order to permit extraction of lithium salt. Methods for extracting and recovering a lithium salt from an aqueous solution by use of the above-described composition are also described.

公开(公告)号：US08926874B2

公开(公告)日：2015-01-06

申请号：US13640085

申请日：2012-06-26

Applicant: Kang-Sup Chung ,  Tae Gong Ryu ,  Byoung Gyu Kim ,  Jung Ho Ryu

Inventor： Kang-Sup Chung ,  Tae Gong Ryu ,  Byoung Gyu Kim ,  Jung Ho Ryu

IPC: B29C65/00 ,  B01J39/10 ,  B01J20/04 ,  B01J20/06 ,  B01J20/30 ,  B01J20/02

CPC classification number: B01J39/10 ,  B01J20/0222 ,  B01J20/04 ,  B01J20/041 ,  B01J20/06 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3042 ,  B01J20/3078

Abstract: The present invention relates to a porous manganese oxide-based lithium absorbent and a method for preparing the same. The method includes the steps of preparing a mixture by mixing a reactant for the synthesis of a lithium-manganese oxide precursor powder with an inorganic binder, molding the mixture, preparing a porous lithium-manganese oxide precursor molded body by heat-treating the molded mixture, and acid-treating the porous lithium-manganese oxide precursor molded body such that lithium ions of the porous lithium-manganese oxide precursor are exchanged with hydrogen ions, wherein pores are formed in the lithium-manganese oxide precursor molded body by gas generated in the heat treatment. The porous manganese oxide-based lithium adsorbent according to the present invention is easy to handle and has many more adsorption reaction sites compared to existing molded adsorbents, thus providing high lithium adsorption efficiency.

Abstract translation: 本发明涉及一种多孔锰氧化物类锂吸收剂及其制备方法。 该方法包括通过将用于合成锂锰氧化物前体粉末的反应物与无机粘合剂混合来制备混合物的步骤，模制该混合物，通过热处理模塑混合物制备多孔锂锰氧化物前体成型体 对多孔锂锰氧化物前体成型体进行酸处理，使得多孔锂锰氧化物前体的锂离子与氢离子交换，其中在锂锰氧化物前体成型体中通过在 热处理。 与现有的成型吸附剂相比，本发明的多孔氧化锰类锂吸附剂易于处理，吸附反应位置更多，因此提供高的锂吸附效率。

公开(公告)号：US4971729A

公开(公告)日：1990-11-20

申请号：US462943

申请日：1990-01-04

Applicant: David A. White

Inventor： David A. White

IPC: B01J20/06 ,  B01J39/10 ,  C01G43/00 ,  G21F9/00 ,  G21F9/12

CPC classification number: B01J39/10 ,  G21F9/12

Abstract: An ion exchange material comprises an oxide of a first element selected from elements of Groups IVa, IVb, Va, Vb, VIa, VIb, VIIa, or lanthanide or actinide series of the Periodic Table, in combination with an oxide of at least one different element selected from elements of the afore-mentioned groups of the Periodic Table so as to form a composite material. For example, a composite ion exchange material may comprise silicon dioxide and manganese dioxide. By selecting the appropriate oxides a composite ion exchange material can be prepared which has greater mechanical and/or chemical stability than an individual oxide of the composite material.

Abstract translation: 离子交换材料包括选自元素周期表第Ⅳa，Ⅳb，Ⅴa，Ⅴb，Ⅵa，Ⅵb，Ⅶa或镧系元素或锕系元素的元素的第一元素的氧化物，以及至少一种不同的氧化物 元素选自上述元素周期表的元素，以形成复合材料。 例如，复合离子交换材料可以包括二氧化硅和二氧化锰。 通过选择合适的氧化物，可以制备复合离子交换材料，其具有比复合材料的单个氧化物更大的机械和/或化学稳定性。

公开(公告)号：US4642193A

公开(公告)日：1987-02-10

申请号：US694749

申请日：1985-01-25

Applicant: Shigeo Miyata ,  Noriko Iizima ,  Tadashi Manabe

Inventor： Shigeo Miyata ,  Noriko Iizima ,  Tadashi Manabe

IPC: B01J43/00 ,  B01J20/02 ,  B01J20/04 ,  B01J20/06 ,  B01J20/08 ,  B01J39/10 ,  B01J41/10 ,  C01F7/00 ,  G21C19/307 ,  G21F9/12 ,  C02F1/42

CPC classification number: G21F9/12 ,  B01J20/06 ,  B01J20/08

Abstract: A method of purifying cooling water used in nuclear reactors, which comprises contacting said cooling water with a hydrotalcite compound of the following formulaM.sub.1-x.sup.2+ M.sub.x.sup.3+ (OH).sub.2 A.sub.x/n.sup.n-. mH.sub.2 O (1)wherein M.sup.2+ represents a divalent metal cation, M.sup.3+ represents a trivalent metal cation, A.sup.n- represents an anion having a valence of n, and x and m satisfy the following expressions0

Abstract translation: 一种净化核反应堆中使用的冷却水的方法，其包括使所述冷却水与下式M1-x2 + Mx3 +（OH）2Ax / nn-的水滑石化合物接触。 mH 2 O（1）其中M2 +表示二价金属阳离子，M3 +表示三价金属阳离子，An表示n价的阴离子，x和m满足以下表达式0

公开(公告)号：US4313844A

公开(公告)日：1982-02-02

申请号：US82658

申请日：1979-10-09

Applicant: Hiroshi Sato ,  Sadaaki Shigeta ,  Hiroyuki Uchida

Inventor： Hiroshi Sato ,  Sadaaki Shigeta ,  Hiroyuki Uchida

IPC: B01J39/08 ,  C09K3/00 ,  B01J39/10 ,  B01J41/10 ,  C02F1/42

CPC classification number: B01J39/085 ,  C22B3/42 ,  Y02P10/234 ,  Y10S423/14

Abstract: An inorganic ion exchanger prepared by kneading a blend of anatase type titanic acid or amorphous titanic acid with sulfuric acid, hydrochloric acid or phosphoric acid and water, extrusion molding the blend, and thereafter, heat treating the extruded product at an elevated temperature. The inorganic ion exchanger has high strength in water and is suitable for use in the removal or the concentration and recovery of injurious or beneficial materials contained in water.

Abstract translation: 通过将锐钛矿型钛酸或无定形钛酸的混合物与硫酸，盐酸或磷酸和水捏合而制备的无机离子交换剂，挤出成型共混物，然后在高温下热处理挤出产物。 无机离子交换剂在水中具有高强度，适用于去除或浓缩和回收水中含有的有害或有益物质。