公开(公告)号：US5215647A

公开(公告)日：1993-06-01

申请号：US728488

申请日：1991-07-11

Applicant: Eit Drent ,  Marinus J. Reynhout ,  Henricus P. M. Tomassen

Inventor： Eit Drent ,  Marinus J. Reynhout ,  Henricus P. M. Tomassen

IPC: C08L73/00 ,  C08G67/02 ,  C10L1/192 ,  C10L1/195 ,  C10L1/198 ,  C10L10/14 ,  C10M143/08 ,  C10M145/04

CPC classification number: C10L1/195 ,  C08G67/02 ,  C10M143/08 ,  C10M145/04 ,  C10M2205/028 ,  C10M2209/00 ,  C10M2209/02 ,  C10M2209/04 ,  C10M2209/10

Abstract: Hydrocarbon oil compositions of improved low temperature properties comprise intimate mixtures of hydrocarbon oil and a linear alternating polymer of carbon monoxide and at least one straight-chain .alpha.-olefin of relatively high carbon number.

公开(公告)号：US5133898A

公开(公告)日：1992-07-28

申请号：US471554

申请日：1990-01-29

Applicant: Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

Inventor： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

IPC: B01F17/00 ,  B01F17/42 ,  B01F17/52 ,  B01F17/54 ,  C08F8/14 ,  C08G81/02 ,  C10L1/192 ,  C10L1/195 ,  C10L1/198 ,  C10L10/18

CPC classification number: B01F17/0028 ,  C08F8/14 ,  C08F2810/30 ,  Y10S516/918

Abstract: Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

Abstract translation: 公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用 选择的醇和聚氧化烯一元醇的混合物。 与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。 它们特别适用于天然和合成油的W / O乳化剂。

公开(公告)号：US5039432A

公开(公告)日：1991-08-13

申请号：US320122

申请日：1989-03-07

Applicant: Wolfgang Ritter ,  Claudia Meyer ,  Wolfgang Zoellner ,  Claus-Peter Herold ,  Stephan V. Tapavicza

Inventor： Wolfgang Ritter ,  Claudia Meyer ,  Wolfgang Zoellner ,  Claus-Peter Herold ,  Stephan V. Tapavicza

IPC: E21B43/22 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/12 ,  C10L1/192 ,  C10L1/196 ,  C10L10/16

CPC classification number: C10L10/16 ,  C10L1/1963 ,  Y10S507/93 ,  Y10S507/931 ,  Y10T137/0391

Abstract: Method of reducing the pour-point and improving the flowability of petroleum oil or a fraction thereof by adding thereto a flowability-improving quantity of at least one copolymer of (a) an acrylic acid ester, a methacrylic acid ester, or a mixture of an acrylic acid ester and a methacrylic acid ester, and (b) not more than 20% by weight, based on the weight of the copolymer, of acrylic acid, methacrylic acid, or a mixture of acrylic acid and methacrylic acid, and wherein said esters in component (a) are esters of a C.sub.16 or higher alcohol or an alcohol mixture wherein at least 75% by weight thereof is one or more alcohols containing at least 16 carbon atoms; and the compositions resulting therefrom.

Abstract translation: 通过向其中加入至少一种（a）丙烯酸酯，甲基丙烯酸酯或其混合物的共聚物的流动性提高量来降低石油油或其馏分的流动性和改善流动性的方法 丙烯酸酯和甲基丙烯酸酯，和（b）基于共聚物的重量，不超过20重量％的丙烯酸，甲基丙烯酸或丙烯酸和甲基丙烯酸的混合物，并且其中所述酯 在组分（a）中是C16或更高级醇或醇混合物的酯，其中至少75％重量是一种或多种含有至少16个碳原子的醇; 和由此得到的组合物。

公开(公告)号：US4943658A

公开(公告)日：1990-07-24

申请号：US173102

申请日：1988-03-28

Applicant: Tatsuo Kinoshita ,  Shuji Minami ,  Kinya Mizui ,  Ryousuke Kaneshige

Inventor： Tatsuo Kinoshita ,  Shuji Minami ,  Kinya Mizui ,  Ryousuke Kaneshige

IPC: C10M143/04 ,  C08F8/06 ,  C09D7/12 ,  C10L1/192 ,  C10L1/195 ,  C10L10/08 ,  C10M107/04 ,  C10M143/06 ,  C10M143/08 ,  C10M143/18 ,  C10N20/00 ,  C10N20/04 ,  C10N30/00 ,  C10N40/00 ,  C10N40/04 ,  C10N40/20 ,  C10N40/36 ,  C10N60/04

CPC classification number: C10M143/18 ,  C08F8/06 ,  C09D7/125 ,  C10M107/04 ,  C08F2800/10 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/0206 ,  C10M2205/022 ,  C10M2205/0225 ,  C10M2205/12 ,  C10N2220/02 ,  C10N2240/00 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/401 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  C10N2250/10

Abstract: There is provided a liquid oxidatively modified ethylenic random copolymer, which is an oxidatively modified product of a liquid ethylenic random copolymer comprising 20 to 80 mol % of ethylene and 80 to 20 mol % of .alpha.-olefin, and has (i) a number average molecular weight (Mn) in the range of from 200 to 10,000, (ii) a molecular weight distribution (Mw/Mn) given as weight average molecular weight (Mw) divided by number average molecular weight (Mn) in the range of up to 4, and (iii) an oxygen content of from 0.1 to 20% by weight, an acid value of from 0.1 to 50, and a saponification value of from 0.1 to 100. It is prepared by contacting a corresponding ethylenic random copolymer with oxygen-containing gas at 100.degree.-250.degree. C.

公开(公告)号：US4900332A

公开(公告)日：1990-02-13

申请号：US176064

申请日：1988-03-31

Applicant: Jacques Denis ,  Bernard Sillion ,  Bernard Damin ,  Robert Leger

Inventor： Jacques Denis ,  Bernard Sillion ,  Bernard Damin ,  Robert Leger

IPC: C08F8/32 ,  C08F8/48 ,  C08F222/00 ,  C10L1/16 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/234 ,  C10L1/236 ,  C10L10/14 ,  F02B3/06

CPC classification number: C08F222/00 ,  C08F8/32 ,  C10L1/195 ,  C10L1/2364 ,  F02B3/06

Abstract: Copolymers of average number molecular weight from about 300 to 5,000 comprising recurrent units originating (A) from alpha olefins, (B) from .alpha.,.beta. unsaturated .alpha., .gamma. dicarboxylic compounds, (C) from unsaturated acid esters of 1,2-diols, optionally etherified or esterified, and (D) optionally from acrylic esters, the proportions of the recurrent units being 5-60% for (A), 10-70% for (B), 10-60% for (C) and 0-60% for (D), at least one of recurrent units (A), (B) and/or (C) comprising at least 12 carbon atoms, and at least 10% of the recurrent units of said copolymer being (B) recurrent units of N-substituted imide type. These copolymers form additives useful to lower the pour point of middle distillates, particularly of gas-oils. The use of said additives at a concentration from 0.001 to 2% by weight results in a substantial decrease of the pour point of the treated middle distillates.

Abstract translation: 平均数分子量为约300至5,000的共聚物包括源自（A）的来自α-烯烃的反应单元，（B）来自α，β不饱和α，γ二羧酸化合物，（C）来自1,2-二醇的不饱和酸酯， 任选地醚化或酯化，和（D）任选地由丙烯酸酯，反应单元的比例对于（A）为5-60％，（B）为10-70％，（C）为10-60％ （D）的60％，至少包含至少12个碳原子的复发单元（A），（B）和/或（C）中的至少一种，所述共聚物的反复单元的至少10％是（B） 单位为N-取代酰亚胺型。 这些共聚物形成可用于降低中间馏分，特别是瓦斯油的倾点的添加剂。 浓度为0.001至2重量％的所述添加剂的使用导致经处理的中间馏分的倾点的显着降低。

公开(公告)号：US4834776A

公开(公告)日：1989-05-30

申请号：US129634

申请日：1987-12-07

Applicant: Joan C. Axelrod ,  Sheldon Chibnik

Inventor： Joan C. Axelrod ,  Sheldon Chibnik

IPC: C10L1/192 ,  C09K3/00 ,  C10L1/10 ,  C10L1/18 ,  C10L1/198 ,  C10L1/22 ,  C10L1/222 ,  C10L1/224 ,  C10L1/234 ,  C10L10/14 ,  F02B3/06

CPC classification number: C10L1/2225 ,  F02B3/06

Abstract: The incorporation of minor amounts of an additive prepared from the reaction products of a long chain oligomeric alkylsuccinic anhydride or the corresponding acid, a mono or polyfunctional epoxide and a long chain secondary amine provide improved cloud point, pour point and filterability for diesel and heating fuels.

公开(公告)号：US4711734A

公开(公告)日：1987-12-08

申请号：US409262

申请日：1982-08-18

Applicant: Takeshi Fujita ,  Hironori Kataoka

Inventor： Takeshi Fujita ,  Hironori Kataoka

IPC: C11D1/72 ,  B01F17/00 ,  B01F17/42 ,  C09D7/00 ,  C09D7/12 ,  C10L1/12 ,  C10L1/192 ,  C10L1/198 ,  C10L10/18 ,  C10M159/12 ,  C10M161/00 ,  C10N20/04 ,  C10N30/00 ,  C10N30/04 ,  C10M129/16 ,  C10M129/18

CPC classification number: B01F17/0028 ,  B01F17/0092

Abstract: Uniform dispersions of oil insoluble substances in the oil phase are produced employing as an oil-miscible dispersing agent, a reaction product of a compound having a molecular weight of at least 1,000 and being represented by the formula:R.sup.1 [(OCH.sub.2 CH.sub.2).sub.x OH].sub.y (I)wherein R.sup.1 is an organic bridging group, x is an integer greater than 1, and y is an integer from 2 to 8, and a compound of the formula: ##STR1## wherein R.sup.2 is a C.sub.6 -C.sub.40 alkyl or phenyl, the molar ratio of compound (II) to compound (I) being at least 1 alone or a mixture thereof with 10-90% by weight of the mixture of a lanolin fatty acid ester.

Abstract translation: 使用油混溶性分散剂，分子量至少为1,000的化合物和由下式表示的化合物R1 [（OCH2CH2）x OH]表示的油相中的油不溶性物质的均匀分散体， y（I）其中R 1是有机桥基，x是大于1的整数，y是2至8的整数，以及下式的化合物：其中R 2是C 6 -C 40 烷基或苯基，化合物（II）与化合物（I）的摩尔比单独为至少1或其混合物与10-90重量％的羊毛脂脂肪酸酯的混合物。

公开(公告)号：US4569679A

公开(公告)日：1986-02-11

申请号：US588645

申请日：1984-03-12

Applicant: Albert Rossi

Inventor： Albert Rossi

IPC: C10L1/18 ,  C10L1/14 ,  C10L1/183 ,  C10L1/188 ,  C10L1/192 ,  C10L1/195 ,  C10L1/22 ,  C10L1/224 ,  C10L1/26

CPC classification number: C10L1/143 ,  C10L1/183 ,  C10L1/188 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/224 ,  C10L1/2383 ,  C10L1/2641

Abstract: An additive concentrate for incorporation into wax containing petroleum fuel oil compositions to improve low temperature flow properties comprising an oil solution containing:(A) a C.sub.30 -C.sub.300 oil-soluble nitrogen salt and/or amide compound wax crystal growth inhibitor formed by reaction of alicyclic C.sub.4 to C.sub.10 carboxylic acid and long chain secondary amine;(B) an organic acid to improve the solubility of (A) in the oil, which acid includes non-linear carboxylic acids including branched or unsaturated fatty acids, aromatic acids, e.g. benzoic acid, phenols, and organic phosphorus containing acids; and(C) a copolymer of ethylene and an unsaturated ester, e.g. vinyl acetate.

Abstract translation: 一种用于掺入含蜡石油燃料油组合物以提高低温流动性的添加剂浓缩物，其包含油溶液，其包含：（A）C30-C300油溶性氮盐和/或酰胺化合物蜡晶体生长抑制剂，其通过脂环族 C4至C10羧酸和长链仲胺; （B）有机酸，以改善（A）在油中的溶解度，该酸包括包括支链或不饱和脂肪酸在内的非线性羧酸，芳香族酸等。 苯甲酸，酚类和含有机磷酸; 和（C）乙烯和不饱和酯的共聚物，例如 乙酸乙烯酯

公开(公告)号：US4491455A

公开(公告)日：1985-01-01

申请号：US420647

申请日：1982-09-21

Applicant: Takaharu Ishizaki ,  Takeshi Nagai ,  Shingo Yamazaki

Inventor： Takaharu Ishizaki ,  Takeshi Nagai ,  Shingo Yamazaki

IPC: C10L1/22 ,  C10L1/14 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/222 ,  C10L1/224 ,  C10L10/16

CPC classification number: C10L1/2225 ,  C10L1/143 ,  C10L1/224 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973

Abstract: The cold flow of fuel oils is improved by adding esters of nitrogen-containing compounds having polyhydroxyl groups with linear saturated fatty acids or a combination of said esters and polymers of one or more monomers selected from the group consisting of olefins, alkyl esters of ethylenically unsaturated carboxylic acids and vinyl esters of saturated fatty acids to fuel oils.

Abstract translation: 燃料油的冷流通过加入具有多羟基的含氮化合物的酯与线性饱和脂肪酸或所述一种或多种选自以下的单体的酯和聚合物的组合来改善：烯烃，烯属不饱和的烷基酯 饱和脂肪酸的羧酸和乙烯基酯与燃料油。

公开(公告)号：US4334891A

公开(公告)日：1982-06-15

申请号：US270813

申请日：1981-06-05

Applicant: Herbert Brooks ,  Frederick A. Waite

Inventor： Herbert Brooks ,  Frederick A. Waite

IPC: C10L1/192 ,  C08J3/11 ,  C10L1/14 ,  C10L1/18 ,  C10L1/196 ,  C10L1/22

CPC classification number: C08J3/11 ,  C10L1/143 ,  C08J2325/16 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/232 ,  C10L1/233 ,  C10L1/2362

Abstract: Specified copolymers of tert-butylstyrene are dissolved in a liquid aliphatic hydrocarbon fuel, especially an aircraft fuel, by the steps of (i) blending the finely-divided copolymer with a non-solvent hydroxylic liquid miscible with the fuel, (ii) mixing the blend into the fuel so as to give a copolymer concentration of 01.-1% by weight, and (iii) dissolving in the fuel so treated an amino compound in an amount of 0.01-0.6 mole per 100 g of copolymer present. The copolymers thus dissolved impart to the fuel a resistance towards mist formation when the fuel is subjected to conditions of shock.