公开(公告)号：US20070142683A1

公开(公告)日：2007-06-21

申请号：US11670339

申请日：2007-02-01

Applicant: Andrea FRENZEL ,  Michael Hesse ,  Andreas Ansmann ,  Ekkehard Schwab

Inventor： Andrea FRENZEL ,  Michael Hesse ,  Andreas Ansmann ,  Ekkehard Schwab

IPC: C07C7/167 ,  C07C5/08

CPC classification number: C07C7/163 ,  B01J23/48 ,  B01J23/50 ,  B01J23/66 ,  B01J35/0006 ,  C07C7/167 ,  C07C2521/08 ,  C07C2523/44 ,  C07C2523/50 ,  C07C11/02

Abstract: A catalyst for the selective hydrogenation of alkynes and dienes in C2-C5+-olefin mixtures is described. These catalysts contain (a) a metal of the tenth group of the Periodic Table, (b) a metal of the eleventh group of the Periodic Table and (c) if required, a compound of a metal of the first or second group of the Periodic Table, these metals being applied to a support which is selected from the group consisting of silica, titanium dioxide, zirconium oxides, spinels, zinc aluminates, zinc titanates or mixtures of these substances, and the metal of the eleventh group being distributed homogeneously over the cross section of the catalyst particle and the metal of the tenth group being present in the edge layer close to the surface of the catalyst particle. Such a catalyst is prepared by applying the metal of the eleventh group, preferably during the preparation of the support itself, by impregnation with a solution of a suitable metal salt.

Abstract translation: 描述了用于C2-C5 + - 烯烃混合物中炔和二烯的选择性氢化的催化剂。 这些催化剂含有（a）元素周期表第十组的金属，（b）元素周期表第十一组的金属和（c）如果需要，可以使用第一组或第二组的金属化合物 周期表中，这些金属被施加到选自二氧化硅，二氧化钛，氧化锆，尖晶石，铝酸锌，钛酸锌或这些物质的混合物的载体上，并且第十一基团的金属均匀地分布在 催化剂颗粒的横截面和第十组的金属存在于靠近催化剂颗粒表面的边缘层中。 这样的催化剂是通过施加第十一基团的金属，优选在制备载体本身期间通过用合适的金属盐的溶液浸渍来制备的。

公开(公告)号：US07115781B2

公开(公告)日：2006-10-03

申请号：US10493504

申请日：2002-10-18

Applicant: Andreas Ansmann ,  Christoph Benisch ,  Peter Bassler ,  Rolf-Hartmuth Fischer ,  Stefan Maixner ,  Johann-Peter Melder ,  Hermann Luyken

Inventor： Andreas Ansmann ,  Christoph Benisch ,  Peter Bassler ,  Rolf-Hartmuth Fischer ,  Stefan Maixner ,  Johann-Peter Melder ,  Hermann Luyken

IPC: C07C209/62

CPC classification number: B01J23/745

Abstract: An oxidic composition which is suitable as a catalyst having divalent and trivalent iron in an atomic ratio of divalent to trivalent iron in the range from greater than 0.5 to 5.5 and oxygen as a counterion to the divalent and trivalent iron. The catalyst composition is useful in the hydrogenation of nitriles to amines.

Abstract translation: 适合作为具有二价和三价铁的二价和三价铁的氧化组合物，其二价至三价铁的原子比在大于0.5至5.5的范围内，氧与二价和三价铁的相反。 催化剂组合物可用于将腈氢化成胺。

公开(公告)号：US06686465B2

公开(公告)日：2004-02-03

申请号：US10258943

申请日：2002-10-29

Applicant: Frank Ohlbach ,  Andreas Ansmann ,  Peter Bassler ,  Rolf-Hartmuth Fischer ,  Hermann Luyken ,  Stefan Maixner ,  Johann-Peter Melder

Inventor： Frank Ohlbach ,  Andreas Ansmann ,  Peter Bassler ,  Rolf-Hartmuth Fischer ,  Hermann Luyken ,  Stefan Maixner ,  Johann-Peter Melder

IPC: C07D20108

CPC classification number: C07D201/08

Abstract: A process is provided for the preparation of cyclic lactams of formula (II): in which n and m can each have the values 0, 1, 2, 3, 4, 5, 6, 7, 8 and 9 and the sum of n+m is at least 3, preferably at least 4, and R1 and R2 are C1-C6-alkyl, C5-C7-cycloalkyl or C6-C12-aryl groups, by reacting a compound (I) of the formula in which R1, R2, m and n are as defined above and R are [sic] nitrile, carboxamide and carboxylic acid groups, with steam in the gas phase.

Abstract translation: 提供了制备式（II）的环状内酰胺的方法：其中n和m各自可以具有0,1,2,3,4,5,6,7,8和9以及n + m为至少3，优选至少4，R 1和R 2为C 1 -C 6 - 烷基，C 5 -C 7 - 环烷基或C 6 -C 12 - 芳基，通过使 R 1，R 2，m和n如上所定义，R是具有气相中蒸汽的[sic]腈，甲酰胺和羧酸基团的甲醛。

公开(公告)号：US06683180B2

公开(公告)日：2004-01-27

申请号：US10297209

申请日：2002-12-04

Applicant: Frank Ohlbach ,  Andreas Ansmann ,  Rolf-Hartmuth Fischer ,  Johann-Peter Melder

Inventor： Frank Ohlbach ,  Andreas Ansmann ,  Rolf-Hartmuth Fischer ,  Johann-Peter Melder

IPC: C07D20108

CPC classification number: C07D201/08 ,  Y02P20/52

Abstract: A process is provided for the preparation of caprolactam from a compound of formula (I): NC—(CH2)5—CO—R  (I) in which R is a carboxamide, carboxylic acid or carboxylic acid ester group, wherein a) a compound (I) or a mixture of such compounds, in the presence of ammonia and optionally a liquid diluent (VI), is hydrogenated with hydrogen in the presence of a catalyst (II) to give a mixture (III), b) the hydrogen and the catalyst (II) are separated from the mixture (III) to give a mixture (IV), and c) the mixture (IV), optionally in the presence of a liquid diluent (VII), is converted to caprolactam in the presence of a catalyst (V).

Abstract translation: 提供了从式（I）化合物制备己内酰胺的方法：其中R是羧酰胺，羧酸或羧酸酯基，其中a）化合物（I）或这些化合物的混合物，在存在下 的氨和任选的液体稀释剂（VI）在催化剂（II）的存在下用氢氢化，得到混合物（III），b）将氢气和催化剂（II）从混合物（III）中分离出来， 任选在液体稀释剂（VII）的存在下，将混合物（IV）和（c）混合物（IV）在催化剂（V）的存在下转化成己内酰胺。

公开(公告)号：US06677486B2

公开(公告)日：2004-01-13

申请号：US09985982

申请日：2001-11-07

Applicant: Andreas Ansmann ,  Christoph Benisch ,  Frank Funke ,  Frank Ohlbach ,  Martin Merger

Inventor： Andreas Ansmann ,  Christoph Benisch ,  Frank Funke ,  Frank Ohlbach ,  Martin Merger

IPC: C07C2948

CPC classification number: C07D295/13 ,  B01J25/00 ,  B01J37/0018 ,  C07C209/48 ,  C07C211/14 ,  C07C211/36

Abstract: Nitriles are hydrogenated to primary amines over an activated, alpha-Al2O3-containing, macroporous Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, which is obtainable by a process comprising the steps in the order (a)-(f): (a) preparing a kneadable composition comprising the alloy, a shaping aid, water and a pore former; (b) shaping the kneadable composition to form a shaped body; (c) calcining the shaped body; (d) activating the calcined shaped body by treatment with aqueous alkali metal hydroxide solution; (e) rinsing the shaped catalyst body with aqueous alkali metal hydroxide solution; (f) rinsing the shaped catalyst body with water.

Abstract translation: 基于铝和至少一种选自铁，钴和镍的过渡金属的合金，并且如果需要，腈在一种活化的含α-Al 2 O 3的大孔阮内催化剂上氢化成伯胺，如果需要， （a） - （f）：（a）制备包含该合金的可捏合组合物的方法可以获得更多的选自钛，锆，铬和锰的过渡金属， 成型助剂，水和成孔剂;（b）使捏合组合物成形以形成成形体;（c）煅烧成形体;（d）用碱金属氢氧化物水溶液处理活化煅烧成形体;（e） 用碱金属氢氧化物水溶液冲洗成型的催化剂体;（f）用水冲洗成型的催化剂体。

公开(公告)号：US06407230B1

公开(公告)日：2002-06-18

申请号：US09646153

申请日：2000-09-14

Applicant: Matthias Eiermann ,  Andreas Ansmann ,  Klemens Flick

Inventor： Matthias Eiermann ,  Andreas Ansmann ,  Klemens Flick

IPC: C07D20108

CPC classification number: C07D277/32 ,  B01J27/1804 ,  C07D213/61

Abstract: A process for preparing lactams by hydrolytic cyclization of aminonitriles in the gas phase in the presence of a metal phosphate catalyst comprises using a catalyst comprising one or more oligophosphates of the general formula (I) M (POa)b  (I) where M is a metal of group 3 or 4 of the periodic table, including the lanthanides, a is >2.5 and

Abstract translation: 在金属磷酸盐催化剂的存在下，通过在气相中水解环化氨基腈制备内酰胺的方法包括使用包含一种或多种通式（I）的低聚磷酸酯的催化剂，其中M是第三或第四族的金属 周期表，包括镧系元素，a为> 2.5和<4.0，b为使得电中性得到确保，或者一种或多种通式（I）的低磷酸盐与一种或多种其它金属的另外的盐的混合物 元素周期表的第3或第4族，包括镧系元素，与无机酸。

公开(公告)号：US06359178B1

公开(公告)日：2002-03-19

申请号：US09762798

申请日：2001-02-13

Applicant: Rolf Fischer ,  Peter Bassler ,  Hermann Luyken ,  Frank Ohlbach ,  Johann-Peter Melder ,  Martin Merger ,  Andreas Ansmann ,  Alwin Rehfinger ,  Guido Voit

Inventor： Rolf Fischer ,  Peter Bassler ,  Hermann Luyken ,  Frank Ohlbach ,  Johann-Peter Melder ,  Martin Merger ,  Andreas Ansmann ,  Alwin Rehfinger ,  Guido Voit

IPC: C07C20948

CPC classification number: C07C209/48 ,  C07C211/12

Abstract: A process for catalytic hydrogenation of adiponitrile to hexamethylenediamine at elevated temperature and elevated pressure in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent comprises a) hydrogenating adiponitrile at from 70 to 220° C. and from 100 to 400 bar in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent to obtain a mixture comprising adiponitrile, 6-aminocapronitrile, hexamethylenediamine and high boilers until the sum total of the 6-aminocapronitrile concentration and the adiponitrile concentration is within the range from 1 to 50% by weight, based on the ammonia-free hydrogenation mixture, b) removing ammonia from the hydrogenation effluent, c) removing hexamethylenediamine from the remaining mixture, d) separating 6-aminocapronitrile and adiponitrile from high boilers individually or together, and e) returning 6-aminocapronitrile, adiponitrile or mixtures thereof into step a).

Abstract translation: 在基于作为催化活性组分的元素铁和作为溶剂的氨的催化剂存在下，在升高的温度和升高的压力下将己二腈催化氢化为己二胺的方法包括在70-220℃和100-400巴下氢化己二腈 在基于作为催化活性成分的元素铁和作为溶剂的氨的催化剂存在下，得到包含己二腈，6-氨基己腈，六亚甲基二胺和高沸点剂的混合物，直到6-氨基己腈浓度和己二腈浓度的总和在范围内 基于无氨氢化混合物，从1至50重量％，b）从氢化流出物中除去氨，c）从剩余的混合物中除去六亚甲基二胺，d）分别或一起从高锅炉中分离6-氨基己腈和己二腈， 和），返回6-氨基己腈，己二腈或其混合物 n步骤a）。