公开(公告)号：US20140066290A1

公开(公告)日：2014-03-06

申请号：US14113758

申请日：2012-04-27

Applicant: Nobuyoshi Koshino ,  Hideyuki Higashimura

Inventor： Nobuyoshi Koshino ,  Hideyuki Higashimura

IPC: H01M4/90 ,  H01M12/08

CPC classification number: H01M4/9008 ,  C07D241/12 ,  C07D257/10 ,  C07D259/00 ,  C07D471/04 ,  C07D471/18 ,  C07D471/22 ,  C07D487/16 ,  C07D487/22 ,  C07D498/22 ,  C07D519/00 ,  H01M12/08 ,  Y02E60/128

Abstract: The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

Abstract translation: 本发明提供一种具有优异的氧还原活性和优异的水氧化活性的空气二次电池用阴极催化剂和使用该催化剂的空气二次电池。 本发明涉及一种空气二次电池用催化剂含有多核金属络合物的阴极催化剂。

公开(公告)号：US20140001422A1

公开(公告)日：2014-01-02

申请号：US14005099

申请日：2012-03-15

Applicant: Takayuki Iijima ,  Hideyuki Higashimura

Inventor： Takayuki Iijima ,  Hideyuki Higashimura

IPC: H01B1/12 ,  H01B1/02

CPC classification number: H01B1/121 ,  B22F1/0003 ,  B22F1/02 ,  C08G2261/91 ,  C08G2261/95 ,  C08K3/08 ,  C22C5/06 ,  H01B1/02 ,  H01B1/22 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/5076 ,  C08K5/098 ,  C08L65/00

Abstract: A composition of a silver-conjugated compound composite containing (1) a silver-conjugated compound composite containing a silver particle with a Feret diameter of 1,000 nm or less and a conjugated compound having a weight average molecular weight of 3.0×102 or more being adsorbed to the silver particles and (2) an ionic compound. The ionic compound may be a compound having a structure represented by the following Formula (hh-1): [Chem. 1] Mm′+aX′n′−b  (hh-1) wherein Mm′+ represents a metal cation, X′n′− represents an anion, a and b each independently represent an integer of 1 or more, and when Mm′+ and X′n′− are each plurally present, they may be the same as or different from each other.

Abstract translation: 含有（1）含有Feret直径为1000nm以下的银粒子和重均分子量为3.0×102以上的共轭化合物被吸附的银共轭化合物复合体的组合物 银粒子和（2）离子化合物。 离子化合物可以是具有由下式（hh-1）表示的结构的化合物：[Chem。 1] Mm'+ aX'n'-b（hh-1）其中Mm'+表示金属阳离子，X'n'-表示阴离子，a和b各自独立地表示1以上的整数，当Mm '+和X'n'各自存在，它们可以彼此相同或不同。

公开(公告)号：US20130341571A1

公开(公告)日：2013-12-26

申请号：US14004003

申请日：2012-03-15

Applicant: Takayuki Iijima ,  Hideyuki Higashimura

Inventor： Takayuki Iijima ,  Hideyuki Higashimura

IPC: H01B1/02

CPC classification number: H01B1/02 ,  B22F1/0003 ,  C08G61/02 ,  C08G61/12 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/152 ,  C08G2261/3142 ,  C08G2261/91 ,  C08G2261/95 ,  C08K3/08 ,  C08K2201/016 ,  C22C5/06 ,  H01B1/121 ,  H01B1/22 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/0043 ,  Y02E10/549 ,  C08K5/098 ,  C08L65/00

Abstract: A metallic composite composition containing: a metallic composite in which a conjugated compound having a molecular weight of 200 or more is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, and an ionic compound, with the proviso that when the ionic compound is a conjugated compound, the ionic compound is a conjugated compound having a molecular weight of less than 200. A mixture containing the metallic composite composition and a conjugated compound having a molecular weight of 200 or more. The ionic compound may be a compound having a structure represented by Formula (hh-1) below: [Chem. 1] Mm′+aX′n′−b  (hh-1) wherein Mm′+ represents a metal cation, X′n′− represents an anion, a and b each independently represent an integer of 1 or more, and when each of Mm′+ and X′n′− is plurally present, they each may be the same as or different from each other.

Abstract translation: 一种金属复合组合物，其含有金属复合体，其中分子量为200以上的共轭化合物吸附在纵横比为1.5以上的金属纳米结构体和离子性化合物上，条件是当离子化合物 是共轭化合物，离子化合物是分子量小于200的共轭化合物。含有金属复合组合物和分子量为200以上的共轭化合物的混合物。 离子性化合物可以是具有由下式（hh-1）表示的结构的化合物：[Chem。 1] Mm'+ aX'n'-b（hh-1）其中Mm'+表示金属阳离子，X'n'-表示阴离子，a和b各自独立地表示1以上的整数， 的M''和X'n'是多个存在的，它们各自可以彼此相同或不同。

公开(公告)号：US08519131B2

公开(公告)日：2013-08-27

申请号：US12530174

申请日：2008-03-10

Applicant: Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Hiroshi Hamamatsu

Inventor： Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Hiroshi Hamamatsu

IPC: C07F15/06 ,  B01J31/12

CPC classification number: C07D213/30 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/223 ,  B01J2531/0252 ,  B01J2531/16 ,  B01J2531/56 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  C07D471/04

Abstract: A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.

Abstract translation: 一种改性金属络合物，其通过使含有含有一个含氮芳族杂环的有机化合物和四种或更多种酚，苯硫酚，苯胺或含氮芳族杂环的结构的金属络合物或具有两个或多个酚环的有机化合物 在其分子中含有3个以上的含氮芳香族杂环作为配体，进行加热，放射线照射或放电处理，直到处理后的质量降低率为1〜90质量％，由此，复合物显示出碳后的碳含量 治疗5％以上。

公开(公告)号：US08349997B2

公开(公告)日：2013-01-08

申请号：US12526747

申请日：2008-02-14

Applicant: Tsutomu Yokozawa ,  Hideyuki Higashimura ,  Tomohisa Temma

Inventor： Tsutomu Yokozawa ,  Hideyuki Higashimura ,  Tomohisa Temma

IPC: C08G75/00

CPC classification number: C08G61/126 ,  C08G61/02 ,  C08G61/12 ,  C08G61/124 ,  C08G2261/126 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/411 ,  C08G2261/417 ,  C09K11/06 ,  C09K2211/14 ,  H01L51/0039 ,  H01L51/0043

Abstract: Disclosed is a method for producing a block copolymer which comprises two or more blocks composed of aromatic units having different basic structures from each other and has a high molecular weight, a narrow chain length distribution and a narrow molecular weight distribution. Also disclosed is a block copolymer produced by the method. The method for producing a block copolymer comprises the step of sequentially reacting two or more aromatic compounds which are selected from aromatic compounds represented by a specific general formula and are different in the group Ar, in the presence of a nickel complex containing a phosphine compound represented by a specific general formula or a palladium complex containing a phosphine compound represented by a specific general formula to thereby form blocks comprising the aromatic compounds sequentially, wherein the two or more aromatic compounds are reacted in descending order of parameter of aromatic ring charge.

Abstract translation: 公开了一种嵌段共聚物的制造方法，其包含两个以上由具有不同碱性结构的芳香族单元构成的嵌段，具有高分子量，窄链长分布和窄分子量分布。 还公开了通过该方法制备的嵌段共聚物。 嵌段共聚物的制造方法包括在含有表示的膦化合物的镍配合物的存在下，使两种以上选自由特定通式表示的芳香族化合物与Ar组不同的芳香族化合物反应的工序 通过具体通式或含有由特定通式表示的膦化合物的钯络合物，从而依次形成包含芳香族化合物的嵌段，其中两个或更多个芳香族化合物以芳环电荷参数的降序进行反应。

公开(公告)号：US08329929B2

公开(公告)日：2012-12-11

申请号：US12530413

申请日：2008-03-10

Applicant: Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

Inventor： Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

IPC: C07F15/00 ,  C07F1/08 ,  C07F5/06 ,  C07F7/00

CPC classification number: C07D213/30 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/2243 ,  B01J2531/0252 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/84 ,  C07D409/14 ,  C07D471/04 ,  C08F110/02 ,  C08F110/06

Abstract: A metal complex represented by the following formula (1): wherein R1 to R6 each independently represent a hydrogen atom or a substituent; Y1 and Y2 each independently represent any one of the following groups: wherein Rα represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; P1 and P2 each represent a group of atoms necessary for forming a heterocyclic ring together with Y1 or Y2 and the two carbon atoms at a position adjacent to Y1 or Y2; P1 and P2 may be linked to each other to form a ring; M represents a transition metal element or typical metal element; m represents 1 or 2; X represents a counter ion or a neutral molecule; n represents the number of X's in the complex, and an integer of 0 or more; and Q1 and Q2 each independently represent an aromatic heterocyclic group.

Abstract translation: 由下式（1）表示的金属络合物：其中R 1至R 6各自独立地表示氢原子或取代基; Y1和Y2各自独立地表示以下基团中的任一个：其中Rα表示氢原子或具有1至4个碳原子的烃基; P1和P2各自表示与Y1或Y2一起形成杂环所需的一组原子，在与Y1或Y2相邻的位置上的两个碳原子; P1和P2可以彼此连接以形成环; M表示过渡金属元素或典型的金属元素; m表示1或2; X表示抗衡离子或中性分子; n表示复合物中X的数目，0以上的整数; 并且Q1和Q2各自独立地表示芳族杂环基。

公开(公告)号：US20120211706A1

公开(公告)日：2012-08-23

申请号：US13504275

申请日：2010-10-25

Applicant: Yusuke Kuramochi ,  Takeshi Ishiyama ,  Hideyuki Higashimura

Inventor： Yusuke Kuramochi ,  Takeshi Ishiyama ,  Hideyuki Higashimura

IPC: C07F5/00 ,  H01B1/12

CPC classification number: C07D233/64 ,  C07D235/14 ,  C07D417/12 ,  C07F5/003 ,  C07F5/022 ,  C07F9/65583 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1044

Abstract: The present invention provides a metal complex that has excellent durability, and a device and the like having excellent durability that uses such a metal complex. Specifically, the present invention provides a metal complex comprising (a) a polydentate ligand having denticity of five or more that includes a heteroaromatic ring which contains two or more atoms selected from the group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom, and (b) an ion of a metal selected from the group consisting of cerium, praseodymium, ytterbium, and lutetium; a composition comprising the metal complex and a charge transport material; an organic thin film obtained by using the metal complex or composition; and a device obtained by using the metal complex, composition, or organic thin film.

Abstract translation: 本发明提供了耐久性优异的金属络合物和使用这种金属络合物的耐久性优良的装置等。 具体地说，本发明提供一种金属配合物，其特征在于，具有（a）具有5以上的牙齿的多齿配体，所述多齿配体包括含有选自氮原子，氧原子和硫原子中的2个以上的原子的杂芳香环 原子，和（b）选自铈，镨，镱和镥的金属离子; 包含金属络合物和电荷输送材料的组合物; 通过使用金属络合物或组合物获得的有机薄膜; 以及通过使用金属络合物，组合物或有机薄膜获得的器件。

公开(公告)号：US20120049167A1

公开(公告)日：2012-03-01

申请号：US13145718

申请日：2010-01-21

Applicant: Yusuke Kuramochi ,  Norifumi Kobayashi ,  Hideyuki Higashimura

Inventor： Yusuke Kuramochi ,  Norifumi Kobayashi ,  Hideyuki Higashimura

IPC: H01L51/54 ,  C08F26/06

CPC classification number: C07D213/18 ,  C07D233/58 ,  C08G61/02 ,  C08G61/10 ,  C08G61/12 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08G2261/5242 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1466 ,  C09K2211/188 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/004 ,  H01L51/0091 ,  H01L51/5012 ,  H05B33/14

Abstract: An organic electroluminescent device in which an organic layer containing a metal coordination compound represented by the following formula (1) is sandwiched between the pair of electrodes composed of an anode and a cathode, MLaXb  (1) wherein M is an ion of a metal of Group 11 of the Periodic Table, L is a ligand represented by the formula (2) shown below, X is an anion, and a and b are defined in the specification, wherein A is a divalent group formed by removing two hydrogen atoms from the formula (3) or (4) shown below, and D1, k1, m1, A, D1, Q1, and Q2 are defined in the specification, wherein X1, X2, X3, X4, X5, R1, R5, R6, and R9 are defined in the specification.

Abstract translation: 一种有机电致发光器件，其中含有由下式（1）表示的金属配位化合物的有机层夹在由阳极和阴极组成的一对电极之间，MLaXb（1）其中M是金属的离子 L是由下述式（2）表示的配体，X是阴离子，a和b在本说明书中定义，其中A是通过除去二个氢原子而形成的二价基团 在本说明书中定义了D1，k1，m1，A，D1，Q1和Q2，其中X1，X2，X3，X4，X5，R1，R5，R6和 R9在本说明书中定义。

公开(公告)号：US20120021897A1

公开(公告)日：2012-01-26

申请号：US13202858

申请日：2010-02-19

Applicant: Masatoshi Iwata ,  Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

Inventor： Masatoshi Iwata ,  Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura

IPC: B01J31/22 ,  C07F15/06 ,  C07D487/22 ,  C07F1/08 ,  C07F3/06 ,  C07D471/22 ,  C07D498/22 ,  C07F15/04

CPC classification number: C07D471/22 ,  B01J31/2243 ,  B01J2231/70 ,  B01J2531/0216 ,  B01J2531/0241 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/845 ,  B01J2531/847 ,  C07D487/22 ,  C07D498/22 ,  C07D513/22 ,  H01L51/0083 ,  H01L51/009 ,  H01L51/0091 ,  H01L51/0092 ,  H01M4/9008

Abstract: A compound represented by the following formula (1): wherein, Y1, Y2, Y3 and Y4 represent a group represented by any of the above formulae; P1, P2, P3 and P4 are an atomic group required for forming an aromatic heterocyclic ring; P5 and P6 are an atomic group required for forming an aromatic ring; Z1 and Z2 represent ORα, —SRα or —NRα2, wherein Rα represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; Q1 and Q2 represent a direct bond or a linking group; a P1-containing ring and a P2-containing ring are bonded to form Q1-containing fused structure; a P3-containing ring and a P4-containing ring are bonded to form Q2-containing fused structure; can be used as a ligand of a metal complex, and the metal complex is useful for a catalyst.

Abstract translation: 由下式（1）表示的化合物：其中，Y1，Y2，Y3和Y4表示由上述任何一个表示的基团; P1，P2，P3和P4是形成芳族杂环所需的原子团; P5和P6是形成芳环所需的原子团; Z1和Z2表示ORα，-SRα或-NRα2，其中Rα表示氢原子或具有1至4个碳原子的烷基; Q1和Q2表示直接键或连接基团; 键合含有P1的环和含有P2的环，形成含有Q1的稠合结构; 键合含有P3的环和含有P4的环，形成含有Q2的稠合结构; 可以用作金属络合物的配体，并且金属络合物可用于催化剂。

公开(公告)号：US20100219399A1

公开(公告)日：2010-09-02

申请号：US12159143

申请日：2006-12-25

Applicant: Daisuke Fukushima ,  Hideyuki Higashimura ,  Akihiko Okada ,  Kazuei Ohuchi ,  Makoto Anryu

Inventor： Daisuke Fukushima ,  Hideyuki Higashimura ,  Akihiko Okada ,  Kazuei Ohuchi ,  Makoto Anryu

IPC: H01L51/54 ,  C08G79/08 ,  C08L85/04 ,  B05D5/00

CPC classification number: C08L53/00 ,  C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  C08G61/124 ,  C08G61/125 ,  C08G61/126 ,  C09K11/06 ,  C09K2211/14 ,  H01L51/0026 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0043 ,  H01L2251/308 ,  H05B33/14 ,  C08L2666/02

Abstract: A block copolymer comprising two or more of blocks of the following formula (1), wherein at least two of a plurality of m's present in the copolymer represent a number of 5 or more, Ar's in adjacent two blocks in the copolymer are mutually different, and the copolymer has two Ar's when composed of 2 blocks of the formula (1), has two or more Ar's when composed of 3 blocks of the formula (1) and has four or more Ar's when composed of 4 or more blocks of the formula (1): (in the formula (1), Ar represents a conjugative divalent group and represents the same divalent group in an identical block, and m represents a number of 1 or more showing the number average polymerization degree of Ar present in one block.).

Abstract translation: 包含两个或更多个下式（1）的嵌段的嵌段共聚物，其中共聚物中存在的多个m中的至少两个表示5个或更多个，共聚物中相邻的两个嵌段中的Ar相互不同， 并且当由2个式（1）的嵌段组成时，该共聚物具有两个Ar，当由3个式（1）的嵌段组成时具有两个或更多个Ar，并且当由4个或更多个式 （1）表示（式（1）中，Ar表示共轭二价基，在同一嵌段中表示相同的二价基，m表示一个嵌段中存在Ar的数均聚合度的1以上的数 。）。