公开(公告)号：US20090294731A1

公开(公告)日：2009-12-03

申请号：US12542164

申请日：2009-08-17

Applicant: Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

Inventor： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC: C09K11/08

CPC classification number: C09K11/7734 ,  C09K11/7737 ,  H01L33/502

Abstract: Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+cations; A2 is a 3+, 4+, or 5+cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1-, 2-, or 3-anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

Abstract translation: 公开了新的绿色荧光体，其包含具有式（Sr，Al）x（Si，A2）（O，A3）2 + x：Eu 2+）的硅酸盐基化合物，其中A1是至少一个二价阳离子 ），包括Mg，Ca，Ba或Zn，或1+ + 3 +阳离子的组合; A2是3+，4+或5 +阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US07575697B2

公开(公告)日：2009-08-18

申请号：US11269953

申请日：2005-11-08

Applicant: Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

Inventor： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC: C09K11/59 ,  C09K11/55 ,  H01L51/54 ,  H01J17/49

CPC classification number: C09K11/7734 ,  C09K11/7737 ,  H01L33/502

Abstract: Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

Abstract translation: 公开了新的绿色荧光体，其包含具有式（Sr，Al）x（Si，A2）（O，A3）2 + x：Eu 2+）的硅酸盐基化合物，其中A1是至少一个二价阳离子 ），包括Mg，Ca，Ba或Zn，或1+和3+阳离子的组合; A2是3+，4+或5+阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US20080197290A1

公开(公告)日：2008-08-21

申请号：US11999729

申请日：2007-12-06

Applicant: Xianglong Yuan ,  Shifan Cheng ,  Yi-Qun Li

Inventor： Xianglong Yuan ,  Shifan Cheng ,  Yi-Qun Li

IPC: G01T1/20

CPC classification number: G01T1/2018

Abstract: Disclosed herein are camera-based x-ray digital image detectors that contain an assembly of a scintillator screen, a wide-angle optical lens or fisheye lens, and a digital image sensor. Images formed by x-ray radiation on the scintillator screen are projected onto a much smaller area image sensor through a fisheye or super-wide-angle optical lens, hence forming a highly distorted image thereon. Transparent lead-contained glasses or plastics are utilized to shield image sensor from x-ray damage. Imaging distortion and light falloff caused by the lens optics are corrected by software algorithms. Sub-millimeter resolution may be achieved with reduced design complexity and substantially lower manufacturing costs.

Abstract translation: 本文公开了包含闪烁体屏幕，广角光学透镜或鱼眼镜头和数字图像传感器的组件的基于摄像机的X射线数字图像检测器。 通过X射线辐射在闪烁体屏幕上形成的图像通过鱼眼或超广角光学透镜投影到更小的区域图像传感器上，从而在其上形成高度失真的图像。 使用透明的含铅玻璃或塑料来屏蔽图像传感器免受x射线损伤。 由镜头光学造成的成像失真和光衰减由软件算法进行校正。 可以实现亚毫米分辨率，降低设计复杂度并显着降低制造成本。

公开(公告)号：US07399428B2

公开(公告)日：2008-07-15

申请号：US11061979

申请日：2005-02-18

Applicant: Yi-Qun Li ,  Shifan Cheng ,  Ning Wang ,  Yi Dong ,  Xiao-Dong Sun

Inventor： Yi-Qun Li ,  Shifan Cheng ,  Ning Wang ,  Yi Dong ,  Xiao-Dong Sun

IPC: C09K11/82

CPC classification number: C09K11/628 ,  C09K11/682 ,  C09K11/7708 ,  C09K11/7771 ,  C30B15/00 ,  C30B29/30 ,  G21K4/00

Abstract: Embodiments of the present invention are directed to compositions and processing methods of rare-earth vanadate based materials that have high emission efficiency in a wavelength range of 480 to 700 nm with the maximum intensity at 535 nm (bright yellow) under UV, X-ray and other forms of high-energy irradiation. Embodiments of the present invention are directed to general chemical compositions of the form (Gd1-xAx)(V1-yBy)(O4-zCz), where A is selected from the group consisting of Bi, Tl, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, and Lu for 0

Abstract translation: 本发明的实施方案涉及在480nm至700nm的波长范围内具有高发射效率且在UV，X射线下具有最大强度为535nm（亮黄色）的稀土类钒酸盐基材料的组合物和加工方法 和其他形式的高能辐射。 本发明的实施方案涉及以下形式的一般化学组成：（1-x A 1 x X）（V 1 -Y B） 其中A选自由Bi，Tl，Y，La，Ce组成的组，其中A选自Bi，Y 1，Y 2，Z 3， Pr，Nd，Pm，Sm，Eu，Tb，Dy，Ho，Er，Tm，Yb和Lu为0

公开(公告)号：US20080138268A1

公开(公告)日：2008-06-12

申请号：US11975356

申请日：2007-10-18

Applicant: Dejie Tao ,  Yi-Qun Li ,  Shifan Cheng

Inventor： Dejie Tao ,  Yi-Qun Li ,  Shifan Cheng

IPC: C01F17/00

CPC classification number: C09K11/7774 ,  C09K11/777 ,  F21K9/64 ,  F21V9/30

Abstract: Disclosed herein are cerium doped, garnet phosphors emitting in the yellow region of the spectrum, and having the general formula (Y,A)3(Al,B)5(O,C)12:Ce3+, where A is Tb, Gd, Sm, La, Sr, Ba, Ca, and/or Mg, and substitutes for Y, B is Si, Ge, B, P, and/or Ga, and substitutes for Al, and C is F, Cl, N, and/or S, where C substitutes for O. Relative to a solid-state-reaction method, the instant co-precipitation methods provide a more homogeneous mixing environment to enhance the distribution of the Ce3+ activator in the YAG matrix. Such a uniform distribution has the benefit of an increased emission intensity. The primary particle size of the as-prepared phosphor is about 200 nm, with a narrow distribution.

Abstract translation: 本文公开了在光谱的黄色区域中发射的铈掺杂的石榴石磷光体，并具有通式（Y，A）3（Al，B）5（O ，C）12：Ce 3+其中A是Tb，Gd，Sm，La，Sr，Ba，Ca和/或Mg，并代替Y， B是Si，Ge，B，P和/或Ga，并代替Al，C是F，Cl，N和/或S，其中C代替O.相对于固态反应方法， 即时共沉淀法提供了更均匀的混合环境，以增强YAG基质中Ce 3+激活剂的分布。 这种均匀分布具有增加的发射强度的益处。 所制备的磷光体的一次粒径为约200nm，分布窄。

公开(公告)号：US20080018235A1

公开(公告)日：2008-01-24

申请号：US11804011

申请日：2007-05-15

Applicant: Ning Wang ,  Yi Dong ,  Shifan Cheng ,  Yi-Qun Li ,  Ravilisetty Rao

Inventor： Ning Wang ,  Yi Dong ,  Shifan Cheng ,  Yi-Qun Li ,  Ravilisetty Rao

IPC: H01J1/63 ,  C01F17/00

CPC classification number: C09K11/7734 ,  H01J1/63

Abstract: Novel aluminate-based green phosphors are disclosed having the formula M1-xEuxMg1-yMnyAlzO[(x+y)+3z/2]; where 0.1

Abstract translation: 公开了具有下式的新型铝酸盐基绿色荧光体：具有下式的M 1-x O x x 1 M y Y y / [（x + y）+ 3z / 2] 其中0.1

公开(公告)号：US20070065947A1

公开(公告)日：2007-03-22

申请号：US11231309

申请日：2005-09-19

Applicant: Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Yi-Qun Li

Inventor： Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Yi-Qun Li

IPC: G01N1/28 ,  G01N33/20 ,  G01N33/543

CPC classification number: B01J19/0046 ,  B01J2219/00315 ,  B01J2219/00364 ,  B01J2219/00369 ,  B01J2219/00387 ,  B01J2219/00477 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/005 ,  B01J2219/00527 ,  B01J2219/00572 ,  B01J2219/00585 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00619 ,  B01J2219/00621 ,  B01J2219/00628 ,  B01J2219/00659 ,  B01J2219/00704 ,  B01J2219/00736 ,  B01J2219/0075 ,  B01J2219/00754

Abstract: This invention provides methods and systems to prepare replicate arrays from master arrays of liquid solutions. Replicate arrays of liquid solutions can be reacted to form product solid inorganic material arrays for analysis and selection of optimum processes and products with desirable properties.

Abstract translation: 本发明提供从液体溶液的主阵列制备复制阵列的方法和系统。 液体溶液的复制阵列可以反应形成产品固体无机材料阵列，用于分析和选择具有所需性能的最佳工艺和产品。

公开(公告)号：US20060027786A1

公开(公告)日：2006-02-09

申请号：US11173342

申请日：2005-07-01

Applicant: Yi Dong ,  Ning Wang ,  Shifan Cheng ,  Yi-Qun Li

Inventor： Yi Dong ,  Ning Wang ,  Shifan Cheng ,  Yi-Qun Li

IPC: C09K11/08 ,  C09K11/77

CPC classification number: C09K11/7734 ,  C09K11/592 ,  H01L33/502 ,  Y02B20/181

Abstract: Embodiments of the present invention are directed in general to novel aluminate-blue phosphors. Specifically, embodiments of the present invention are directed to use of the novel aluminate-based blue phosphors in white light illumination systems, and in display applications such as back lighting in liquid crystal displays (LCD's) and plasma display panels (PDPs). Embodiments of the present invention are further directed toward aluminate-based phosphors having the general formula (M1−xEux)2−zMgzAlyO[1+(3/2)y], where M is a divalent alkaline earth metal other than magnesium (Mg) from group IIA of the periodic table, where 0.05

Abstract translation: 本发明的实施方案一般涉及新型的铝酸盐 - 蓝色荧光体。 具体地，本发明的实施方案涉及在白光照明系统中以及液晶显示器（LCD）和等离子体显示面板（PDP）中的背光照明等显示应用中使用新型铝酸盐系蓝色荧光体。 本发明的实施方案进一步涉及具有以下通式的铝酸盐基荧光体：（M 1-x O 2 x 2）2-z Mg 其中M是镁（Mg）以外的二价碱土金属， 来自周期表的IIA族，其中0.05

公开(公告)号：US20060022170A1

公开(公告)日：2006-02-02

申请号：US11061979

申请日：2005-02-18

Applicant: Yi-Qun Li ,  Shifan Cheng ,  Ning Wang ,  Yi Dong ,  Xiao-Dong Sun

Inventor： Yi-Qun Li ,  Shifan Cheng ,  Ning Wang ,  Yi Dong ,  Xiao-Dong Sun

IPC: C09K11/68 ,  C09K11/77 ,  C09K11/08 ,  C09K11/02

CPC classification number: C09K11/628 ,  C09K11/682 ,  C09K11/7708 ,  C09K11/7771 ,  C30B15/00 ,  C30B29/30 ,  G21K4/00

Abstract: Embodiments of the present invention are directed to compositions and processing methods of rare-earth vanadate based materials that have high emission efficiency in a wavelength range of 480 to 700 nm with the maximum intensity at 535 nm (bright yellow) under UV, X-ray and other forms of high-energy irradiation. Embodiments of the present invention are directed to general chemical compositions of the form (Gd1-xAx)(V1-yBy)(O4-zCz), where A is selected from the group consisting of Bi, Ti, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, and Lu for 0

Abstract translation: 本发明的实施方案涉及在480nm至700nm的波长范围内具有高发射效率且在UV，X射线下具有最大强度为535nm（亮黄色）的稀土类钒酸盐基材料的组合物和加工方法 和其他形式的高能辐射。 本发明的实施方案涉及以下形式的一般化学组成：（1-x A 1 x X）（V 1 -Y B） 其中A选自由Bi，Ti，Y，La，Ce组成的组，其中A选自Bi，Ti，Y，La，Ce， Pr，Nd，Pm，Sm，Eu，Tb，Dy，Ho，Er，Tm，Yb和Lu为0

公开(公告)号：US08133461B2

公开(公告)日：2012-03-13

申请号：US11975356

申请日：2007-10-18

Applicant: Dejie Tao ,  Yi-Qun Li ,  Shifan Cheng

Inventor： Dejie Tao ,  Yi-Qun Li ,  Shifan Cheng

IPC: C01F17/00

CPC classification number: C09K11/7774 ,  C09K11/777 ,  F21K9/64 ,  F21V9/30

Abstract: Disclosed herein are cerium doped, garnet phosphors emitting in the yellow region of the spectrum, and having the general formula (Y,A)3(Al,B)5(O,C)12:Ce3+, where A is Tb, Gd, Sm, La, Sr, Ba, Ca, and/or Mg, and substitutes for Y, B is Si, Ge, B, P, and/or Ga, and substitutes for Al, and C is F, Cl, N, and/or S, where C substitutes for O. Relative to a solid-state-reaction method, the instant co-precipitation methods provide a more homogeneous mixing environment to enhance the distribution of the Ce3+ activator in the YAG matrix. Such a uniform distribution has the benefit of an increased emission intensity. The primary particle size of the as-prepared phosphor is about 200 nm, with a narrow distribution.

Abstract translation: 本发明公开了在光谱黄色区域发射的具有通式（Y，A）3（Al，B）5（O，C）12：Ce 3+）的铈掺杂石榴石荧光体，其中A为Tb，Gd， Sm，La，Sr，Ba，Ca和/或Mg，并且代替Y，B是Si，Ge，B，P和/或Ga，并代替Al，C是F，Cl，N和 /或S，其中C代替O.相对于固态反应方法，即时共沉淀法提供更均匀的混合环境以增强Ce 3+活化剂在YAG基质中的分布。 这种均匀分布具有增加的发射强度的益处。 所制备的磷光体的一次粒径为约200nm，分布窄。