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公开(公告)号：US20160177453A1
公开(公告)日：2016-06-23
申请号：US15055657
申请日：2016-02-29
Applicant: Deepak Shukla
Inventor： Deepak Shukla
CPC classification number: C09D4/00 , B05D3/06 , B05D3/067 , C08F2/50 , C08J3/28 , C08J2367/02 , C08J2433/06 , C08K5/3432 , C08K5/3462 , C08K5/45 , C08K5/524 , C23C18/1608 , C23C18/1612 , C23C18/204 , C23C18/30 , C23C18/405 , C08F2222/1013 , C08F2222/1053
Abstract: Multiple photocured and copper electrolessly plated patterns are formed on a continuous flexible solid polymeric film in a roll-to-roll process. A photocurable composition is applied directly to the film in a patternwise fashion using flexographic printing members to form multiple patterns of the photocurable composition directly on the film. The photocurable composition contains an N-oxyazinium salt photoinitiator, a photosensitizer for the N-oxyazinium salt, an organic phosphite N-oxyazinium salt efficiency amplifier, an aromatic heterocyclic nitrogen-containing base, a metal seed catalyst for copper electroless plating, and one or more photocurable acrylates in designed relationships. The multiple patterns of the photocurable composition are exposed to form multiple photocured patterns directly on a product substrate and then electrolessly plated with copper to form multiple copper electrolessly plated patterns. Each electrically-conductive pattern can be incorporated into an electronic device for various purposes including touch screen displays.
Abstract translation: 在卷对卷过程中，在连续的柔性固体聚合物膜上形成多个光固化和铜无电镀图案。 使用柔性版印刷构件以图案方式将光可固化组合物直接施加到膜上，以直接在膜上形成可光固化组合物的多个图案。 光固化性组合物含有N-氧嗪鎓光引发剂，N-氧嗪鎓盐的光敏剂，有机亚磷酸酯N-氧嗪鎓盐效率放大器，芳香族杂环含氮碱，铜化学镀的金属种子催化剂，以及一种或 更多的光固化丙烯酸酯在设计的关系。 可光固化组合物的多个图案被曝光以直接在产品基底上形成多个光固化图案，然后用铜无电镀以形成多个铜无电镀图案。 每个导电图案可以结合到用于包括触摸屏显示器在内的各种目的的电子设备中。
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32.发明申请公开(公告)号：US20160168717A1
公开(公告)日：2016-06-16
申请号：US15001322
申请日：2016-01-20
Applicant: Deepak Shukla
Inventor： Deepak Shukla
CPC classification number: C23C18/30 , B01J23/50 , B01J31/06 , B01J31/181 , B01J35/026 , B01J37/0215 , B01J37/348 , C09D11/03 , C09D11/037 , C09D11/101 , C09D11/52 , C23C18/1608 , C23C18/182 , C23C18/1831 , C23C18/1868 , C23C18/1879 , C23C18/204 , C23C18/405 , H05K3/185 , H05K2203/125
Abstract: A non-aqueous metal catalytic composition includes (a) a silver complex comprising reducible silver ions, (b) an oxyazinium salt silver ion photoreducing agent, (c) a hindered pyridine, (d) a photocurable component, a non-curable polymer, or combination of a photocurable component and a non-curable polymer, and (e) a photo sensitizer different from all components (a) through (d) in the non-aqueous metal catalytic composition, in an amount of at least 1 weight %. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.
Abstract translation: 非水性金属催化剂组合物包括（a）包含可还原银离子的银络合物，（b）嗪嗪盐银离子光还原剂，（c）受阻吡啶，（d）可光固化组分，不可固化聚合物， 或光固化性组分和不可固化聚合物的组合，和（e）在非水性金属催化剂组合物中与所有组分（a）至（d）不同的光敏剂，其量为至少1重量％。 该非水金属催化剂组合物可用于在合适的还原条件下原位形成银金属颗粒。 银金属可以以合适的层或图案提供在基底上，然后可随后对其进行化学镀以形成用于各种制品的导电层或图案或用作电子设备中的触摸屏显示器。
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公开(公告)号：US09188861B2
公开(公告)日：2015-11-17
申请号：US14197293
申请日：2014-03-05
Applicant: Deepak Shukla , Mark R. Mis
Inventor： Deepak Shukla , Mark R. Mis
CPC classification number: G03F7/038 , G03F7/0045 , G03F7/0047 , G03F7/028 , G03F7/16
Abstract: A photopolymerizable composition has five essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and (d) metal particles. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing systems once various photocured patterns are formed from the photopolymerizable compositions.
Abstract translation: 可光聚合组合物具有五个基本组分：（a）可光聚合的环氧材料，（b）光酸产生剂如鎓盐，（c）电子给体光敏剂，其氧化电位至少为0.4V且至多并包括3V 与SCE，（d）金属颗粒。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦可光聚合组合物形成各种光固化图案，就可以在卷对卷印刷系统中进行的化学镀方法。
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公开(公告)号：US20150253661A1
公开(公告)日：2015-09-10
申请号：US14197293
申请日：2014-03-05
Applicant: Deepak Shukla , Mark R. Mis
Inventor： Deepak Shukla , Mark R. Mis
CPC classification number: G03F7/038 , G03F7/0045 , G03F7/0047 , G03F7/028 , G03F7/16
Abstract: A photopolymerizable composition has five essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and (d) metal particles. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing systems once various photocured patterns are formed from the photopolymerizable compositions.
Abstract translation: 可光聚合组合物具有五个基本组分：（a）可光聚合的环氧材料，（b）光酸产生剂如鎓盐，（c）电子给体光敏剂，其氧化电位至少为0.4V且至多并包括3V 与SCE，（d）金属颗粒。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上，以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦可光聚合组合物形成各种光固化图案，就可以在卷对卷印刷系统中进行的化学镀方法。
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公开(公告)号：US20150011699A1
公开(公告)日：2015-01-08
申请号：US14494712
申请日：2014-09-24
Applicant: Deepak Shukla , Dianne Marie Meyer , Mark R. Mis , Matthew Dirmyer
Inventor： Deepak Shukla , Dianne Marie Meyer , Mark R. Mis , Matthew Dirmyer
CPC classification number: H01B3/447 , C08F8/42 , C08F220/14 , C08F230/04 , C08K5/0091 , C08K5/56 , C08L33/04 , C08L67/02 , C08F220/24 , C08F220/20
Abstract: Organic polymeric bi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise a poly(meth)acrylate or polyester having metal coordination sites, and the same or different bi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer. The bi-metallic alkoxide or aryloxide molecules can be represented by Structure (I) shown herein. Such composites are generally soluble at room temperature in various organic solvents and be provided in homogeneous organic solvent solutions that can be suitably applied to a substrate to form dielectric materials.
Abstract translation: 有机聚合双金属醇盐或芳氧化物复合材料被用作具有改进的性能如改进的流动性的各种装置中的介电材料。 这些复合材料包含具有金属配位点的聚（甲基）丙烯酸酯或聚酯，以及与有机聚合物配位的相同或不同的双金属醇盐或芳氧化物分子。 双金属醇盐或芳氧化物分子可以由本文所示的结构（I）表示。 这种复合材料通常在室温下在各种有机溶剂中是可溶的，并且可以在均匀的有机溶剂溶液中提供，其可以适当地施加到基底上以形成电介质材料。
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Patent Agency Ranking
36.发明授权公开(公告)号：US08916336B2
公开(公告)日：2014-12-23
申请号：US14158902
申请日：2014-01-20
Applicant: Deepak Shukla , Kevin M. Donovan , Matthew Dirmyer
Inventor： Deepak Shukla , Kevin M. Donovan , Matthew Dirmyer
CPC classification number: G03F7/405 , B82Y30/00 , G03F7/0045 , G03F7/038
Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be used in methods to form predetermined patterns of metal nanoparticles.
Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以用于形成预定图案的金属纳米颗粒的方法。
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公开(公告)号：US20140287365A1
公开(公告)日：2014-09-25
申请号：US14158884
申请日：2014-01-20
Applicant: Deepak Shukla , Kevin M. Donovan , Mark R. Mis
Inventor： Deepak Shukla , Kevin M. Donovan , Mark R. Mis
IPC: G03F7/30
CPC classification number: G03F7/30 , G03F7/0045 , G03F7/038 , G03F7/405
Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles and used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material.
Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品，并且用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键，除去未交联的聚合物和与二硫化物反应性材料的反应。
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公开(公告)号：US20140239236A1
公开(公告)日：2014-08-28
申请号：US14269235
申请日：2014-05-05
Applicant: Deepak Shukla , Debasis Majumdar
Inventor： Deepak Shukla , Debasis Majumdar
CPC classification number: B01J19/123 , C01B32/23 , H01B1/04 , H01B1/24
Abstract: Graphite oxide can be converted to its reduced form (r-GO) using exposing UV radiation having a peak wavelength (λmax) of less than 400 nm while being maintained at a temperature that is greater than room temperature. This conversion method is efficient and can be carried out with various forms of graphite oxide samples, below atmospheric pressure, or in a reducing environment.
Abstract translation: 使用具有小于400nm的峰值波长（λmax）的UV辐射，同时保持在大于室温的温度下，可将石墨氧化物转化为其还原形式（r-GO）。 该转化方法是有效的并且可以用各种形式的氧化石墨样品，低于大气压或在还原环境中进行。
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公开(公告)号：US08816211B2
公开(公告)日：2014-08-26
申请号：US13026365
申请日：2011-02-14
Applicant: Deepak Shukla
Inventor： Deepak Shukla
IPC: H05K1/00 , C08F2/48 , H05K3/28 , G03F7/029 , C09D4/06 , C09D4/00 , C08F222/10 , C08F220/06 , C08F220/14 , H05K3/02 , H05K3/00
CPC classification number: G03F7/029 , C08F2/48 , C08F220/06 , C08F220/14 , C08F2222/1013 , C08F2222/1026 , C08F2222/1053 , C09D4/00 , C09D4/06 , H05K3/0076 , H05K3/022 , H05K3/287 , Y10T428/24612 , Y10T428/24802
Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment, and the photocurable compositions can be used to form various articles.
Abstract translation: 通过将其与有机亚磷酸酯和醛混合来增加光引发剂的光固化效率。 该混合物或光引发剂组合物可用于固化丙烯酸酯或其它可光固化的化合物，特别是在含氧环境中，并且可光固化组合物可用于形成各种制品。
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公开(公告)号：US20140128551A1
公开(公告)日：2014-05-08
申请号：US13671854
申请日：2012-11-08
Applicant: Deepak Shukla , Dianne M. Meyer , Mark R. Mis , Matthew Dirmyer
Inventor： Deepak Shukla , Dianne M. Meyer , Mark R. Mis , Matthew Dirmyer
IPC: C08F226/06 , C08F22/10
CPC classification number: C08F230/04
Abstract: Organic polymeric multi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise an organic polymer comprising metal coordination sites, and multi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer, the multi-metallic alkoxide or aryloxide molecules being represented by: (M)n(OR)x wherein at least one M is a metal selected from Group 2 of the Periodic Table and at least one other M is a metal selected from any of Groups 3 to 12 and Rows 4 and 5 of the Periodic Table, n is an integer of at least 2, R represents the same or different alkyl or aryl groups, and x is an integer of at least 2.
Abstract translation: 有机聚合多金属醇盐或芳氧化物复合材料用作具有改进性能的各种装置中的介电材料，例如改进的流动性。 这些复合材料包括包含金属配位点的有机聚合物和与有机聚合物配位的多金属醇盐或芳氧化物分子，多金属醇盐或芳氧化物分子由以下表示：（M）n（OR）x，其中至少 一个M是选自元素周期表第2族的金属，并且至少一个其它M是选自元素周期表第3至12族和第4和5族中的任一个的金属，n是至少2的整数，R 表示相同或不同的烷基或芳基，x为至少2的整数。
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