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公开(公告)号:US20130150534A1
公开(公告)日:2013-06-13
申请号:US13693495
申请日:2012-12-04
Applicant: ROHM AND HAAS COMPANY
Inventor: Larry F. Brinkman , Amira Avril Marine , David E. Vietti , Joseph J. Zupancic
CPC classification number: C08G63/918 , C08G18/10 , C08G18/12 , C08G18/36 , C08G18/4288 , C08G18/683 , C08L67/02
Abstract: An isocyanate-terminated prepolymer having three components. The first component is 30-60 wt % polymerized residues of a first polyol containing a substituent of formula (I) attached via a carbon-carbon single bond to a saturated carbon atom in a fatty acid hydrocarbyl group; wherein R1 and R2 are esterified residues of aliphatic or cycloaliphatic diols; and wherein the first polyol contains: (i) from 0.33 to 0.4 units of formula (I) per fatty acid hydrocarbyl group, and (ii) from 0 to 12 wt % esterified residues of at least one C4-C12 anhydride, C4-C12 diacid or C4-C12 lactone, not including units of formula (I) attached to a fatty acid hydrocarbyl group; and wherein the first polyol has a hydroxyl number from 75 to 150 mg KOH/g. The second component is 40-55 wt % polymerized residues of diphenyl methane diisocyanate. The third component is 0-20 wt % polymerized residues of a glycol having Mn from 300 to 3500.
Abstract translation: 具有三种成分的异氰酸酯封端的预聚物。 第一组分是含有通过碳 - 碳单键与脂肪酸烃基中的饱和碳原子连接的式(I)的取代基的第一多元醇的30-60重量%聚合残基; 其中R1和R2是脂族或脂环族二醇的酯化残基; 并且其中所述第一多元醇包含:(i)每个脂肪酸烃基为0.33至0.4单位的式(I)单元,和(ii)至少一种C 4 -C 12酐,C 4 -C 12烷基酯的0-12重量%酯化残基 二酸或C 4 -C 12内酯,不包括连接到脂肪酸烃基的式(I)单元; 并且其中所述第一多元醇具有75至150mg KOH / g的羟值。 第二组分是二苯基甲烷二异氰酸酯的40-55重量%聚合残余物。 第三成分是Mn为300〜3500的二醇的聚合残渣为0〜20重量%。
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公开(公告)号:US20250059417A1
公开(公告)日:2025-02-20
申请号:US18937946
申请日:2024-11-05
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Elodie Hablot , Jie Wu , Kalyan Sehanobish , Thorsten Schmidt , Joseph J. Zupancic , Daniele Vinci , Marco Frasconi , Tuoqi Li
IPC: C09J175/12 , B32B7/12 , B32B27/08 , B32B27/30 , B32B27/32 , B32B27/34 , C08G18/12 , C08G18/32 , C08G18/72 , C08G18/73 , C08G18/76 , C08K3/36 , C09J183/12
Abstract: Two-component solventless polyurethane adhesive compositions are disclosed comprising an isocyanate component comprising an isocyanate blend, and a polyol component comprising an amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines, wherein the amine-initiated polyol comprises a functionality of from 2 to 12, a hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s, and a silicone-based additive (e.g., an anti-foaming agent and/or a wetting agent). The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Laminate structures comprising the disclosed adhesive compositions and further comprising a polymeric barrier substrate are also disclosed.
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公开(公告)号:US12139647B2
公开(公告)日:2024-11-12
申请号:US17999005
申请日:2021-04-23
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Yinzhong Guo , Jie Wu
IPC: C09J167/00 , C08G18/58 , C08K3/32
Abstract: Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.
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公开(公告)号:US12134715B2
公开(公告)日:2024-11-05
申请号:US17436531
申请日:2020-03-04
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Matthew M. Yonkey , Paul G. Clark , Thorsten Schmidt , Wenwen Li
IPC: C09J175/06 , B32B7/12 , B32B15/085 , B32B27/08 , B32B27/32 , B32B27/36 , C08G18/12 , C08G18/44 , C08G18/46 , C08G18/73
Abstract: The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component; and (B) a polyol component containing (i) a polyester-polycarbonate polyol and (ii) a phosphate-terminated polyol. The present disclosure also provides a method of forming the two-component solvent-less adhesive composition.
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公开(公告)号:US12054652B2
公开(公告)日:2024-08-06
申请号:US17436434
申请日:2020-03-04
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Matthew M. Yonkey , Paul G. Clark , Thorsten Schmidt , Ken Kawamoto , Wenwen Li
IPC: C08G18/46 , B32B7/12 , B32B15/085 , B32B27/08 , B32B27/32 , B32B27/36 , C08G18/12 , C08G18/38 , C09J175/06 , C09J175/12
CPC classification number: C09J175/06 , B32B7/12 , B32B15/085 , B32B27/08 , B32B27/32 , B32B27/36 , C08G18/12 , C08G18/3885 , C08G18/4615
Abstract: The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component and (B) a polyol component containing a poly-ester-amide polycarbonate polyol. The present disclosure also provides a method of forming a two-component solvent-less adhesive composition.
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公开(公告)号:US11773303B2
公开(公告)日:2023-10-03
申请号:US16617047
申请日:2018-04-04
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Wenwen Li , Joseph J. Zupancic , Paul Clark , Thorsten Schmidt
IPC: C09J175/06 , C08G18/12 , C08G18/50 , C08G18/76
CPC classification number: C09J175/06 , C08G18/12 , C08G18/509 , C08G18/5084 , C08G18/7671
Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.
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公开(公告)号:US11746267B2
公开(公告)日:2023-09-05
申请号:US17436515
申请日:2020-03-04
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Matthew M. Yonkey , Paul G. Clark , Thorsten Schmidt , Ken Kawamoto , Wenwen Li
IPC: C09J175/12 , B32B7/12 , B32B15/085 , B32B15/20 , B32B27/08 , B32B27/32 , B32B27/36
CPC classification number: C09J175/12 , B32B7/12 , B32B15/085 , B32B15/20 , B32B27/08 , B32B27/32 , B32B27/36
Abstract: The present disclosure provides a two-component solvent-based adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a polyol component containing a polyester-amide polycarbonate polyol; and (C) a solvent. The present disclosure also provides a method of forming the two-component solvent-based adhesive composition.
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公开(公告)号:US20220289900A1
公开(公告)日:2022-09-15
申请号:US17597416
申请日:2020-06-10
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Joseph J. Zupancic , Tuoqi Li , Wenwen Li
IPC: C08G59/22 , C08G63/91 , C09J163/00
Abstract: An epoxy terminated polyester; an adhesive formulation including the epoxy terminated polyester and a curative composition; a laminating adhesive prepared from the above adhesive formulation; a process of making a laminate; a laminate made by the above process; and a flexible package prepared from the above laminate.
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公开(公告)号:US20220145148A1
公开(公告)日:2022-05-12
申请号:US17436563
申请日:2020-03-04
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Tuoqi Li , Joseph J. Zupancic , Matthew M. Yonkey , Paul G. Clark , Thorsten Schmidt , Wenwen Li
IPC: C09J175/08 , C08G18/10 , C08G18/08 , C08G18/76 , C08G18/44 , C08G18/38 , C08G18/48 , C08G18/40 , C08G18/66 , B32B7/12 , B32B27/32 , B32B15/085 , B32B27/36 , B32B27/08 , B32B15/20
Abstract: The present disclosure provides a two-component solvent-based adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a polyol component containing (i) a polyester-polycarbonate polyol and (ii) a phosphate-terminated polyol; and (iii) a solvent. The present disclosure also provides a method of forming a two-component solvent-based adhesive composition.
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公开(公告)号:US10513643B2
公开(公告)日:2019-12-24
申请号:US15526109
申请日:2015-11-10
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Joseph J. Zupancic , Amira A. Marine , David E. Vietti , Daniele Vinci
IPC: C09J167/00 , C09D167/00 , C08L67/00 , C08K5/52 , C08L63/00 , C08K5/29 , C08L67/02 , C08L75/06
Abstract: The instant invention provides a curable formulation suitable for laminating adhesive applications, and laminating adhesives made therefrom. The curable formulation suitable for laminating adhesive applications according to the present invention comprises a high molecular weight polyester resin, an epoxy-terminated polyester, an additive, a curing agent, and a solvent, wherein, upon curing under curing conditions, the curable formulation forms at least one interpenetrating polymer network.
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