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    Photochromic articles that include photochromic-dichroic materials
    31.
    发明授权
    Photochromic articles that include photochromic-dichroic materials 有权
    包含光致变色二色性材料的光致变色制品

    公开(公告)号：US09334439B2

    公开(公告)日：2016-05-10

    申请号：US13835413

    申请日：2013-03-15

    Applicant: Transitions Optical, Inc.

    Inventor： Rachael L. DeMeio ,  Anil Kumar ,  Meng He ,  Darrin R. Dabideen ,  Sujit Mondal

    IPC: B60J1/00 ,  G02B1/10 ,  G02B5/23 ,  G02C7/02 ,  C09K9/02 ,  G03C1/73 ,  G02B1/04 ,  G03C1/685 ,  G02C7/10 ,  B60J3/00

    CPC classification number: G02B5/23 ,  B60J3/007 ,  C09K9/02 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1088 ,  G02B1/043 ,  G02B1/10 ,  G02B5/208 ,  G02B5/223 ,  G02C7/102 ,  G03C1/685 ,  G03C1/695 ,  G03C1/73 ,  C08L33/10 ,  C08L83/04

    Abstract: The present invention relates to photochromic articles that include a substrate and at least one photochromic material that is adapted to change from an unactivated form to an activated form by exposure to radiation substantially in the wavelength range from 380 to 450 nanometers when measured over a range of from 380 to 700 nanometers. The photochromic article is also adapted to retain at least 12 percent of the delta OD measured in the Outdoor Test when tested in the Behind the Windshield Test. The photochromic material can be selected from certain compounds including, for example, fluoranthenoxazines, naphthopyrans, phenanthropyrans, fluoranthenopyrans, and indenonaphthopyrans, which each have bonded thereto at least one chiral or achiral lengthening group that provides the photochromic compound with dichroic properties. The present invention also relates to methods of forming a photochromic article.

    Abstract translation: 本发明涉及光致变色制品，其包括基材和至少一种光致变色材料，其适于通过暴露于基本上在380至450纳米的波长范围内的辐射而从未活化形式转变为活化形式 从380到700纳米。 当在挡风玻璃测试后面进行测试时，光致变色制品也适用于保留户外测试中测量的ΔOD的至少12％。 光致变色材料可以选自某些化合物，包括例如荧蒽酮，萘并吡喃，菲并吡喃，荧蒽吡喃和茚并萘并吡喃，它们各自具有至少一个提供具有二色性的光致变色化合物的手性或非手性延长基。 本发明还涉及形成光致变色制品的方法。

    Alignment polymers
    34.
    发明授权
    Alignment polymers 有权

    公开(公告)号：US11130912B2

    公开(公告)日：2021-09-28

    申请号：US15573174

    申请日：2015-06-12

    Applicant: Transitions Optical, Inc.

    Inventor： Anil Kumar ,  Meng He ,  Ryan Stayshich ,  Gobinda Saha

    IPC: C09K19/38 ,  C08F220/30 ,  C08F220/36 ,  G02F1/1337 ,  C09K19/34 ,  C09K19/04

    Abstract: The present invention relates to polymers that include residues of at least one monomer represented by the following Formula (I). With reference to Formula (I), at least one of E1 and E2 independently is, or is independently substituted with, at least one reactive group, such as a (meth)acryloyl group. Monomers represented by Formula (I) and monomer residues thereof have alignment properties, such as photoalignment properties. The present invention also relates to alignment layers that include such polymers, and articles of manufacture, such as optical elements, that include one or more such alignment layers.

    Optical Articles and Method of Preparing the Same
    35.
    发明申请
    Optical Articles and Method of Preparing the Same 审中-公开

    公开(公告)号：US20180299599A1

    公开(公告)日：2018-10-18

    申请号：US15767366

    申请日：2015-10-30

    Applicant: Transitions Optical, Inc.

    Inventor： Anil Kumar ,  David John Park ,  Brian Smyth ,  Delwin S. Jackson ,  Henry Nguyen ,  John S. Ligas ,  Linda K. Anderson

    IPC: G02B5/30 ,  B29D11/00 ,  G02C7/02 ,  G02C7/10

    Abstract: An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

    Photochromic Compounds
    36.
    发明申请
    Photochromic Compounds 审中-公开

    公开(公告)号：US20180291008A1

    公开(公告)日：2018-10-11

    申请号：US16008157

    申请日：2018-06-14

    Applicant: Transitions Optical, Inc.

    Inventor： Meng He ,  Darrin R. Dabideen ,  Terry A. Kellar, II ,  Anil Kumar

    IPC: C07D405/10 ,  G02C7/10 ,  G02B1/04 ,  G03C1/73 ,  G03C1/685 ,  G02B5/30 ,  G02B5/23 ,  C09K9/02 ,  C07D311/94 ,  C07D311/92 ,  G02B5/22

    Abstract: A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N3, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSO2R′″, and/or CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R′″ is —CF3 or a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound.

    Methods of Making Fused Ring Compounds
    40.
    发明申请
    Methods of Making Fused Ring Compounds 有权
    制备稠环化合物的方法

    公开(公告)号：US20170050909A1

    公开(公告)日：2017-02-23

    申请号：US15344919

    申请日：2016-11-07

    Applicant: Transitions Optical, Inc.

    Inventor： Meng He ,  Anil Kumar

    IPC: C07C39/17 ,  C07C51/353 ,  C07D307/33 ,  C07D311/94

    CPC classification number: C07C39/17 ,  C07C37/11 ,  C07C41/01 ,  C07C51/353 ,  C07C2602/08 ,  C07C2603/40 ,  C07D307/33 ,  C07D311/94 ,  C07D405/04 ,  C07D407/04

    Abstract: The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).

    Abstract translation: 关于式II的不饱和化合物：环-A可以选自任选取代的芳基（例如苯基）; m可以是例如0至4; 每个m的R 1可以选自任选被至少一个连接基团（例如-O-）中断的任选取代的烃基（例如C 1 -C 6烷基）; 并且R 3和R 16各自独立地选自例如氢或任选取代的烃基，例如C 1 -C 8烷基。 当环A是苯基时，由式II表示的不饱和化合物可以称为不饱和茚酮酸/酯化合物或茚酮酸/酯化合物（取决于R 16是氢还是任选取代的烃基 ）。

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