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公开(公告)号:US10689317B2
公开(公告)日:2020-06-23
申请号:US15881196
申请日:2018-01-26
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Anil Kumar
IPC: C07D405/04 , C07D407/04 , C07D311/94 , C07C51/353 , C07C37/11 , C07C41/01 , C07C39/17 , C07D307/33
Abstract: The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).
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公开(公告)号:US10532998B2
公开(公告)日:2020-01-14
申请号:US16009254
申请日:2018-06-15
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Darrin R. Dabideen , Terry A. Kellar, II , Anil Kumar
IPC: C07D405/10 , G02C7/10 , G02B1/04 , G03C1/73 , G03C1/685 , G02B5/30 , G02B5/23 , C09K9/02 , C07D311/92 , G02B5/22 , C07D311/94
Abstract: A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N3, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSO2R″′, and/or —CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R″′ is —CF3 or a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound.
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公开(公告)号:US10145996B2
公开(公告)日:2018-12-04
申请号:US15050500
申请日:2016-02-23
Applicant: Transitions Optical, Inc.
Inventor: Rachael L. DeMeio , Darrin R. Dabideen , Meng He , Anil Kumar , Sujit Mondal
IPC: G02B5/23 , G02C7/02 , G02C7/10 , G03C1/685 , G03C1/695 , G03C1/73 , B60J3/00 , C09K9/02 , G02B1/04 , G02B5/20 , G02B5/22 , G02B1/10
Abstract: The present invention relates to photochromic articles that include a substrate and at least one photochromic material that is adapted to change from an unactivated form to an activated form by exposure to radiation substantially in the wavelength range from 380 to 450 nanometers when measured over a range of from 380 to 700 nanometers. The photochromic article is also adapted to retain at least 12 percent of the delta OD measured in the Outdoor Test when tested in the Behind the Windshield Test. The photochromic material can be selected from certain compounds including, for example, fluoranthenoxazines, naphthopyrans, phenanthropyrans, fluoranthenopyrans, and indenonaphthopyrans, which each have bonded thereto at least one chiral or achiral lengthening group that provides the photochromic compound with dichroic properties. The present invention also relates to methods of forming a photochromic article.
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公开(公告)号:US20180148396A1
公开(公告)日:2018-05-31
申请号:US15881196
申请日:2018-01-26
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Anil Kumar
IPC: C07C39/17 , C07D407/04 , C07D307/33 , C07D405/04 , C07C41/01 , C07C51/353 , C07D311/94 , C07C37/11
CPC classification number: C07C39/17 , C07C37/11 , C07C41/01 , C07C51/353 , C07C2602/08 , C07C2603/40 , C07D307/33 , C07D311/94 , C07D405/04 , C07D407/04
Abstract: The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).
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公开(公告)号:US09878971B2
公开(公告)日:2018-01-30
申请号:US15344919
申请日:2016-11-07
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Anil Kumar
IPC: C07D405/04 , C07D407/04 , C07D311/94 , C07D307/33 , C07C51/353 , C07C37/11 , C07C41/01 , C07C39/17
CPC classification number: C07C39/17 , C07C37/11 , C07C41/01 , C07C51/353 , C07C2602/08 , C07C2603/40 , C07D307/33 , C07D311/94 , C07D405/04 , C07D407/04
Abstract: The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).
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公开(公告)号:US09309455B2
公开(公告)日:2016-04-12
申请号:US14183687
申请日:2014-02-19
Applicant: TRANSITIONS OPTICAL, INC.
Inventor: Meng He , Anil Kumar , Darrin R. Dabideen
IPC: C09K9/02 , C07D311/92 , C07D311/94 , G02B5/30 , G03C1/73 , G02B5/23
CPC classification number: C09K9/02 , C07D311/92 , C07D311/94 , C09B11/02 , C09B57/00 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1088 , G02B5/23 , G02B5/3016 , G03C1/73
Abstract: The present invention relates to compounds represented by the following Formula (II), Ring-A of Formula II can be, for example, an aryl group, and Q′ and Q′″ can each be independently selected from groups, such as, halogen, —OH, —CN, amine groups, amide groups, carboxylic acid ester groups, carboxylic acid groups, alkenyl groups, alkynyl groups, carbonate groups, sulfide groups, and sulfonic acid ester groups. The present invention also relates to photochromic compositions and photochromic articles that include one or more photochromic compounds such as represented by Formula II.
Abstract translation: 本发明涉及由下式(II)表示的化合物,式II的环-A可以是例如芳基,Q'和Q'“各自独立地选自如下的基团,例如卤素 ,-OH,-CN,胺基,酰胺基,羧酸酯基,羧酸基,烯基,炔基,碳酸酯基,硫醚基和磺酸酯基。 本发明还涉及包含一种或多种由式II表示的光致变色化合物的光致变色组合物和光致变色制品。
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公开(公告)号:US20140166948A1
公开(公告)日:2014-06-19
申请号:US14183687
申请日:2014-02-19
Applicant: TRANSITIONS OPTICAL, INC.
Inventor: Meng He , Anil Kumar , Darrin R. Dabideen
IPC: C09K9/02
CPC classification number: C09K9/02 , C07D311/92 , C07D311/94 , C09B11/02 , C09B57/00 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1088 , G02B5/23 , G02B5/3016 , G03C1/73
Abstract: The present invention relates to compounds represented by the following Formula (II), Ring-A of Formula II can be, for example, an aryl group, and Q′ and Q′″ can each be independently selected from groups, such as, halogen, —OH, —CN, amine groups, amide groups, carboxylic acid ester groups, carboxylic acid groups, alkenyl groups, alkynyl groups, carbonate groups, sulfide groups, and sulfonic acid ester groups. The present invention also relates to photochromic compositions and photochromic articles that include one or more photochromic compounds such as represented by Formula II.
Abstract translation: 本发明涉及由下式(II)表示的化合物,式II的环-A可以是例如芳基,Q'和Q'“各自独立地选自如下的基团,例如卤素 ,-OH,-CN,胺基,酰胺基,羧酸酯基,羧酸基,烯基,炔基,碳酸酯基,硫醚基和磺酸酯基。 本发明还涉及包含一种或多种由式II表示的光致变色化合物的光致变色组合物和光致变色制品。
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公开(公告)号:US20180127653A1
公开(公告)日:2018-05-10
申请号:US15573174
申请日:2015-06-12
Applicant: Transitions Optical, Inc.
Inventor: Anil Kumar , Meng He , Ryan Stayshich , Gobinda Saha
IPC: C09K19/38 , C08F220/30 , C08F220/36 , C09K19/34
Abstract: The present invention relates to polymers that include residues of at least one monomer represented by the following Formula (I). With reference to Formula (I), at least one of E1 and E2 independently is, or is independently substituted with, at least one reactive group, such as a (meth)acryloyl group. Monomers represented by Formula (I) and monomer residues thereof have alignment properties, such as photoalignment properties. The present invention also relates to alignment layers that include such polymers, and articles of manufacture, such as optical elements, that include one or more such alignment layers.
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公开(公告)号:US09487499B2
公开(公告)日:2016-11-08
申请号:US14822938
申请日:2015-08-11
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Anil Kumar
IPC: C07D405/04 , C07D407/04 , C07D311/94 , C07C37/11 , C07C41/01 , C07C51/353
CPC classification number: C07C39/17 , C07C37/11 , C07C41/01 , C07C51/353 , C07C2602/08 , C07C2603/40 , C07D307/33 , C07D311/94 , C07D405/04 , C07D407/04
Abstract: The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C1-C6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R3 and R16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C1-C8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R16 is hydrogen, or an optionally substituted hydrocarbyl group).
Abstract translation: 关于式II的不饱和化合物:环-A可以选自任选取代的芳基(例如苯基); m可以是例如0至4; 每个m的R 1可以选自任选被至少一个连接基团(例如-O-)中断的任选取代的烃基(例如C 1 -C 6烷基); 并且R 3和R 16各自独立地选自例如氢或任选取代的烃基,例如C 1 -C 8烷基。 当环A是苯基时,由式II表示的不饱和化合物可以称为不饱和茚酮酸/酯化合物或茚酮酸/酯化合物(取决于R 16是氢还是任选取代的烃基 )。
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公开(公告)号:US09206151B2
公开(公告)日:2015-12-08
申请号:US14084739
申请日:2013-11-20
Applicant: Transitions Optical, Inc.
Inventor: Meng He , Massimiliano Tomasulo , Allison Greene , Anil Kumar
IPC: C07D307/02 , C07D307/89 , C07D209/70 , C07C69/017 , C07C67/00 , C07D311/78 , C07C65/17 , C07C51/09 , C07C65/26 , C07D209/58 , C07D307/77 , C07C63/44
CPC classification number: C07C65/26 , C07C51/09 , C07C51/38 , C07C63/44 , C07C63/72 , C07C65/17 , C07C67/00 , C07C69/017 , C07C2602/08 , C07C2603/40 , C07D209/58 , C07D209/70 , C07D307/77 , C07D307/89 , C07D311/78
Abstract: The present invention relates to methods of preparing fused ring indeno compounds that involves reacting together a dienophile and a lactone compound, in the presence of a catalyst, and a carboxylic acid anhydride. With some embodiments, the fused ring indeno compound is represented by the following Formula (I-A), the dienophile is represented by the following Formula (II-A), and the lactone compound is represented by the following Formula (III-A):
Abstract translation: 本发明涉及制备稠环茚并化合物的方法,该方法包括在催化剂和羧酸酐的存在下使亲双酯和内酯化合物反应。 在一些实施方案中,稠环茚并化合物由下式(I-A)表示,亲双烯体由下式(II-A)表示,内酯化合物由下式(III-A)表示:
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