Alkadiene/vinylaromatic copolymers containing side groups, and their use
    41.
    发明授权
    Alkadiene/vinylaromatic copolymers containing side groups, and their use 失效
    含有侧基的二烯/乙烯基芳族共聚物及其用途

    公开(公告)号:US5290874A

    公开(公告)日:1994-03-01

    申请号:US854386

    申请日:1992-03-19

    Abstract: The novel alkadiene/vinyl-aromatic copolymers which contain side groups and have a random, block-like or star-like structure and whose polymerized alkadiene comonomer units are partially or completely selectively hydrogenated, and which contain one or more side groups having one or more radicals capable of (4+2) cycloaddition (Diels-Alder reaction) with dienophiles are suitable as such as viscosity index (VI) improvers or can be used for the preparation of dispersant VI improvers. For this purpose, they are reacted with one or more dienophiles which are capable of a Diels-Alder (4+2) cycloaddition reaction and preferably contain strongly polar functional groups. The resulting selectively hydrogenated alkadiene/vinylaromatic copolymers having one or more side groups which constitute a (4+2) cycloadduct or a Diels-Alder adduct can be modified in their performance characteristics by further reaction with ammonia, an organic amine, an alkylene oxide, a polyalkylene oxide and/or a condensate of ammonia and/or an organic amine with an alkylene oxide.

    Abstract translation: 含有侧基且具有无规,嵌段状或星形结构且其聚合的链烯二
    烯共聚单体部分或全部被选择性氢化的新型链二烯/乙烯基 - 芳族共聚物,其含有一个或多个具有一个或多个 具有双亲性的(4 + 2)环加成(Diels-Alder反应)的基团是适合的,如粘度指数(VI)改进剂或可用于制备分散剂VI改进剂。 为此,它们与一种或多种能够进行狄尔斯 - 阿尔德(4 + 2)环加成反应并且优选含有极性极性官能团的亲二烯体反应。 可以通过与氨,有机胺,环氧烷烃等进一步反应,将具有构成(4 + 2)环加成物或狄尔斯 - 阿尔德加合物的一个或多个侧基的所得选择性氢化的二烯烃/乙烯基芳族共聚物的性能特性改性, 聚氧化烯和/或氨和/或有机胺与烯化氧的缩合物。

    Preparation of isobutene homo- or copolymer derivatives
    46.
    发明授权
    Preparation of isobutene homo- or copolymer derivatives 有权
    异丁烯均聚物或共聚物衍生物的制备

    公开(公告)号:US09296841B2

    公开(公告)日:2016-03-29

    申请号:US13305283

    申请日:2011-11-28

    Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250,000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.

    Abstract translation: (i)在卤化铁 - 给体络合物,三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法( ii)使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应,和(iii)在与亚结构反应的情况下,进一步反应以完成低分子量的形成 极地组。 均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团,硝基,羟基,硫醇基,羧酸或羧酸衍生物 功能,磺酸或磺酸衍生物功能,醛官能团和/或甲硅烷基。

    Method for producing a polyisobutene
    49.
    发明授权
    Method for producing a polyisobutene 失效
    聚异丁烯的制造方法

    公开(公告)号:US07745554B2

    公开(公告)日:2010-06-29

    申请号:US12089930

    申请日:2006-10-13

    CPC classification number: C08F110/10 C08F4/14

    Abstract: The invention relates to a process for preparing polyisobutene having a mean molecular weight Mn of from 400 to 50 000, in particular from 500 to 10 000, by polymerizing isobutene in the presence of a BF3-containing complex catalyst, wherein the polymerization is carried out at least temporarily in the presence of one or more cyclic ethers.

    Abstract translation: 本发明涉及通过在含BF 3的络合物催化剂存在下聚合异丁烯来制备平均分子量Mn为400至50,000,特别是500至10000的聚异丁烯的方法,其中进行聚合 至少暂时存在一种或多种环醚。

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