公开(公告)号：US20090247725A1

公开(公告)日：2009-10-01

申请号：US12058331

申请日：2008-03-28

Applicant: Beatriz Penalver Bernabe ,  Lioba Maria Kloppenburg ,  Matt Kuhlman ,  Roy Ray Odle ,  Eric Pressman ,  Narayan Ramesh ,  Harpreet Singh

Inventor： Beatriz Penalver Bernabe ,  Lioba Maria Kloppenburg ,  Matt Kuhlman ,  Roy Ray Odle ,  Eric Pressman ,  Narayan Ramesh ,  Harpreet Singh

IPC: C07D307/89 ,  C08G73/10

CPC classification number: C07D307/88 ,  C07D307/89 ,  C08G73/1046

Abstract: a method for preparing an oxydiphthalic anhydride comprises contacting, under reactive and substantially anhydrous conditions in a reactor, at least one halophthalic anhydride containing more than 250 ppm chlorophthalide impurity with a carbonate of the formula M2CO3, wherein M is an alkali metal, in the presence of a catalytic proportion of at least one phase transfer catalyst selected from the group consisting of hexaalkylguanidinium halides and alpha,omega-bis(pentaalkylguanidinium)alkane salts, phosphonium salts, phosphazenium salts, pyridinium salts, phosphazenium salts, ammonium salts, and combinations thereof. The phase transfer catalyst is present in a sufficient amount to prepare the oxydiphthalic anhydride when the chlorophthalide is present in an amount that is more than 250 ppm, and the oxydiphthalic anhydride is produced in a yield, based on the carbonate, of at least 70%.

Abstract translation: 一种制备氧联二邻苯二甲酸酐的方法包括在反应器和反应性基本上无水的条件下，在反应器中使至少一种含有多于250ppm氯酞酸盐杂质的卤代邻苯二甲酸酐与式M2CO3的碳酸盐接触，其中M为碱金属， 选自六烷基卤化镓和α，ω-双（五烷基胍）烷烃盐，鏻盐，磷氮烯基鏻盐，吡啶鎓盐，磷氮烯基鏻盐，铵盐及其组合的至少一种相转移催化剂的催化剂比例。 当氯代苯酞以250ppm以上的量存在时，相转移催化剂的存在量足以制备氧联二邻苯二甲酸酐，并且基于碳酸酯的产率以氧化邻苯二甲酸酐的产率为至少70％ 。

公开(公告)号：US20090099300A1

公开(公告)日：2009-04-16

申请号：US12099809

申请日：2008-04-09

Applicant: Robert Russell Gallucci ,  Tara J. Mullen ,  Roy Ray Odle ,  Kapil Chandrakant Sheth ,  James Mitchell White

Inventor： Robert Russell Gallucci ,  Tara J. Mullen ,  Roy Ray Odle ,  Kapil Chandrakant Sheth ,  James Mitchell White

IPC: C08L61/00 ,  C08L73/02

CPC classification number: C08G73/1071 ,  C08G73/1046 ,  C08G73/1053 ,  C08G73/1064 ,  C08G73/1067 ,  C08J3/005 ,  C08K3/013 ,  C08L79/08 ,  C08L81/06 ,  C08L2205/02 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/14

Abstract: Methods of making miscible and compatible immiscible polymer blends are disclosed. The polymer blends have a polyimide as a component. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures. The polymer blends may optionally include one or more fillers.

Abstract translation: 公开了制备可混溶和相容的不混溶聚合物共混物的方法。 聚合物共混物具有聚酰亚胺作为组分。 可混溶的聚合物共混物具有单一的玻璃化转变温度。 相容的聚合物共混物具有两个玻璃化转变温度。 聚合物共混物可以任选地包括一种或多种填料。

公开(公告)号：US20090029615A1

公开(公告)日：2009-01-29

申请号：US12181023

申请日：2008-07-28

Applicant: Prameela Susarla ,  Amitabh Bansal ,  Xiaolan Wei ,  Ganesh Kailasam ,  Thomas Link Guggenheim ,  Karthik Venkataraman ,  Erik C. Hagberg ,  Roy Ray Odle

Inventor： Prameela Susarla ,  Amitabh Bansal ,  Xiaolan Wei ,  Ganesh Kailasam ,  Thomas Link Guggenheim ,  Karthik Venkataraman ,  Erik C. Hagberg ,  Roy Ray Odle

IPC: D03D15/00 ,  C08G73/00 ,  D04H13/00 ,  B29C47/00

CPC classification number: C08G73/1053 ,  C08L79/08 ,  D01D5/12 ,  D01D10/02 ,  D01F6/74 ,  D04H3/005 ,  D10B2331/06 ,  Y10T442/30 ,  Y10T442/3984 ,  Y10T442/60 ,  Y10T442/696

Abstract: A composition is described, which comprises a crystallizable polyetherimide derived from the polymerization of: (a) a dianhydride component, comprising more than 96.8 mole % of 4,4′-bisphenol A dianhydride or a chemical equivalent thereof; and (b) a diamine component comprising a diamine or a chemical equivalent thereof, wherein the crystallizable polyetherimide has a Tm ranging from 250° C. to 400° C. and the difference between the Tm and Tg of the composition is more than 50° C. Further described are articles, such as fibers, made from the composition, methods for making the composition, methods for making the articles, and methods for using the articles.

Abstract translation: 描述了一种组合物，其包含衍生自以下聚合的可结晶聚醚酰亚胺：（a）二酐组分，其包含大于96.8摩尔％的4,4'-双酚A二酐或其化学等价物; 和（b）包含二胺或其化学等价物的二胺组分，其中可结晶聚醚酰亚胺的Tm为250℃至400℃，组合物的Tm和Tg之间的差值大于50℃ 进一步描述了由组合物制成的制品，例如纤维，用于制备组合物的方法，制造制品的方法以及使用制品的方法。

公开(公告)号：US06590108B1

公开(公告)日：2003-07-08

申请号：US10065473

申请日：2002-10-22

Applicant: Roy Ray Odle ,  Thomas Link Guggenheim ,  William James Swatos ,  Michael J. Vollmer

Inventor： Roy Ray Odle ,  Thomas Link Guggenheim ,  William James Swatos ,  Michael J. Vollmer

IPC: G07D30789

CPC classification number: C08G73/1053 ,  C08G73/1007

Abstract: A method for the synthesis of a dianhydride comprises transimidation of bis (imide) (IV) in the presence of a substituted phthalic anhydride or 4-substituted tetrahydrophthalic anhydride to yield dianhydride (V)

Abstract translation: 合成二酐的方法包括在取代的邻苯二甲酸酐或4-取代的四氢邻苯二甲酸酐的存在下，双（酰亚胺）（Ⅳ）的酰化反应得到二酐（Ⅴ）

公开(公告)号：US06498224B1

公开(公告)日：2002-12-24

申请号：US09683257

申请日：2001-12-05

Applicant: Roy Ray Odle ,  Thomas Link Guggenheim ,  William James Swatos ,  Michael J. Vollmer

Inventor： Roy Ray Odle ,  Thomas Link Guggenheim ,  William James Swatos ,  Michael J. Vollmer

IPC: C08G7310

CPC classification number: C08G73/1053 ,  C08G73/1007

Abstract: A new method for the synthesis of poly(etherimide)s comprises transimidation of bis(imide) (IV) in the presence of a substituted phthalic anhydride or 4-substituted tetrahydrophthalic anhydride to yield dianhydride (V) which may then be reacted with a diamine to produce poly(etherimide)s. By-product substituted N-alkylphthalimide or 4-substituted N-alkyltetrahydrophthalic anhydride may be recycled or converted to 4-substituted N-alkylphthalimide for use in the formation bisimide (IV), obviating the need for a nitration step.

Abstract translation: 用于合成聚（醚酰亚胺）的新方法包括在取代的邻苯二甲酸酐或4-取代的四氢邻苯二甲酸酐的存在下，双（酰亚胺）（Ⅳ）的转移，得到二酐（Ⅴ），然后可与二胺 以产生聚（醚酰亚胺）。 副产物取代的N-烷基邻苯二甲酰亚胺或4-取代的N-烷基四氢邻苯二甲酸酐可以循环使用或转化为4-取代的N-烷基邻苯二甲酰亚胺，用于形成双酰亚胺（IV），从而避免了硝化步骤的需要。

公开(公告)号：US09414547B2

公开(公告)日：2016-08-16

申请号：US13754847

申请日：2013-01-30

Applicant: Thomas Link Guggenheim ,  Roy Ray Odle

Inventor： Thomas Link Guggenheim ,  Roy Ray Odle

IPC: A01G9/02 ,  A01G1/00 ,  A01G13/00 ,  A01G9/10

CPC classification number: A01G1/001 ,  A01G9/026 ,  A01G9/0299 ,  A01G13/0243 ,  A01G22/00

Abstract: Methods to grow, provide and plant a young tree using a novel removable tubular container are disclosed. The container promotes the growth of a well formed protected root structure that minimizes transplant shock at the time the young tree is moved and permanently planted. The removable container and methods described provide for a fast growing inexpensive tree that is easily planted by a single person.

Abstract translation: 公开了使用新型可移除管状容器生长，提供和种植幼树的方法。 该容器促进形成良好形成的保护根结构的生长，使幼树移动和永久种植时的移植冲击最小化。 所描述的可移动容器和方法提供了一种快速增长的便宜的树，其容易由单个人种植。

公开(公告)号：US09161440B2

公开(公告)日：2015-10-13

申请号：US11758773

申请日：2007-06-06

Applicant: Kwok Pong Chan ,  Erik Hagberg ,  Tara J. Mullen ,  Roy Ray Odle

Inventor： Kwok Pong Chan ,  Erik Hagberg ,  Tara J. Mullen ,  Roy Ray Odle

IPC: B32B15/08 ,  C08G69/28 ,  C08K3/34 ,  H05K1/03 ,  C08G73/10 ,  C08J5/18 ,  C08L79/08

CPC classification number: H05K1/0346 ,  B32B15/08 ,  C08G73/1007 ,  C08J5/18 ,  C08J2379/08 ,  C08K3/346 ,  C08L79/08 ,  H05K2201/0154 ,  H05K2201/068 ,  Y10T428/12569 ,  Y10T428/2938 ,  Y10T428/31765

Abstract: An article comprises a solvent cast film comprising a polyetherimide comprising structural units derived from a dianhydride component selected from the group consisting of 3,4′-oxydiphthalic anhydride, 3,3′-oxydiphthalic anhydride, 4,4′-oxydiphthalic anhydride, and combinations thereof, and a diamine component. The polyetherimide has a glass transition temperature that is at least 190° C. The film has a coefficient of thermal expansion of less than 60 ppm/° C., a thickness from 0.1 to 250 micrometers, and less than 5% residual solvent by weight. The film has less than 15 molar % of a member selected from the group consisting of biphenyltetracarboxylic acid, dianhydrides of biphenyltetracarboxylic acid, esters of biphenyltetracarboxylic acid, and combinations thereof.

Abstract translation: 一种制品包括含有聚醚酰亚胺的溶剂流延膜，该聚醚酰亚胺包含衍生自二酐组分的结构单元，所述二酐组分选自3,4'-氧联二邻苯二甲酸酐，3,3'-氧联二邻苯二甲酸酐，4,4'-氧联二邻苯二甲酸酐和组合 和二胺组分。 聚醚酰亚胺的玻璃化转变温度至少为190℃。该薄膜的热膨胀系数小于60ppm /℃，厚度为0.1至250微米，小于5％的残留溶剂重量 。 该膜具有少于15摩尔％的选自联苯四羧酸，联苯四羧酸的二酐，联苯四羧酸的酯及其组合的成员。

公开(公告)号：US09040651B2

公开(公告)日：2015-05-26

申请号：US13285043

申请日：2011-10-31

Applicant: Eric Lee Lutz ,  William Hoy Heath ,  Roy Ray Odle ,  Thomas Link Guggenheim ,  Juan Justino Rodriguez Ordonez ,  Jose Roman Galdamez Pena

Inventor： Eric Lee Lutz ,  William Hoy Heath ,  Roy Ray Odle ,  Thomas Link Guggenheim ,  Juan Justino Rodriguez Ordonez ,  Jose Roman Galdamez Pena

IPC: C08G75/00 ,  C08G75/23 ,  C08G65/40 ,  C08G65/00

CPC classification number: C08G75/23 ,  C08G65/00 ,  C08G65/40 ,  C08G65/4056

Abstract: A poly(aryl ether sulfone) comprises units of formula (I): wherein Ar1 is a divalent C6-C15 aromatic group, Ar2 is a divalent C6-C15 aromatic group, Ar3 is a divalent C6-C15 aromatic group, and n is greater than 1; and a terminal group of formula (II) derived from a monofunctional phenoxide wherein is X is a hydrogen atom or an organic substituent having from 1 to 20 carbon atoms; wherein the poly(aryl ether sulfone) has a hydroxyl group content greater than 0 and less than 50 parts per million (ppm), based on the poly(aryl ether sulfone) weight, a glass transition temperature of 180 to 290° C., a weight average molecular weight of 20,000 to 100,000, a halogen content of greater than 0 and less than 3000 ppm based on the poly(aryl ether sulfone) weight. The poly(aryl ether sulfone) is free of methoxy groups.

Abstract translation: 聚（芳基醚砜）包括式（I）的单元：其中Ar1是二价C 6 -C 15芳族基团，Ar 2是二价C 6 -C 15芳族基团，Ar 3是二价C 6 -C 15芳族基团，n大于 比1; 和衍生自单官能酚盐的式（II）的末端基团，其中X为氢原子或具有1至20个碳原子的有机取代基; 其中聚（芳基醚砜）的羟基含量大于0且小于50ppm（ppm），基于聚（芳基醚砜）重量，玻璃化转变温度为180-290℃， 重均分子量为20,000至100,000，卤素含量大于0且小于3000ppm，基于聚（芳基醚砜）重量。 聚（芳基醚砜）不含甲氧基。

公开(公告)号：US20140208645A1

公开(公告)日：2014-07-31

申请号：US13754847

申请日：2013-01-30

Applicant: Thomas Link Guggenheim ,  Roy Ray Odle

Inventor： Thomas Link Guggenheim ,  Roy Ray Odle

IPC: A01G1/00 ,  A01G9/02

CPC classification number: A01G1/001 ,  A01G9/026 ,  A01G9/0299 ,  A01G13/0243 ,  A01G22/00

Abstract: Methods to grow, provide and plant a young tree using a novel removable tubular container are disclosed. The container promotes the growth of a well formed protected root structure that minimizes transplant shock at the time the young tree is moved and permanently planted. The removable container and methods described provide for a fast growing inexpensive tree that is easily planted by a single person.

Abstract translation: 公开了使用新型可移除管状容器生长，提供和种植幼树的方法。 该容器促进形成良好形成的保护根结构的生长，使幼树移动和永久种植时的移植冲击最小化。 所描述的可移动容器和方法提供了一种快速增长的便宜的树，其容易由单个人种植。

公开(公告)号：US08568867B2

公开(公告)日：2013-10-29

申请号：US11758796

申请日：2007-06-06

Applicant: Kwok Pong Chan ,  Erik Hagberg ,  Tara J. Mullen ,  Roy Ray Odle

Inventor： Kwok Pong Chan ,  Erik Hagberg ,  Tara J. Mullen ,  Roy Ray Odle

IPC: B32B5/16 ,  B32B15/08 ,  B32B27/28

CPC classification number: H05K1/0346 ,  C08G73/1007 ,  C08J5/18 ,  C08J2379/08 ,  C08L79/08 ,  H05K1/0373 ,  H05K2201/0154 ,  H05K2201/0209 ,  H05K2201/0257 ,  H05K2201/068 ,  Y10T428/12569 ,  Y10T428/25 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31721

Abstract: A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4′-oxydiphthalic dianhydride, 3,3′-oxydiphthalic dianhydride, 4,4′-oxydiphthalic dianhydride, and combinations thereof, with a diamine component comprising 4,4′-diaminodiphenylsulfone; wherein the polyimide has a glass transition temperature from 190° C. to 400° C.; and wherein the film has a coefficient of thermal expansion of less than 60 ppm/° C., a thickness from 0.1 to 250 micrometers, endless than 5% residual solvent by weight.

Abstract translation: 溶剂流延膜包括聚酰亚胺，其包含衍生自二酐组分的聚合的结构单元，所述二酐组分包含二酐，其选自3,4'-氧二邻苯二甲酸二酐，3,3'-氧联二邻苯二甲酸二酐，4,4'-氧联二邻苯二甲酸二酐， 和其组合与二胺组分包含4,4'-二氨基二苯砜; 其中所述聚酰亚胺的玻璃化转变温度为190℃至400℃; 并且其中所述膜具有小于60ppm /℃的热膨胀系数，0.1至250微米的厚度，不超过5重量％的残留溶剂。