公开(公告)号：US10975221B2

公开(公告)日：2021-04-13

申请号：US16344051

申请日：2017-10-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Shijing Cheng ,  Sheng Ye ,  David J. Yarusso ,  Jianhui Xia

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08K5/07 ,  C09J7/38 ,  C08K5/00 ,  C08K5/45 ,  C08K5/56 ,  C08L33/10 ,  C09J133/10 ,  C09J133/02

Abstract: The present disclosure provides a crosslinkable composition including a (meth)acrylate polymer and a visible light absorbing compound. Two percent or less of the carbon-carbon bonds in the crosslinkable composition are double bonds. The composition allows for inclusion of one or more materials degradable by ultraviolet radiation and/or stabilized against ultraviolet radiation. Methods for making a crosslinked composition is also provided. One method includes obtaining a crosslinkable composition and subjecting the crosslinkable composition to radiation having a wavelength of 400 nm or greater. Another method includes subjecting a crosslinkable composition to first and second radiations that are different from each other.

公开(公告)号：US10927276B2

公开(公告)日：2021-02-23

申请号：US15576407

申请日：2016-06-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Cyrus A. Anderson ,  Thomas Q. Chastek ,  Xiao Gao ,  Kathleen S. Shafer ,  Sheng Ye

IPC: B32B17/10 ,  C09J5/00 ,  C09J163/00 ,  C08L71/00 ,  B32B7/12 ,  B32B37/12 ,  C09J131/04 ,  C09J167/00

Abstract: Methods of bonding hardware to glass and other substrates are provided that do not require use of primers, mixing, fixturing, or autoclaving. These methods include the steps of disposing an adhesive layer on a bonding surface of either the hardware or the vehicular glass, the adhesive layer comprising a curable composition that is dimensionally stable at ambient conditions; either before or after disposing the adhesive layer on the bonding surface, irradiating the adhesive layer with ultraviolet radiation to initiate curing of the curable composition; placing the hardware so as to be bonded to the vehicular glass by the adhesive layer; and allowing the adhesive layer to cure.

公开(公告)号：US20200347874A1

公开(公告)日：2020-11-05

申请号：US16932724

申请日：2020-07-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jonathan D. Zook ,  Larry S. Hebert ,  Michael D. Swan ,  Sheng Ye ,  Susan E. DeMoss ,  Robin E. Wright

IPC: F16B37/14 ,  B64D45/02

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and methods of their use, and in particular light weight seal caps having higher dielectric breakdown strength, lower weight, and/or lower wall thickness. In some embodiments, the seal caps according to the present invention are made of a material having a dielectric breakdown strength of greater than 1.0 kV/mm, in some embodiments greater than 15.0 kV/mm, and in some embodiments greater than 50.0 kV/mm. In some embodiments, the seal caps according to the present invention are thin-walled, having an average wall thickness of less than 1.5 mm and in some embodiments less than less than 0.5 mm. In some embodiments, the seal cap comprises a polyurethane polymer, a polythioether polymer, a polysulfide polymer, a fluorinated thermoplastic polymer, a THV polymer, a fluorinated thermoset polymer, an engineering thermoplastic, and/or a PEEK polymer.

公开(公告)号：US20200308403A1

公开(公告)日：2020-10-01

申请号：US16946253

申请日：2020-06-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Sheng Ye ,  Junting Li ,  Yizhong Wang ,  Joel D. Oxman ,  Susan E. DeMoss ,  Jonathan D. Zook

IPC: C08L81/02 ,  B64D45/02 ,  C08G18/04 ,  C08G75/02 ,  C09J181/02 ,  C08L81/00 ,  C08G75/00 ,  B05D3/02 ,  C08F8/34

Abstract: Compositions that are curable to polythioether polymers are provided, comprising: a) a dithiol monomer; b) a diene monomer; c) a radical cleaved photoinitiator; d) a peroxide; and e) an amine; where the peroxide and amine together are a peroxide-amine redox initiator. In some embodiments, the amine is a tertiary amine. In some embodiments, the amine is selected from the group consisting of dihydroxyethyl-p-toluidine, N,N-diisopropylethylamine, and N, N, N′, N″, N″-pentamethyl-diethylenetriamine. In some embodiments, the peroxide is selected from the group consisting of di-tert-butyl peroxide, methyl ethyl ketone peroxide, and benzoyl peroxide. In some embodiments, the composition may additionally comprise a polythiol monomer having three or more thiol groups

公开(公告)号：US20200181387A1

公开(公告)日：2020-06-11

申请号：US16629429

申请日：2018-07-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Xuan Jiang ,  Jeffrey N. Bartow ,  Robert J. DeVoe ,  Tatsuo Fukushi ,  Klaus Hintzer ,  Tho Q. Nguyen ,  Sheng Ye ,  Fee Zentis

IPC: C08L27/20 ,  C08F214/22 ,  C08K5/357 ,  C08K5/14 ,  B29C35/08

Abstract: Described herein is a curable composition comprising an amorphous fluoropolymer having an iodine, bromine and/or nitrile cure site; a peroxide cure system comprising a peroxide and a Type II coagent; and a photoinitiator, wherein the curable composition is substantially free of a binder material. Also described herein, are methods of curing the curable composition using actinic radiation and articles thereof.

公开(公告)号：US10183758B2

公开(公告)日：2019-01-22

申请号：US15467147

申请日：2017-03-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jonathan D. Zook ,  Larry S. Hebert ,  Michael D. Swan ,  Sheng Ye ,  Susan E. DeMoss ,  Robin E. Wright

IPC: F16B33/00 ,  B64D37/06 ,  B64D45/02 ,  F16B37/14 ,  B64D37/02

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and in particular translucent or transparent seals or seal caps. In some embodiments, a seal cap which is optically translucent and optionally visibly transparent contains an uncured sealant, which is optionally optically translucent or visibly transparent, and is applied to a fastener. In some embodiments, the sealant is cured by application of actinic radiation to the sealant through the seal cap. In another aspect, a protected fastener construction is provided comprising: q) a fastener; r) a seal cap; and s) a cured sealant; wherein the sealant is optically translucent and optionally visibly transparent.

公开(公告)号：US10072135B2

公开(公告)日：2018-09-11

申请号：US15109385

申请日：2014-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Sheng Ye ,  Kathleen S. Shafer ,  Michael S. Wendland ,  Jonathan D. Zook ,  Susan E. DeMoss

IPC: C07D277/82 ,  C08K5/47 ,  C09J11/06 ,  C09J181/02 ,  G01N21/25 ,  G01N33/44 ,  C09B29/033 ,  C08K5/00 ,  G01N21/17

CPC classification number: C08K5/47 ,  C07D277/82 ,  C08K5/0041 ,  C09B29/0088 ,  C09B29/0813 ,  C09B29/0823 ,  C09B69/106 ,  C09J11/06 ,  C09J181/02 ,  G01N21/25 ,  G01N33/442 ,  G01N2021/1748 ,  G01N2021/1761 ,  C08L81/02

Abstract: A curable composition having a polythiol; at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof; and a dye compound represented by formula: A crosslinked composition prepared from the curable composition, a method for indicating curing in a curable composition, and a method of stabilizing a curable composition comprising a polythiol and at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof are also disclosed.

公开(公告)号：US20170362434A1

公开(公告)日：2017-12-21

申请号：US15533758

申请日：2015-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Sheng Ye ,  Junting Li ,  Yizhong Wang ,  Joel D. Oxman ,  Susan E. DeMoss ,  Jonathan D. Zook

IPC: C08L81/02 ,  C08L81/00 ,  C08G18/04 ,  B05D3/02 ,  C08F8/34 ,  B64D45/02 ,  C09J181/02 ,  C08G75/02

CPC classification number: C08L81/02 ,  B05D3/02 ,  B64D45/02 ,  C08F8/34 ,  C08G18/04 ,  C08G75/00 ,  C08G75/02 ,  C08L81/00 ,  C09J181/02

Abstract: Compositions that are curable to polythioether polymers are provided, comprising: a) a dithiol monomer; b) a diene monomer; c) a radical cleaved photoinitiator; d) a peroxide; and e) an amine; where the peroxide and amine together are a peroxide-amine redox initiator. In some embodiments, the amine is a tertiary amine. In some embodiments, the amine is selected from the group consisting of dihydroxyethyl-p-toluidine, N,N-diisopropylethylamine, and N, N, N′, N″, N″-pentamethyl-diethylenetriamine. In some embodiments, the peroxide is selected from the group consisting of di-tert-butyl peroxide, methyl ethyl ketone peroxide, and benzoyl peroxide. In some embodiments, the composition may additionally comprise a polythiol monomer having three or more thiol groups.

公开(公告)号：US20160374531A1

公开(公告)日：2016-12-29

申请号：US15024621

申请日：2016-02-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Paul N. Daveloose ,  Matthew S. Cole ,  Ibrahim S. Gunes ,  Sheng Ye ,  Stewart H. Corn ,  Deval Y. Vashistha ,  Shridhar B. Shinde

IPC: A47L13/17

CPC classification number: A47L13/17 ,  A47L13/16 ,  C08J9/365 ,  C08J2301/02 ,  C08J2375/04

Abstract: A scrubbing article including a substrate and a UV treated texture layer on a surface of the substrate. The substrate is formed from a single layer of foam or sponge material having a thickness that is conducive to handling or holding. The UV treated texture layer is a resin-based material forming a textured abrasive layer on the surface of the substrate.

Abstract translation: 一种洗涤物品，其在基材的表面上具有基材和UV处理的织构层。 衬底由具有有利于处理或保持的厚度的单层泡沫或海绵材料形成。 UV处理的纹理层是在基材表面上形成纹理磨料层的树脂基材料。

公开(公告)号：US20160068274A1

公开(公告)日：2016-03-10

申请号：US14783913

申请日：2014-04-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jonathan D. Zook ,  Larry S. Hebert ,  Michael D. Swan ,  Sheng Ye ,  Susan E. DeMoss ,  Robin E. Wright

IPC: B64D37/06

CPC classification number: B64D37/06 ,  B64D37/02 ,  B64D45/02 ,  F16B33/004 ,  F16B37/14

Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and in particular translucent or transparent seals or seal caps. In some embodiments, a seal cap which is optically translucent and optionally visibly transparent contains an uncured sealant, which is optionally optically translucent or visibly transparent, and is applied to a fastener. In some embodiments, the sealant is cured by application of actinic radiation to the sealant through the seal cap. In another aspect, a protected fastener construction is provided comprising: q) a fastener; r) a seal cap; and s) a cured sealant; wherein the sealant is optically translucent and optionally visibly transparent.

Abstract translation: 本公开提供了用于密封紧固件，包括密封帽，特别是半透明或透明密封件或密封帽的方法和制品。 在一些实施例中，光学半透明并且可选地可见地透明的密封盖包含未固化的密封剂，其是任选的光学半透明或可见透明的，并被施加到紧固件。 在一些实施例中，通过将光化辐射施加到通过密封帽的密封剂来固化密封剂。 在另一方面，提供了一种受保护的紧固件结构，包括：q）紧固件; r）密封盖; 和s）固化的密封剂; 其中所述密封剂是光学半透明的并且可选地可视地透明。