公开(公告)号：US20240287648A1

公开(公告)日：2024-08-29

申请号：US18582791

申请日：2024-02-21

Applicant: CORNING INCORPORATED

Inventor： David Eugene Baker ,  Deqiu Fan ,  Qiang Fu ,  Yuhui Jin ,  Grace MaryAlice Yu Leahy ,  William James McKendrick ,  Cedrick Alexander O’Shaughnessy

IPC: C22B26/12 ,  C22B7/00 ,  H01M10/54

CPC classification number: C22B26/12 ,  C22B7/001 ,  H01M10/54

Abstract: A method for extracting lithium metal ions from glass includes contacting the glass with a molten salt bath for a duration of time, wherein the glass includes lithium and the contacting the glass with the molten salt bath for the duration of time extracts at least 40% of the lithium metal ions from the glass. The method further includes removing residual solids from the molten salt bath, wherein the residual solids include residual glass having a reduced concentration of lithium. The method further includes precipitating lithium metal ions from the molten salt bath to produce a solid precipitated lithium salt and separating the precipitated lithium salt from the molten salt bath.

公开(公告)号：US12071364B2

公开(公告)日：2024-08-27

申请号：US18133106

申请日：2023-04-11

Applicant: CORNING INCORPORATED

Inventor： Carol Ann Click ,  James Howard Edmonston ,  Qiang Fu ,  Jill Marie Hall ,  Mathieu Gerard Jacques Hubert ,  Dhananjay Joshi ,  Andrew Peter Kittleson ,  Katherine Weber Kroemer ,  Galan Gregory Moore ,  Rohit Rai ,  John Richard Ridge ,  John Robert Saltzer, Jr. ,  Charlene Marie Smith ,  Erika Lynn Stapleton ,  Matthew Daniel Trosa ,  Ljerka Ukrainczyk ,  Shelby Kerin Wilson ,  Bin Yang ,  Zheming Zheng

IPC: C03C4/18 ,  C03C10/00 ,  H05K5/03 ,  H05K5/00

CPC classification number: C03C10/0027 ,  C03C4/18 ,  H05K5/03 ,  C03C2204/00 ,  H05K5/0017

Abstract: A glass ceramic article including a lithium disilicate crystalline phase, a petalite crystalline phased, and a residual glass phase. The glass ceramic article has a warp (μm) 0.91×10(2-0.03t) of electromagnetic radiation wavelengths from 450 nm to 800 nm, where t is the thickness of the glass ceramic article in mm.

公开(公告)号：US20240279108A1

公开(公告)日：2024-08-22

申请号：US18641770

申请日：2024-04-22

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Matthew John Dejneka ,  Qiang Fu ,  Sinue Gomez ,  Robert Michael Morena ,  Charlene Marie Smith

IPC: C03C3/087 ,  B32B17/06 ,  C03C3/085 ,  C03C3/091 ,  C03C3/093 ,  C03C3/097 ,  C03C4/18 ,  C03C21/00 ,  H05K5/00 ,  H05K5/03

CPC classification number: C03C3/087 ,  B32B17/06 ,  C03C3/085 ,  C03C3/091 ,  C03C3/093 ,  C03C3/097 ,  C03C21/002 ,  H05K5/03 ,  B32B2307/50 ,  C03C4/18 ,  C03C2204/00 ,  H05K5/0017

Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 μm; in others, at least about 100 μm. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.

公开(公告)号：US20240182352A1

公开(公告)日：2024-06-06

申请号：US18386292

申请日：2023-11-02

Applicant: CORNING INCORPORATED

Inventor： Qiang Fu ,  Yuhui Jin ,  William James McKendrick ,  Cedrick Alexander O’Shaughnessy ,  Wei Sun

IPC: C03C3/085

CPC classification number: C03C3/085 ,  C03C21/002

Abstract: A method of regenerating a lithium-poisoned molten salt bath is provided. The method includes contacting glass particulates with the molten salt bath such that poisoning ions are exchanged from the bath into the glass. The glass compositions utilized in the method are also provided.

公开(公告)号：US20240140854A1

公开(公告)日：2024-05-02

申请号：US18279254

申请日：2022-03-01

Applicant: CORNING INCORPORATED

Inventor： Qiang Fu ,  Aize Li ,  Hugh Michael McMahon

IPC: C03C3/078 ,  C03B37/02 ,  C03C3/062 ,  C03C3/097 ,  C03C3/112 ,  C03C4/00

CPC classification number: C03C3/078 ,  C03B37/02 ,  C03C3/062 ,  C03C3/097 ,  C03C3/112 ,  C03C4/0021

Abstract: A silicate-based glass composition includes 15-65 wt. % SiO2, 2.5-25 wt. % MgO, 1-30 wt. % P2O5, and 15-50 wt. % CaO, such that the composition has a hydrolytic resistance of glass grains (HGB) of at most 3, when measured by International Organization for Standardization section 719 (ISO 719) and forms a bioactive crystalline phase in a simulated body fluid.

公开(公告)号：US11840475B2

公开(公告)日：2023-12-12

申请号：US17864693

申请日：2022-07-14

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Charlene Marie Smith

IPC: C03C10/00 ,  C03C1/04 ,  C03C4/02

CPC classification number: C03C10/0027 ,  C03C1/04 ,  C03C4/02 ,  C03C2204/00

Abstract: A glass-ceramic article comprises a petalite crystalline phase and a lithium silicate crystalline phase. The weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article. The glass-ceramic article has a transmittance color coordinate in the CIELAB color space of: L*=from 20 to 90; a*=from −20 to 40; and b*=from −60 to 60 for a CIE illuminant F02 under SCI UVC conditions. In some embodiments, the colorant is selected from the group consisting of TiO2, Fe2O3, NiO, Co3O4, MnO2, Cr2O3, CuO, Au, Ag, and V2O5.

公开(公告)号：US20230348319A1

公开(公告)日：2023-11-02

申请号：US18211702

申请日：2023-06-20

Applicant: CORNING INCORPORATED

Inventor： Carol Ann Click ,  Qiang Fu ,  Mathieu Gerard Jacques Hubert ,  Charlene Marie Smith ,  Alana Marie Whittier

IPC: C03C10/00 ,  C03C4/02 ,  C03C21/00

CPC classification number: C03C10/0027 ,  C03C4/02 ,  C03C10/0036 ,  C03C21/002 ,  C03C21/005

Abstract: A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO2; 0.2-10 mol % Al2O3; 0-5 mol % B2O3; 15-30 mol % Li2O; 0-2 mol % Na2O; 0-2 mol % K2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P2O5; 0.1-10 mol % ZrO2; 0-4 mol % TiO2; and 0-1.0 mol % SnO2. Lithium disilicate and either β-spodumene or β-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na2O (on an oxide basis), with the mole percentage of Na2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.

公开(公告)号：US20230242437A1

公开(公告)日：2023-08-03

申请号：US18131556

申请日：2023-04-06

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Charlene Marie Smith

IPC: C03C10/00 ,  C03B32/02 ,  C03C3/097 ,  C03C21/00 ,  C03C4/02

CPC classification number: C03C10/0027 ,  C03B32/02 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C4/02 ,  C03C2204/00

Abstract: In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO2; from about 2 wt. % to about 20 wt. % Al2O3; from about 5 wt. % to about 20 wt. % Li2O; greater than 0 wt % to about 3 wt. % Na2O; a non-zero amount of P2O5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO2. In embodiments, ZrO2 (wt. %)+P2O5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.

公开(公告)号：US11649187B2

公开(公告)日：2023-05-16

申请号：US17237272

申请日：2021-04-22

Applicant: CORNING INCORPORATED

Inventor： Carol Ann Click ,  James Howard Edmonston ,  Qiang Fu ,  Jill Marie Hall ,  Mathieu Gerard Jacques Hubert ,  Dhananjay Joshi ,  Andrew Peter Kittleson ,  Katherine Weber Kroemer ,  Galan Gregory Moore ,  Rohit Rai ,  John Richard Ridge ,  John Robert Saltzer, Jr. ,  Charlene Marie Smith ,  Erika Lynn Stapleton ,  Matthew Daniel Trosa ,  Ljerka Ukrainczyk ,  Shelby Kerin Wilson ,  Bin Yang ,  Zheming Zheng

IPC: C03C4/18 ,  C03C10/00 ,  H05K5/03 ,  H05K5/00

CPC classification number: C03C10/0027 ,  C03C4/18 ,  H05K5/03 ,  C03C2204/00 ,  H05K5/0017

Abstract: A glass ceramic article including a lithium disilicate crystalline phase, a petalite crystalline phased, and a residual glass phase. The glass ceramic article has a warp (μm) 0.91×10(2−0.03t) of electromagnetic radiation wavelengths from 450 nm to 800 nm, where t is the thickness of the glass ceramic article in mm.

公开(公告)号：US20230045516A1

公开(公告)日：2023-02-09

申请号：US17782379

申请日：2020-12-09

Applicant: CORNING INCORPORATED

Inventor： Pei-Chen Chiang ,  Qiang Fu ,  Cheng-I Hsu ,  Wei-Lun Hsu

IPC: C12N15/87 ,  C03C12/00 ,  C03C17/28 ,  C03C3/064 ,  C03C3/097 ,  C03C3/112 ,  C03C4/00 ,  C03C8/06 ,  C03C8/08 ,  C03C8/16

Abstract: A pH-switchable carrier composition includes a plurality of bioactive glass particles, wherein each of the bioactive glass particle is optionally at least a partially coated with a surface modifier; wherein the bioactive glass particles, with or without, the surface modifier can bind to a nucleic acid compound upon contact at pH in the range of about 7 to about 11, and exhibit controlled release of the nucleic acid compound at pH in the range of about 5 to 6.