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41.
公开(公告)号:US20200071626A1
公开(公告)日:2020-03-05
申请号:US16545976
申请日:2019-08-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Kapil Kandel , Teng Xu , Glenn A. Heeter , Frank Cheng-Yu Wang , Anthony S. Mennito , David T. Ferrughelli , Krystle J. Emanuele
IPC: C10G47/24
Abstract: Processes for improving hydrocarbon feedstock compatibility are provided. More specifically, a process for preparing a liquid hydrocarbon product includes heat soaking a tar stream to produce a reduced reactivity tar and blending the reduced reactivity tar with a utility fluid comprising recycle solvent to produce a lower viscosity, reduced reactivity tar. The process also includes hydroprocessing the lower viscosity, reduced reactivity tar at a temperature of greater than 350° C. to produce a total liquids product containing the liquid hydrocarbon product and the recycle solvent. The process further includes separating the recycle solvent from the total liquids product, where the recycle solvent has the SBN of greater than 110, and flowing the recycle solvent to the reduced reactivity tar for blending to produce the lower viscosity, reduced reactivity tar.
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公开(公告)号:US10052617B2
公开(公告)日:2018-08-21
申请号:US14967612
申请日:2015-12-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Neeraj Sangar , Teng Xu , Larry L. Iaccino , Mobae Afeworki
CPC classification number: B01J29/48 , B01J29/076 , B01J29/90 , B01J35/002 , B01J38/06 , B01J38/14 , B01J2229/186 , B01J2229/36 , B01J2229/40 , C07C2/76 , C07C2529/48 , C10G50/00 , C10G2300/1025 , C10G2400/30 , Y02P20/584 , Y02P20/588 , C07C15/00
Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises molybdenum or a compound thereof dispersed on an aluminosilicate zeolite, wherein the amount of aluminum present as aluminum molybdate in the catalyst is less than 2700 ppm by weight.
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公开(公告)号:US10035961B2
公开(公告)日:2018-07-31
申请号:US14713611
申请日:2015-05-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: James H. Beech, Jr. , Reyyan Koc-Karabocek , Christopher M. Evans , Jeffrey C. Yeh , Teng Xu
CPC classification number: C10G67/02 , B01J8/007 , B01J2208/00946 , C10G31/09 , C10G31/10 , C10G47/36 , C10G67/04
Abstract: Aspects of the invention provide a process for upgrading a hydrocarbon feed. The process includes providing a hydrocarbon feed and a utility fluid. Then selectively extracting from the feed at least a portion of particulates to produce a raffinate and an extract. Third hydroprocessing at least a portion of the raffinate.
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公开(公告)号:US10000710B2
公开(公告)日:2018-06-19
申请号:US14639272
申请日:2015-03-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: David T. Ferrughelli , Emmanuel Ulysse , Teng Xu
IPC: C10G47/06 , C10G47/26 , C10G49/04 , C10G49/12 , C10G69/06 , C10G47/12 , C10G45/14 , C10G45/66 , C10G47/24 , C10G49/10
CPC classification number: C10G47/06 , C10G45/14 , C10G45/66 , C10G47/12 , C10G47/24 , C10G47/26 , C10G49/04 , C10G49/10 , C10G49/12 , C10G69/06
Abstract: A process for upgrading pyrolysis tar to higher value products. More particularly, this invention relates to the upgrading of steam cracker tar using relatively small amounts of a transition metal sulfide-containing particulate catalyst dispersed throughout the tar chargestock and in the presence of hydrogen, at relatively mild hydroconversion conditions.
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公开(公告)号:US09657239B2
公开(公告)日:2017-05-23
申请号:US14683511
申请日:2015-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: James H. Beech, Jr. , Reyyan Koc-Karabocek , William E. Lewis , Teng Xu
IPC: C10G69/06 , C10G49/00 , C10G49/22 , C10G45/02 , C10G45/44 , C10G45/58 , C10G47/00 , C10G69/00 , C10G49/24 , C10L1/04
CPC classification number: C10G69/06 , C10G45/02 , C10G45/44 , C10G45/58 , C10G47/00 , C10G49/00 , C10G49/22 , C10G2300/4081 , C10L1/04
Abstract: The invention relates to a process for upgrading pyrolysis tar in the presence of a utility fluid. The utility fluid contains 1-ring and/or 2-ring aromatics and has a final boiling point ≦430° C. The invention also relates to the upgraded pyrolysis tar, and to the use of the upgraded pyrolysis tar, e.g., for fuel oil blending.
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公开(公告)号:US20150344790A1
公开(公告)日:2015-12-03
申请号:US14639272
申请日:2015-03-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: David T. Ferrughelli , Emmanuel Ulysse , Teng Xu
IPC: C10G47/12
CPC classification number: C10G47/06 , C10G45/14 , C10G45/66 , C10G47/12 , C10G47/24 , C10G47/26 , C10G49/04 , C10G49/10 , C10G49/12 , C10G69/06
Abstract: A process for upgrading pyrolysis tar to higher value products. More particularly, this invention relates to the upgrading of steam cracker tar using relatively small amounts of a transition metal sulfide-containing particulate catalyst dispersed throughout the tar chargestock and in the presence of hydrogen, at relatively mild hydroconversion conditions.
Abstract translation: 将热解焦油升级为更高价值产品的过程。 更具体地说,本发明涉及在相对温和的加氢转化条件下,使用相对少量的分散在焦油装料中的氢过渡金属硫化物的颗粒催化剂升级蒸汽裂解焦油。
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公开(公告)号:US20150315496A1
公开(公告)日:2015-11-05
申请号:US14683458
申请日:2015-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Nikolaos Soultanidis , John S. Buchanan , Christopher M. Evans , David T. Ferrughelli , Luc R. M. Martens , Keith G. Reed , Frank C. Wang , Teng Xu , Cathleen Yung
CPC classification number: C10G49/00 , C10G49/22 , C10G49/24 , C10G69/00 , C10G69/06 , C10G2300/4031 , C10G2300/4081 , C10L1/04
Abstract: The invention relates to a utility fluid, such as a fluid containing aromatic and non-aromatic ringed molecules, useful as a diluent when hydroprocessing pyrolysis tar, such as steam cracker tar. The specified utility fluid comprises ≧10.0 wt % aromatic and non-aromatic ring compounds and each of the following: (a) ≧1.0 wt % of 1.0 ring class compounds; (b) ≧5.0 wt % of 1.5 ring class compounds; (c) ≧5.0 wt % of 2.0 ring class compounds; and (d) ≦0.1 wt % of 5.0 ring class compounds. The invention also relates to methods for producing such a utility fluid and to processes for hydroprocessing pyrolysis tar.
Abstract translation: 本发明涉及一种效用流体,例如含有芳族和非芳族环状分子的流体,当加氢处理热解焦油(例如蒸汽裂解焦油)时可用作稀释剂。 指定的实用流体包含≥10.0重量%的芳香族和非芳香族环化合物,以下各项:(a)1.0重量%的1.0个环类化合物; (b)≥5.0重量%的1.5种环类化合物; (c)2.0重量%的2.0环类化合物; 和(d)≦̸ 0.1重量%的5.0环类化合物。 本发明还涉及制备这种效用流体的方法和用于加氢处理热解焦油的方法。
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公开(公告)号:US11939543B2
公开(公告)日:2024-03-26
申请号:US17264951
申请日:2019-07-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Teng Xu , James R. Lattner , Frank Cheng-Yu Wang , Bryan Tiedemann , Renyuan Yu
CPC classification number: C10G9/16 , C10G9/36 , C10G45/28 , C10G69/06 , C10G75/04 , C10G2300/202 , C10G2300/301 , C10G2300/4081 , C10G2300/42 , C10G2300/44 , C10G2300/807 , C10G2400/18 , C10G2400/30
Abstract: In an embodiment, a method for decreasing reactor fouling in a steam cracking process is provided. The method includes steam cracking a hydrocarbon feed to obtain a quench oil composition comprising a concentration of donatable hydrogen of 0.5 wt. % or more based on a total weight percent of the quench oil composition; exposing a steam cracker effluent flowing from a pyrolysis furnace to the quench oil composition to form a mixture; and fractionating the mixture in a separation apparatus to obtain a steam cracker tar. In another embodiment, a hydrocarbon mixture is provided. The hydrocarbon mixture includes a mid-cut composition.
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公开(公告)号:US11674093B2
公开(公告)日:2023-06-13
申请号:US17298972
申请日:2019-12-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John S. Coleman , Kapil Kandel , Michael J. Clemmons , Teng Xu , Giovanni S. Contello
CPC classification number: C10G55/04 , C10G69/06 , C10G2300/201 , C10G2300/206 , C10G2300/308 , C10G2300/4006
Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and includes blending a tar stream containing particles with a fluid to produce a fluid-feed mixture containing tar, the particles, and the fluid, and centrifuging the fluid-feed mixture at a temperature of greater than 60° C. to produce a higher density portion and a lower density portion, where the lower density portion contains no more than 25 wt % of the particles in the fluid-feed mixture.
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公开(公告)号:US20230174876A1
公开(公告)日:2023-06-08
申请号:US17998033
申请日:2021-05-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Maryam Peer Lachegurabi , Krystle J. Emanuele , Kapil Kandel , Frank Cheng-Yu Wang , Teng Xu
CPC classification number: C10G65/02 , C10G35/04 , C10G49/22 , C10G49/24 , C10G69/08 , C10G69/06 , C10G2300/802 , C10G2300/4081 , C10G2300/4031 , C10G2300/301 , C10G2300/308 , C10G2300/44 , C10G2300/202
Abstract: Hydrocarbon-containing fluids are provided for use during solvent-assisted hydroprocessing of pyrolysis tar, such as steam cracker tar. The hydrocarbon-containing fluids can be used at any convenient time, such as during start-up of a pyrolysis process when recycled liquid pyrolysis product is not available; when the amount of liquid pyrolysis product available for recycle is not sufficient to maintain desired hydroprocessing conditions; and/or when the changes to the quality of the liquid pyrolysis product reduce the suitability of the recycle stream for use as a utility fluid.
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