SORBENTS FOR THE OXIDATION AND REMOVAL OF MERCURY
    41.
    发明申请
    SORBENTS FOR THE OXIDATION AND REMOVAL OF MERCURY 有权
    氧化和去除汞的分子

    公开(公告)号:US20090297413A1

    公开(公告)日:2009-12-03

    申请号:US12429058

    申请日:2009-04-23

    Abstract: A promoted carbon and/or non-carbon base sorbent are described that are highly effective for the removal of mercury from flue gas streams. The promoted sorbent comprises a carbon and/or non-carbon base sorbent that has reacted with and contains forms of halogen and halides. Optional components may be added to increase and/or preserve reactivity and mercury capacity. These may be added directly with the base sorbent, or in-flight within a gas stream (air, flue gas, etc.), to enhance base sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The promoted sorbent can be regenerated and reused. Base sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active base sorbent into the mercury contaminated gas stream are described.

    Abstract translation: 描述了促进的碳和/或非碳碱吸附剂,其对于从烟道气流中除去汞是非常有效的。 促进的吸附剂包括与卤素和卤化物反应并含有卤素和卤素形式的碳和/或非碳碱吸附剂。 可以添加任选的组分以增加和/或保持反应性和汞容量。 这些可以直接与碱性吸附剂一起添加,或者在气流(空气,烟道气等)内飞行,以增强碱性吸附剂性能和/或汞捕获。 获得的汞去除效率超过常规方法。 促进的吸附剂可以再生和再利用。 还描述了基础吸附剂的处理和制备方法。 描述了将活性碱吸附剂引入汞污染气体流中的新的飞行前准备,引入和控制的方法。

    Process and composition for purifying hydrogen selenide and hydrogen
telluride, to remove moisture and oxidant impurities therefrom
    43.
    发明授权
    Process and composition for purifying hydrogen selenide and hydrogen telluride, to remove moisture and oxidant impurities therefrom 失效
    用于净化硒化氢和碲化氢的方法和组合物,以从中除去水分和氧化剂杂质

    公开(公告)号:US4797227A

    公开(公告)日:1989-01-10

    申请号:US80478

    申请日:1987-07-31

    Abstract: A scavenger, having utility for purifying a mixture comprising:(i) a primary component selected from one or more members of the group consisting of hydrogen selenide and hydrogen telluride, and(ii) impurities selected from one or more members of the group consisting of moisture and oxidants, comprising:(a) a support; and(b) associated with said support, one or more members of the group consisting of:(I) precursor compounds of the formula R.sub.3-x AlH.sub.x, wherein x is 0 or 1, and R is a hydrocarbon radical containing from 1 to 12 carbon atoms; and(II) aluminum chalconides of the formula Al.sub.2 M.sub.3, wherein M is selenium or tellurium.Illustrative supports useful in such scavenger include aluminosilicates, alumina, silica, carbon, and macroreticulate polymers. A process and apparatus are disclosed for purifying hydrogen selenide and/or hydrogen telluride, to remove moisture and/or oxidant impurities therefrom, in which a bed of the scavenger is employed.

    Abstract translation: 一种清除剂,其用于纯化混合物,其包含:(i)选自硒化氢和碲化氢中的一种或多种成员的主要成分,和(ii)选自以下的一种或多种成员的杂质: 水分和氧化剂,包括:(a)载体; 和(b)与所述载体相关联,所述组中的一个或多个成员由以下组成:(I)式R3-xAlHx的前体化合物,其中x为0或1,R为含有1至12碳的烃基 原子 和(II)式Al 2 M 3的铝金卤素,其中M是硒或碲。 在这种清除剂中有用的说明性的载体包括硅铝酸盐,氧化铝,二氧化硅,碳和大理石聚合物。 公开了一种用于净化硒化氢和/或碲化氢以从其中除去其中的水分和/或氧化剂杂质的方法和装置,其中采用清除剂床。

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