公开(公告)号：US08546286B2

公开(公告)日：2013-10-01

申请号：US12653511

申请日：2009-12-15

Applicant: Stephen J. McCarthy ,  Jean W. Beeckman

Inventor： Stephen J. McCarthy ,  Jean W. Beeckman

IPC: B01J29/06 ,  B01J33/00

CPC classification number: B01J37/0205 ,  B01J23/42 ,  B01J23/44 ,  B01J29/0325 ,  B01J29/043 ,  B01J29/068 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/088 ,  B01J37/10 ,  B01J37/18 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C10G45/54 ,  C10G2300/1096

Abstract: In a process for producing a metal containing catalyst composition suitable for effecting hydrocarbon hydrogenation and/or dehydrogenation reactions, a catalyst support comprising a porous crystalline material combined with an amorphous binder is treated with an anchoring material capable of bonding to the surface of the support and to a metal component. In addition, a precursor to the metal component is deposited on the surface of the catalyst support and then the treated catalyst support having the precursor deposited thereon is subjected to conditions effective to convert the precursor to the metal component and to cause the anchoring material to bond to the surface of the support and to the metal component.

Abstract translation: 在适用于进行烃氢化和/或脱氢反应的含金属催化剂组合物的制备方法中，将包含与无定形粘合剂结合的多孔结晶材料的催化剂载体用能够粘合到载体表面的锚定材料进行处理， 到金属部件。 另外，金属组分的前体沉积在催化剂载体的表面上，然后将其上沉积有前体的经处理的催化剂载体进行有效地将前体转化为金属组分并使锚定材料结合 到支撑体的表面和金属部件。

公开(公告)号：US20130251612A1

公开(公告)日：2013-09-26

申请号：US13888700

申请日：2013-05-07

Applicant: YASUYOSHI KATO ,  NAOMI IMADA ,  KEIICHIRO KAI

Inventor： YASUYOSHI KATO ,  NAOMI IMADA ,  KEIICHIRO KAI

IPC: B01J27/199 ,  B01D53/64

CPC classification number: B01J27/199 ,  B01D53/64 ,  B01D53/8628 ,  B01D53/8665 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01J21/063 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/06 ,  B01J37/0225 ,  B01J37/04 ,  B01J37/28

Abstract: An exhaust gas purification catalyst contains titanium oxide as a main component and an oxide of one element or two or more elements selected from the group consisting of tungsten (W), molybdenum (Mo), and vanadium (V) as an active component, wherein the exhaust gas purification catalyst contains phosphoric acid or a water soluble phosphoric acid compound so that the atomic ratio of phosphorus (P) to a catalytically active component represented by the following formula is more than 0 and 1.0 or less; P/catalytically active component (atomic ratio)=number of moles of P/(number of moles of W+number of moles of Mo+number of moles of V).

Abstract translation: 废气净化催化剂含有作为主要成分的氧化钛和选自钨（W），钼（Mo）和钒（V））作为活性成分的一种或两种以上的元素的氧化物，其中 废气净化催化剂含有磷酸或水溶性磷酸化合物，使得磷（P）与下式所示的催化活性成分的原子比大于0且为1.0以下; P /催化活性成分（原子比）= P /摩尔数（W的摩尔数+ Mo的摩尔数+ V的摩尔数）。

公开(公告)号：US20130190166A1

公开(公告)日：2013-07-25

申请号：US13821376

申请日：2011-09-05

Applicant: Yasuyoshi Kato ,  Seiji Ikemoto

Inventor： Yasuyoshi Kato ,  Seiji Ikemoto

IPC: B01D53/56 ,  B01J29/26

CPC classification number: B01D53/565 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/50 ,  B01D2255/504 ,  B01D2255/70 ,  B01J21/063 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J27/199 ,  B01J29/084 ,  B01J29/088 ,  B01J29/18 ,  B01J29/185 ,  B01J29/26 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0225 ,  B01J37/08 ,  B01J37/088 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: To provide a catalyst having excellent performance and durability by improving a NOx reduction ratio at 350° C. or higher without deteriorating excellent durability of a Ti—V—Mo—P catalyst in view of problems of conventional art. A NOx reduction catalyst for exhaust gas, which is composed of a catalyst composition that comprises titanium (Ti), an oxide of phosphorous, molybdenum (Mo) and/or tungsten (W), oxide of vanadium (V), and high-silica zeolite that has an SiO2/Al2O3 ratio of not less than 20 is obtained by kneading in the presence of water, drying and calcining (1) titanium oxide, and phosphoric acid or an ammonium salt of phosphoric acid in an amount of more than 1% by weight and not more than 15% by weight relative to the titanium oxide in terms of H3PO4, (2) an oxo acid or oxo acid salt of molybdenum (Mo) and/or tungsten (W) and an oxo acid salt of vanadium (V) or vanadyl salt respectively in an amount of more than 0% by atom and not more than 8% by atom relative to the titanium oxide and (3) high-silica zeolite in an amount of more than 0% by weight and not more than 20% by weight relative to the titanium oxide.

Abstract translation: 考虑到现有技术的问题，通过提高350℃以上的NOx还原率而不劣化Ti-V-Mo-P催化剂的优异耐久性，提供具有优异性能和耐久性的催化剂。 用于排气的NOx还原催化剂由包含钛（Ti），磷的氧化物，钼（Mo）和/或钨（W），钒（V）的氧化物）和高二氧化硅 通过在水的存在下捏合，干燥和煅烧（1）氧化钛，磷酸或磷酸铵盐的量大于1重量％，得到SiO 2 / Al 2 O 3比不小于20的沸石， （ⅱ）钼（Mo）和/或钨（W）和钒（W）的含氧酸盐的含氧酸或含氧酸盐（V）和钒的含氧酸盐（重量），并且不超过15重量％ V）或氧钒盐分别以相对于氧化钛大于0原子％且不超过8原子％的量，和（3）高于0重量％且不超过0重量％的高硅石沸石 相对于氧化钛为20重量％以下。

公开(公告)号：US20130184499A1

公开(公告)日：2013-07-18

申请号：US13736229

申请日：2013-01-08

Applicant: BioAmber International S.a.r.l.

Inventor： Setrak K. Tanielyan ,  Robert L. Augustine ,  Leo E. Manzer ,  James F. White ,  Ramesh D. Bhagat ,  Balaraju Miryala

IPC: B01J27/20

CPC classification number: B01J27/20 ,  B01J21/18 ,  B01J23/6567 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/06 ,  B01J37/12 ,  B01J37/28

Abstract: A reduced metallic catalyst or pre-activated catalyst is formed by contacting a precursor catalyst or a reduced metallic catalyst with a modifier solution in the presence of a source of hydrogen and heat treating the precursor catalyst or the reduced metallic catalyst at super-atmospheric pressure to obtain the reduced metallic catalyst from the precursor catalyst or the pre-activated catalyst from the reduced metallic catalyst. A method of hydrogenating a hydrogenatable precursor includes providing a reduced metallic catalyst or the pre-activated catalyst prepared with modifier buffer and contacting the reduced metallic catalyst or pre-activated catalyst with the hydrogenatable precursor in the presence of hydrogen and, optionally, in the presence of a modifier solution.

Abstract translation: 通过在氢源存在下使前体催化剂或还原金属催化剂与改性剂溶液接触并在超大气压下将前体催化剂或还原金属催化剂热处理接触而形成还原的金属催化剂或预活化催化剂， 从还原的金属催化剂获得来自前体催化剂或预活化催化剂的还原金属催化剂。 氢化可氢化前体的氢化方法包括提供还原金属催化剂或由改性剂缓冲剂制备的预活化催化剂，并在还原氢存在下使还原金属催化剂或预活化催化剂与可氢化前体接触 的改性剂溶液。

公开(公告)号：US20130000183A1

公开(公告)日：2013-01-03

申请号：US13446926

申请日：2012-04-13

Applicant: Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hackskaylo

Inventor： Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hackskaylo

IPC: B01J29/04 ,  C10L1/00

CPC classification number: B01J29/40 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/49 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02P30/20

Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodies. Such catalysts can be used for the thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

Abstract translation: 公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。 更具体地，提供了用于制备用于生物质转化的催化剂的方法。 该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型为成型体。 这种催化剂可用于将微生物量热生物转化为液体产物如生物油，导致比常规催化剂更高的生物油产率和较低的焦炭。

公开(公告)号：US20120181219A1

公开(公告)日：2012-07-19

申请号：US13498165

申请日：2010-09-14

Applicant: Hiroyuki Seki ,  Yoshiaki Fukui ,  Masanori Yoshida ,  Shogo Tagawa ,  Tomoyasu Kagawa

Inventor： Hiroyuki Seki ,  Yoshiaki Fukui ,  Masanori Yoshida ,  Shogo Tagawa ,  Tomoyasu Kagawa

IPC: C10G45/12 ,  B01J21/12

CPC classification number: B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/28 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/70

Abstract: The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst includes at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is ¼ or less of the diffraction peak area indicating the aluminum crystal structure ascribed to γ-alumina (400) planes, as measured by X-ray diffraction analysis. The catalyst has (a) a specific surface area (SA) of 150 m2/g or greater, (b) a total pore volume (PVo) of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å), and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30 percent of the average pore diameter (PD) being 70 percent or greater of the total pore volume (PVo).

Abstract translation: 本发明提供一种加氢脱硫催化剂，其在用于烃油，特别是直馏瓦斯油的加氢处理中表现出高的脱硫活性。 催化剂包括至少一种选自元素周期表中的VIA和VIII族的金属组分，负载在二氧化硅 - 二氧化钛 - 氧化铝载体上，其中表示锐钛型二氧化钛（101）晶面的晶体结构的衍射峰面积的总和和 表示金红石型二氧化钛（110）面的晶体结构的衍射峰面积，通过X射线衍射分析测定，表示归因于γ-氧化铝（400）面的铝结晶结构的衍射峰面积的1/4以下。 催化剂的（a）比表面积（SA）为150m 2 / g以上，（b）总孔体积（PVo）为0.30ml / g以上，（c）平均孔径（PD）为 6〜15nm（60〜150），（d）直径在平均孔径（PD）±30％以内的孔的孔体积（PVp）的比例为总孔体积的70％以上 （PVo）。

公开(公告)号：US08178740B2

公开(公告)日：2012-05-15

申请号：US12330538

申请日：2008-12-09

Applicant: Christopher P. Nicholas ,  Laszlo T. Nemeth ,  Deng-Yang Jan

Inventor： Christopher P. Nicholas ,  Laszlo T. Nemeth ,  Deng-Yang Jan

IPC: C07C2/12

CPC classification number: C07C2/12 ,  B01J29/005 ,  B01J29/06 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/62 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7046 ,  B01J29/83 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2527/173 ,  C07C2529/70 ,  C10G2300/1088 ,  C10G2300/1092 ,  C10G2300/305 ,  C10G2400/02 ,  C10G2400/22

Abstract: A process for the use in the oligomerization of olefins is presented. The process produces a gasoline boiling range product having a high research octane number and almost no aromatics content. The process utilizes a solid catalyst comprising a zeolite that is treated with a phosphorous containing reagent to generate a catalyst having phosphorous content between 0.5 and 15 wt %.

Abstract translation: 提出了一种用于烯烃低聚的方法。 该方法产生具有高研究辛烷值和几乎不含芳烃含量的汽油沸点产物。 该方法利用包含沸石的固体催化剂，该沸石用含磷试剂处理以产生磷含量在0.5至15重量％之间的催化剂。

公开(公告)号：US20120091038A1

公开(公告)日：2012-04-19

申请号：US13274509

申请日：2011-10-17

Applicant: Sylvie LACOMBE ,  Malika Boualleg ,  Eric Sanchez

Inventor： Sylvie LACOMBE ,  Malika Boualleg ,  Eric Sanchez

IPC: C10G35/06 ,  B01J27/135 ,  B01J27/132 ,  B01J21/04 ,  B01J27/185 ,  B01J27/02 ,  B01J27/14 ,  B01J27/13 ,  B01J27/138

CPC classification number: C10G35/09 ,  B01J21/04 ,  B01J23/42 ,  B01J23/468 ,  B01J23/626 ,  B01J23/6567 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/20 ,  B01J37/28 ,  C10G2300/1096 ,  C10G2300/305

Abstract: The present invention concerns an optimized reforming catalyst comprising at least platinum, at least one promoter metal selected from the group formed by rhenium and iridium, at least one halogen, and at least one alumina support with a low sulphur and phosphorus content.

Abstract translation: 本发明涉及一种优化的重整催化剂，其包含至少一种铂，至少一种选自由铼和铱形成的助催化剂金属，至少一种卤素和至少一种具有低硫和磷含量的氧化铝载体。

公开(公告)号：US08138114B2

公开(公告)日：2012-03-20

申请号：US12884690

申请日：2010-09-17

Applicant: Hungwen Jen ,  George Graham ,  Robert McCabe

Inventor： Hungwen Jen ,  George Graham ,  Robert McCabe

IPC: B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC classification number: B01J37/0207 ,  B01D53/9418 ,  B01D2255/911 ,  B01J27/185 ,  B01J37/28 ,  Y02A50/2325

Abstract: A method of providing an automobile exhaust catalyst composition. The method includes acidifying a support composition with a conjugate base oxide of an inorganic acid having a Ka to obtain an acidified support exhaust catalyst composition. The support composition includes a combination of a cerium-containing oxide compound and non-cerium-containing compound selected from the group consisting of alkali metal containing compounds, alkaline-earth metal containing compounds and combinations thereof.

Abstract translation: 一种提供汽车尾气催化剂组合物的方法。 该方法包括用具有Ka的无机酸的共轭基础氧化物酸化载体组合物以获得酸化的载体排出催化剂组合物。 载体组合物包括选自含碱金属化合物，含碱土金属化合物及其组合的含铈氧化物化合物和非含铈化合物的组合。

公开(公告)号：US08084387B2

公开(公告)日：2011-12-27

申请号：US12594617

申请日：2008-01-30

Applicant: Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

Inventor： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

IPC: B01J27/185 ,  B01J23/40 ,  B01J23/42 ,  B01J23/00 ,  B01J23/08 ,  C01F7/02 ,  C07C27/00 ,  C07C27/06

CPC classification number: B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

Abstract: The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

Abstract translation: 本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。 具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。 特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。 因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。