公开(公告)号：US20240351008A1

公开(公告)日：2024-10-24

申请号：US18714756

申请日：2022-11-29

Applicant: NIPPON KAYAKU KABUSHIKI KAISHA

Inventor： Shigeki Okumura ,  Tsukasa KAGAWA ,  Shogo YASUDA

IPC: B01J23/887 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/00 ,  B01J35/61 ,  B01J35/64 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07C2/84 ,  C07C45/35 ,  C07C51/25

CPC classification number: B01J23/8876 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/002 ,  B01J35/612 ,  B01J35/651 ,  B01J35/653 ,  B01J35/657 ,  B01J37/0045 ,  B01J37/0063 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  C07C2/84 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847

Abstract: The present invention relates to a catalyst having at least one peak in each of a range of a pore diameter of 0.45 μm to 10.0 μm and a range of a pore diameter of 0.040 μm to 0.45 μm in a pore distribution (−dV/d (log D) vs D) measured by mercury porosimetry, in which when a maximum value of −dV/d (log D) in the range of the pore diameter of 0.45 μm to 10.0 μm is represented by A and a maximum value of −dV/d (log D) in the range of the pore diameter of 0.040 μm to 0.45 μm is represented by B, (B/A) is 0.20 to 13.0 (V represents a volume (unit: mL/g) of filled mercury per sample weight, D represents the pore diameter (unit: μm), log D represents a natural logarithm of D, and −dV/d (log D) represents a reciprocal of a value obtained by differentiating a cumulative pore volume in a specific pore diameter range by a logarithm of the pore diameter).

公开(公告)号：US20240336546A1

公开(公告)日：2024-10-10

申请号：US18571875

申请日：2022-04-08

Applicant: Resonac Corporation

Inventor： Masafumi KOYANO ,  Gen INOUE ,  Toshihiro KIMURA

IPC: C07C29/04 ,  B01J8/06 ,  B01J21/08 ,  B01J23/30 ,  B01J37/02 ,  C07B41/02

CPC classification number: C07C29/04 ,  B01J8/065 ,  B01J21/08 ,  B01J23/30 ,  B01J37/0215 ,  B01J37/0236 ,  C07B41/02

Abstract: Provided is a method for producing an alcohol through an olefin hydration reaction using a heteropolyacid catalyst, the method enabling the catalyst to be stably used over a long period. In the olefin hydration reaction, in which the heteropolyacid catalyst is used, the pressure loss during the period of passing a feed-material gas through a catalyst layer is regulated to a certain value or less. Specifically, the method for producing an alcohol comprises using a solid-acid catalyst including a supported heteropolyacid or salt thereof, supplying water and a 2C-5C olefin to a reactor, and hydrating the olefin in a gas phase, wherein the pressure loss during the period of passing the feed-material gas through a layer of the catalyst is regulated to 350 kPa or less.

公开(公告)号：US20240335819A1

公开(公告)日：2024-10-10

申请号：US18746623

申请日：2024-06-18

Applicant: Ecovyst Catalyst Technologies LLC

Inventor： Parag Rasiklal SHAH ,  Yatao Rachel HU

IPC: B01J23/20 ,  B01J21/08 ,  B01J35/30 ,  B01J35/40 ,  B01J35/61 ,  B01J35/63 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  C07C1/24

CPC classification number: B01J23/20 ,  B01J21/08 ,  B01J35/397 ,  B01J35/40 ,  B01J35/615 ,  B01J35/635 ,  B01J35/638 ,  B01J37/0207 ,  B01J37/04 ,  B01J37/082 ,  C07C1/24 ,  C07C2521/08 ,  C07C2523/20

Abstract: A method for making a supported tantalum oxide catalyst precursor or catalyst with controlled Ta distribution and the resulting supported Ta catalyst. In an embodiment, the method comprises selecting a Ta-precursor with appropriate reactivity with the surface hydroxyls of the solid oxide support material to give a desired Ta distribution in the catalyst precursor or catalyst. In an embodiment the method comprises controlling the number of surface hydroxyls available on the support material to react with the Ta-precursor by thermal methods, such as calcination, to achieve the desired Ta distribution.

公开(公告)号：US12104125B2

公开(公告)日：2024-10-01

申请号：US17300009

申请日：2021-02-05

Applicant: INFINIUM TECHNOLOGY, LLC

Inventor： Robert Schuetzle ,  Dennis Schuetzle ,  Orion Hanbury

IPC: C10G2/00 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/78 ,  B01J23/89 ,  B01J35/00 ,  B01J35/30 ,  C07C1/12 ,  C25B1/04

CPC classification number: C10G2/50 ,  B01J21/005 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/78 ,  B01J23/8946 ,  B01J23/8986 ,  B01J35/00 ,  B01J35/30 ,  C07C1/12 ,  C10G2/30 ,  C25B1/04 ,  C10G2300/42

Abstract: Embodiments of the present invention relate to two improved catalysts and associated processes that directly convert carbon dioxide and hydrogen to liquid fuels. A catalytic system comprises two catalysts in series that are operated in tandem to directly produce synthetic liquid fuels. The carbon conversion efficiency for CO2 to liquid fuels is greater than 45%. The fuel is distilled into a premium diesel fuels (approximately 70 volume %) and naphtha (approximately 30 volume %) which are used directly as “drop-in” fuels without requiring any further processing. Any light hydrocarbons that are present with the carbon dioxide are also converted directly to fuels. This process is directly applicable to the conversion of CO2 collected from ethanol plants, cement plants, power plants, biogas, carbon dioxide/hydrocarbon mixtures from secondary oil recovery, and other carbon dioxide/hydrocarbon streams. The catalyst system is durable, efficient and maintains a relatively constant level of fuel productivity over long periods of time without requiring re-activation or replacement.

公开(公告)号：US20240316544A1

公开(公告)日：2024-09-26

申请号：US18579568

申请日：2022-07-25

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Xiaoying Bao

IPC: B01J38/12 ,  B01J21/06 ,  B01J21/08 ,  B01J23/42 ,  B01J23/90 ,  C07C5/32

CPC classification number: B01J38/12 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J23/90 ,  C07C5/325 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/42

Abstract: Processes for regenerating an at least partially deactivated catalyst that can include a Group (10) element, an inorganic support, and a contaminant. The Group (10) element can have a concentration of from 0.06 wt % to 6 wt %, based on the weight of the inorganic support. The process can include (I) heating the deactivated catalyst using a heating gas mixture that includes H2O at a concentration >5 mol %, based on the total moles in the mixture to produce a precursor catalyst. The process can also include (II) providing an oxidative gas that includes ≤5 mol % of H2O, based on the total moles in the oxidative gas, and (III) contacting the precursor catalyst at an oxidizing temperature with the oxidative gas for a duration of at least 30 seconds to produce an oxidized precursor catalyst. The process can also include (IV) obtaining a regenerated catalyst from the oxidized precursor catalyst.

公开(公告)号：US12091615B2

公开(公告)日：2024-09-17

申请号：US17633099

申请日：2020-10-03

Applicant: Reliance Industries Limited

Inventor： Ravichandran Gopal ,  Nirav Jethalal Jani ,  Ankit Vipinkumar Patel ,  Asit Kumar Das

IPC: C10G11/05 ,  B01J21/04 ,  B01J21/08 ,  B01J21/16 ,  B01J23/10 ,  B01J29/08 ,  B01J35/23 ,  B01J35/30 ,  B01J35/51 ,  B01J35/61 ,  B01J35/63 ,  B01J37/00 ,  C10G3/00

CPC classification number: C10G11/05 ,  B01J21/04 ,  B01J21/08 ,  B01J21/16 ,  B01J23/10 ,  B01J29/088 ,  B01J35/23 ,  B01J35/30 ,  B01J35/51 ,  B01J35/615 ,  B01J35/633 ,  B01J37/0045 ,  C10G3/49 ,  C10G2300/70 ,  C10G2400/20

Abstract: The present disclosure relates to an FCC catalyst composition and a process for preparing the same. In a first aspect, there is provided an FCC catalyst composition comprising 25 to 45 wt % Y-type zeolite, 20 to 40 wt % silicon oxide, 5 to 25 wt % alumina, 5 to 35 wt % of at least one clay and 0.5 to 3 wt % of at least one rare earth oxide. The weight % of each of the component is with respect to the total weight of the composition. The FCC catalyst composition has an average particle size in the range of 45-120μ. In a second aspect, there is provided a process for preparing the FCC catalyst composition, which uses ball milled pseudoboehmite having an average particle size in the range of 1 to 8 micron and the whole process is carried out at a pH value in the range of 6 to 7.

公开(公告)号：US20240299910A1

公开(公告)日：2024-09-12

申请号：US18654882

申请日：2024-05-03

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Eric D. Schwerdtfeger ,  Jeremy M. Praetorius

IPC: B01J21/08 ,  B01J23/26 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J21/08 ,  B01J23/26 ,  B01J37/0217 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08

Abstract: A method of preparing a catalyst comprising a) drying a chrominated-silica support followed by contacting with a titanium(IV) alkoxide to form a metalized support, b) drying a metalized support followed by contacting with an aqueous alkaline solution comprising from about 3 wt. % to about 20 wt. % of a nitrogen-containing compound to form a hydrolyzed metalized support, and c) drying the hydrolyzed metalized support followed by calcination at a temperature in a range of from about 400° C. to about 1000° C. and maintaining the temperature in the range of from about 400° C. to about 1000° C. for a time period of from about 1 minute to about 24 hours to form the catalyst.

公开(公告)号：US20240286973A1

公开(公告)日：2024-08-29

申请号：US18659092

申请日：2024-05-09

Applicant: Chevron Phillips Chemical Company LP

Inventor： Masud M. Monwar ,  Jared L. Barr ,  Carlos A. Cruz ,  Kathy S. Clear ,  Max P. McDaniel ,  William C. Ellis

IPC: C07B33/00 ,  B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/39 ,  B01J35/61 ,  B01J35/63 ,  B01J37/08 ,  B01J37/16 ,  B01J37/34 ,  B01J38/02 ,  C07C29/48 ,  C07C29/50 ,  C07C45/27 ,  C07C45/28 ,  C07C51/16 ,  C07C51/225

CPC classification number: C07B33/00 ,  B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/39 ,  B01J35/613 ,  B01J35/615 ,  B01J35/617 ,  B01J35/618 ,  B01J35/633 ,  B01J35/635 ,  B01J35/638 ,  B01J37/082 ,  B01J37/16 ,  B01J37/34 ,  B01J37/345 ,  B01J38/02 ,  C07C29/48 ,  C07C29/50 ,  C07C45/27 ,  C07C45/28 ,  C07C51/16 ,  C07C51/225

Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.

公开(公告)号：US20240269653A1

公开(公告)日：2024-08-15

申请号：US18569159

申请日：2022-06-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Aaron R. Garg ,  Xiaoying Bao ,  Colin L. Beswick ,  Chuansheng Bai ,  Christian A. Diaz Urrutia

IPC: B01J23/62 ,  B01J21/08 ,  B01J21/16 ,  B01J23/02 ,  B01J35/32 ,  B01J35/40 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  C07C5/32

CPC classification number: B01J23/626 ,  B01J21/08 ,  B01J21/16 ,  B01J23/02 ,  B01J35/32 ,  B01J35/40 ,  B01J37/0009 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/088 ,  B01J37/10 ,  C07C5/325 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/66 ,  C07C2523/89

Abstract: Catalyst compositions and processes for making and using same. The catalyst composition can include catalyst particles. The catalyst particles can include 0.001 wt % to 6 wt % of Pt and up to 10 wt % of a promoter that can include Sn, Cu, Au, Ag, Ga, or a combination thereof, or a mixture thereof disposed on a support. The support can include at least 0.5 wt % of a Group 2 element. All weight percent values are based on the weight of the support. The catalyst particles can have a median particle size in a range from 10 μm to 500 pm. The catalyst particles can have an apparent loose bulk density in a range from 0.3 g/cm3 to 2 g/cm3, as measured according to ASTM D7481-18 modified with a 10, 25, or 50 mL graduated cylinder instead of a 100 or 250 mL graduated cylinder.

公开(公告)号：US12043587B2

公开(公告)日：2024-07-23

申请号：US17695993

申请日：2022-03-16

Applicant: Gevo, Inc.

Inventor： Jonathan Smith ,  Madeline Sjodin

IPC: C07C1/24 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J23/30 ,  B01J29/40 ,  C07C2/12 ,  C07C6/04 ,  C10G3/00

CPC classification number: C07C1/24 ,  B01J21/04 ,  B01J21/066 ,  B01J21/08 ,  B01J23/30 ,  B01J29/40 ,  C07C2/12 ,  C07C6/04 ,  C10G3/49 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/30 ,  C07C2529/40 ,  C10G2400/20 ,  C10G2400/22

Abstract: This disclosure relates to a single stage process for the direct conversion of alcohols, e.g. ethanol, to olefinic mixtures (C2-C7) with low levels of aromatics carried out in a single reactor with two fixed catalyst beds in series, or two catalytic fixed bed reactors in series wherein the first reactor operates at a lower or higher temperature than the operating temperature of the second reactor. The process transformation of ethanol is comprised of ethanol dehydration to ethylene and water in high yield with the first catalyst in the first reactor, or via the first fixed catalyst bed, followed by directly feeding the ethylene and water to the second reactor, or second fixed catalyst bed, with conversion of said ethylene and water to a C2-C7 olefinic mixture with the second catalyst(s) in high yields with minimal aromatic compound formation.