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    CATALYST MIXING PROCESS AND REGENERATOR RELATING THERETO
    41.
    发明申请
    CATALYST MIXING PROCESS AND REGENERATOR RELATING THERETO 有权
    催化剂混合过程和与其相关的再生器

    公开(公告)号：US20130310244A1

    公开(公告)日：2013-11-21

    申请号：US13475104

    申请日：2012-05-18

    Applicant: Charles L. Hemler, JR.

    Inventor： Charles L. Hemler, JR.

    IPC: B01J38/04 ,  B01J8/00

    CPC classification number: B01J29/90 ,  B01J8/003 ,  B01J8/0055 ,  B01J8/08 ,  B01J8/1845 ,  B01J8/26 ,  B01J38/10 ,  B01J38/12 ,  B01J2208/00752 ,  B01J2208/0084 ,  B01J2208/00849 ,  B01J2208/025

    Abstract: One exemplary embodiment can be a process for mixing catalyst in a regenerator. The process can include providing a first stream of catalyst, a second stream of catalyst mixed with the first stream of catalyst, and an oxygen-containing gas to a chamber via a distributor of the regenerator. Generally, the chamber imparts a swirl to at least one of the oxygen-containing gas, the first catalyst, and the second catalyst for regenerating the catalyst.

    Abstract translation: 一个示例性实施方案可以是在再生器中混合催化剂的方法。 该方法可以包括提供第一催化剂流，与第一催化剂流混合的第二催化剂流，以及通过再生器的分配器向室内提供含氧气体。 通常，室向至少一种含氧气体，第一催化剂和第二催化剂施加涡流以再生催化剂。

    Methods for hydrocracking a heavy oil feedstock using an in situ colloidal or molecular catalyst and recycling the colloidal or molecular catalyst
    44.
    发明授权
    Methods for hydrocracking a heavy oil feedstock using an in situ colloidal or molecular catalyst and recycling the colloidal or molecular catalyst 有权
    使用原位胶体或分子催化剂加氢裂化重油原料并循环使用胶体或分子催化剂的方法

    公开(公告)号：US08303802B2

    公开(公告)日：2012-11-06

    申请号：US13116195

    申请日：2011-05-26

    Applicant: Roger K. Lott ,  Lap-Keung Lee

    Inventor： Roger K. Lott ,  Lap-Keung Lee

    IPC: C10G47/02 ,  C10G65/10

    CPC classification number: C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

    Abstract: An ebullated bed hydroprocessing system, and also a method for upgrading an existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a catalyst precursor capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the catalyst precursor to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system. Asphaltene or other hydrocarbon molecules too large to diffuse into the pores of the supported catalyst can be upgraded by the colloidal or molecular catalyst. A slurry phase reactor may be positioned upstream from one or more ebullated bed reactors or converted from an existing ebullated bed reactor.

    Abstract translation: 沸腾床加氢处理系统以及用于升级现有沸腾床加氢处理系统的方法包括将能够形成胶体或分子催化剂的胶体或分子催化剂或催化剂前体引入沸腾床反应器。 胶体或分子催化剂通过将催化剂前体紧密地混合到重油原料中并将原料的温度升高到催化剂前体的分解温度以形成原位形成胶态或分子催化剂而形成。 改进的沸腾床加氢处理系统包括至少一个沸腾床反应器，其使用多孔负载催化剂和胶体或分子催化剂来催化涉及原料和氢的加氢处理反应。 胶体或分子催化剂提供催化剂，否则将在沸腾床加氢处理系统内构成催化剂自由区。 太大而不能扩散到负载型催化剂的孔中的沥青质或其他烃类分子可以通过胶体或分子催化剂来提升。 浆料相反应器可以位于一个或多个沸腾床反应器的上游或从现有的沸腾床反应器转化。

    Photocatalytic reactor
    45.
    发明授权
    Photocatalytic reactor 失效
    光催化反应器

    公开(公告)号：US08173015B2

    公开(公告)日：2012-05-08

    申请号：US12447110

    申请日：2007-10-25

    Applicant: Neil Robert Foster ,  Kourosh Bassiti

    Inventor： Neil Robert Foster ,  Kourosh Bassiti

    IPC: C02F1/32 ,  C02F1/74

    CPC classification number: C02F1/325 ,  B01J8/08 ,  B01J19/123 ,  B01J35/004 ,  B01J2208/00884 ,  B01J2219/0884 ,  B01J2219/0892 ,  C02F1/725 ,  C02F1/74 ,  C02F2305/10

    Abstract: A photocatalytic reactor for carrying out a photocatalytic reaction on a liquid which is to be treated, the reactor comprising a reaction chamber which comprises: (i) a foraminated member which supports a plurality of mobile photocatalyst particles, the size and density of which is such that they tend to rest on the foraminated member in use; and (ii) an aeration device which causes gas bubbles to rise from the foraminated member and agitate the mobile photocatalyst particles. The reactor may be a flow-through reactor. The photocatalytic reactor can be applied to the remediation of waste water using titanium oxide.

    Abstract translation: 1.一种光催化反应器，用于对待处理的液体进行光催化反应，所述反应器包括反应室，所述反应室包括：（i）支撑多个可移动光催化剂颗粒的被测部件，其尺寸和密度为 他们倾向于依靠被使用的受损员工; 和（ii）使得气泡从被处理部件上升并搅拌移动光催化剂粒子的曝气装置。 反应器可以是流通反应器。 光催化反应器可用于使用氧化钛对废水的修复。

    METHODS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST AND RECYCLING THE COLLOIDAL OR MOLECULAR CATALYST
    47.
    发明申请
    METHODS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST AND RECYCLING THE COLLOIDAL OR MOLECULAR CATALYST 有权
    使用原位胶体或分子催化剂水解破碎重油的方法，回收胶体或分子催化剂

    公开(公告)号：US20110226667A1

    公开(公告)日：2011-09-22

    申请号：US13116195

    申请日：2011-05-26

    Applicant: Roger K. Lott ,  Lap-Keung Lee

    Inventor： Roger K. Lott ,  Lap-Keung Lee

    IPC: C10G47/30 ,  B01J8/20

    CPC classification number: C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

    Abstract: An ebullated bed hydroprocessing system, and also a method for upgrading an existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a catalyst precursor capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the catalyst precursor to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system. Asphaltene or other hydrocarbon molecules too large to diffuse into the pores of the supported catalyst can be upgraded by the colloidal or molecular catalyst. A slurry phase reactor may be positioned upstream from one or more ebullated bed reactors or converted from an existing ebullated bed reactor.

    Abstract translation: 沸腾床加氢处理系统以及用于升级现有沸腾床加氢处理系统的方法包括将能够形成胶体或分子催化剂的胶体或分子催化剂或催化剂前体引入沸腾床反应器。 胶体或分子催化剂通过将催化剂前体紧密地混合到重油原料中并将原料的温度升高到催化剂前体的分解温度以形成原位形成胶态或分子催化剂而形成。 改进的沸腾床加氢处理系统包括至少一个沸腾床反应器，其使用多孔负载催化剂和胶体或分子催化剂来催化涉及原料和氢的加氢处理反应。 胶体或分子催化剂提供催化剂，否则将在沸腾床加氢处理系统内构成催化剂自由区。 太大而不能扩散到负载型催化剂的孔中的沥青质或其他烃类分子可以通过胶体或分子催化剂来提升。 浆料相反应器可以位于一个或多个沸腾床反应器的上游或从现有的沸腾床反应器转化。

    METHODS AND SYSTEMS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST
    48.
    发明申请
    METHODS AND SYSTEMS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST 有权
    使用原位胶体或分子催化剂水解重油油料的方法和系统

    公开(公告)号：US20110220553A1

    公开(公告)日：2011-09-15

    申请号：US13113722

    申请日：2011-05-23

    Applicant: Roger K. Lott ,  Lap-Keung Lee

    Inventor： Roger K. Lott ,  Lap-Keung Lee

    IPC: C10G47/02 ,  C10G47/00 ,  B01J19/00

    CPC classification number: C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

    Abstract: A hydrocracking system involves introducing a heavy oil feedstock and a colloidal or molecular catalyst, or a catalyst precursor capable of forming the colloidal or molecular catalyst, into a hydrocracking reactor. The colloidal or molecular catalyst is formed in situ within the heavy oil feedstock by 1) premixing the catalyst precursor with a hydrocarbon diluents to form a catalyst precursor mixture, 2) mixing the catalyst precursor mixture with the heavy oil feedstock, and 3) raising the temperature of the feedstock to above the decomposition temperature of the catalyst precursor to form the colloidal or molecular catalyst. The colloidal or molecular catalyst catalyzes upgrading reactions between the heavy oil feedstock and hydrogen and eliminates or reduces formation of coke precursors and sediment. The colloidal or molecular catalyst can be the sole or primary hydrocracking catalyst in a stand-alone hydrocracking reactor or it can be used together with a porous supported catalyst within a fixed bed or ebullated bed reactor.

    Abstract translation: 加氢裂化系统包括将重油原料和能够形成胶体或分子催化剂的胶体或分子催化剂或催化剂前体引入加氢裂化反应器。 胶体或分子催化剂在重油原料中原位形成，1）用烃稀释剂预混合催化剂前体以形成催化剂前体混合物，2）将催化剂前体混合物与重油原料混合，3） 原料的温度高于催化剂前体的分解温度，以形成胶体或分子催化剂。 胶体或分子催化剂催化重油原料与氢气之间的升级反应，消除或减少焦炭前体和沉淀物的形成。 胶体或分子催化剂可以是独立加氢裂化反应器中的唯一或一级加氢裂化催化剂，或者可以与固定床或沸腾床反应器内的多孔载体催化剂一起使用。

    Use of copolymers of perfluoro(alkyl vinyl ether) for photochemical reactions
    49.
    发明授权
    Use of copolymers of perfluoro(alkyl vinyl ether) for photochemical reactions 失效
    使用全氟（烷基乙烯基醚）共聚物进行光化学反应

    公开(公告)号：US07943015B2

    公开(公告)日：2011-05-17

    申请号：US11792642

    申请日：2005-12-19

    Applicant: Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    Inventor： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC: B01J19/12 ,  C07C17/20 ,  C07C19/01 ,  C07C19/08

    CPC classification number: B01J19/123 ,  B01J8/08 ,  B01J19/127 ,  B01J19/24 ,  B01J19/2415 ,  B01J19/243 ,  B01J23/26 ,  B01J37/088 ,  C07C17/10 ,  C07C17/206 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/18 ,  C07C21/185

    Abstract: A photochemical reaction apparatus including a reactor and a light source situated so that light from the light source is directed through a portion of the reactor wall is disclosed. The apparatus is characterized by the portion of the reaction wall comprising a copolymer of a perfluoro (alkyl vinyl ether). The perfluoro (alkyl vinyl ether) is selected from the group consisting of CF30CF═CF2, C2F5OCF═CF2, C3F7OCF═F2, and mixture thereof. Also disclosed is a photochemical reaction process wherein light from a light source is directed through said reactor wall to interact with reactants in said reactor. A process for increasing the fluorine content of at least one compound selected from hydrocarbons and halohydrocarbons, comprising: (a) photochlorinating said at least one compound; and (b) reacting the halogenated hydrocarbon produced in (a) with HF. A process for producing an olefinic compound, comprising: (a) photochlorinating at least one compound selected from hydrocarbons and halohydrocarbons containing at least two carbon atoms and at least two hydrogen atoms to produce a halogenated hydrocarbon containing a hydrogen substituent and a chlorine substituent on adjacent carbon atoms; and (b) subjecting the halogenated hydrocarbon produced in (a) to dehydrohalogenation.

    Abstract translation: 公开了一种光化学反应装置，其包括反应器和光源，其位于使得来自光源的光被引导通过反应器壁的一部分。 该装置的特征在于反应壁的一部分包含全氟（烷基乙烯基醚）的共聚物。 全氟（烷基乙烯基醚）选自CF 30CF≡CF2，C 2 F 5 OCF = CF 2，C 3 F 7 OCF = F 2，及其混合物。 还公开了光化学反应方法，其中来自光源的光被引导通过所述反应器壁以与所述反应器中的反应物相互作用。 一种提高至少一种选自烃和卤代烃的化合物的氟含量的方法，包括：（a）将所述至少一种化合物进行光氯化; 和（b）使（a）中制备的卤代烃与HF反应。 一种制备烯烃化合物的方法，包括：（a）将至少一种选自含有至少两个碳原子和至少两个氢原子的烃和卤代烃的化合物进行光氯化以产生在邻近的含氢取代基和氯取代基的卤代烃 碳原子 和（b）使（a）中制备的卤代烃脱卤化氢。

    METHODS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST AND RECYCLING THE COLLOIDAL OR MOLECULAR CATALYST
    50.
    发明申请
    METHODS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST AND RECYCLING THE COLLOIDAL OR MOLECULAR CATALYST 有权
    使用原位胶体或分子催化剂水解破碎重油的方法，回收胶体或分子催化剂

    公开(公告)号：US20100294701A1

    公开(公告)日：2010-11-25

    申请号：US12838761

    申请日：2010-07-19

    Applicant: Roger K. Lott ,  Lap-Keung Lee

    Inventor： Roger K. Lott ,  Lap-Keung Lee

    IPC: C10G47/26

    CPC classification number: C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

    Abstract: A hydrocracking system involves introducing a heavy oil feedstock and a colloidal or molecular catalyst, or a precursor composition capable of forming the colloidal or molecular catalyst, into a hydrocracking reactor. The colloidal or molecular catalyst is formed in situ within the heavy oil feedstock by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst. The colloidal or molecular catalyst catalyzes upgrading reactions between the heavy oil feedstock and hydrogen and eliminates or reduces formation of coke precursors and sediment. At least a portion of a resid fraction containing residual colloidal or molecular catalyst is recycled back into the hydrocracking reactor to further upgrade the recycled resid fraction portion and provide recycled colloidal or molecular catalyst within the hydrocracking reactor.

    Abstract translation: 加氢裂化系统包括将重油原料和能形成胶体或分子催化剂的胶体或分子催化剂或前体组合物引入加氢裂化反应器。 通过将催化剂前体组合物紧密地混合到重油原料中并将原料的温度提高到高于前体组合物的分解温度以形成胶体或分子催化剂，在重油原料内原位形成胶态或分子催化剂。 胶体或分子催化剂催化重油原料与氢气之间的升级反应，消除或减少焦炭前体和沉淀物的形成。 含有残留的胶体或分子催化剂的残渣部分的至少一部分循环回到加氢裂化反应器中以进一步升级再循环的残渣部分，并在加氢裂化反应器内提供再循环的胶体或分子催化剂。

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