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    Method of forming an organic thin film
    42.
    发明授权
    Method of forming an organic thin film 失效
    形成有机薄膜的方法

    公开(公告)号：US5415899A

    公开(公告)日：1995-05-16

    申请号：US70973

    申请日：1993-06-04

    Applicant: Toshio Nakayama ,  Syun Egusa ,  Nobuhiro Gemma ,  Akira Miura

    Inventor： Toshio Nakayama ,  Syun Egusa ,  Nobuhiro Gemma ,  Akira Miura

    IPC: B05D1/20

    CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00

    Abstract: A method of forming an organic thin film includes developing organic molecules having a hydrophilic portion and a hydrophobic portion on a water surface, and compressing the organic molecules thereby to form a monomolecular layer of a predetermined surface pressure. The monomolecular layer is brought into contact with a given substrate. Then, the substrate to which the monomolecular layer is adhered, is pulled at such a rate that the surface pressure is not substantially lowered, thus transferring the monomolecular layer onto the substrate.

    Abstract translation: 形成有机薄膜的方法包括在水表面上显影具有亲水部分和疏水部分的有机分子，并压缩有机分子，从而形成预定表面压力的单分子层。 使单分子层与给定的基材接触。 然后，以使得表面压力基本上不降低的速度被拉出，其中粘附单分子层的衬底，从而将单分子层转移到衬底上。

    Process for producing polyacetylene or polyacene type long conjugated polymers
    44.
    发明授权
    Process for producing polyacetylene or polyacene type long conjugated polymers 失效

    公开(公告)号：US5304583A

    公开(公告)日：1994-04-19

    申请号：US959432

    申请日：1992-10-13

    Applicant: Kazufumi Ogawa

    Inventor： Kazufumi Ogawa

    IPC: B05D1/18 ,  B05D1/20 ,  G02F1/361 ,  H01B1/12 ,  C08J3/28

    CPC classification number: B05D1/185 ,  B05D1/202 ,  B82Y10/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3618 ,  H01B1/125

    Abstract: This invention relates to production of a super long conjugated polymer to be used for a molecular device, etc. According to this invention, an acetylene derivative is previously oriented and formed into a monomolecular film on the surface of a substrate and its acetylenic group is polymerized by a catalyst or by irradiation of an energy beam while keeping the orientation. Since the respective molecules are oriented and aligned on the substrate surface, the polymerization reaction readily proceeds, and after the polymerization the resulting polyacetylene molecules are prevented from the breakage of conjugated bonds caused by thermal agitation or twisting of the polyacetylene molecules. Accordingly, a polyacetylene or polyacene type polymer having long conjugated bonds can be obtained easily.

    Process for producing polyacetylene or polyacene type long conjugated polymers
    46.
    发明授权
    Process for producing polyacetylene or polyacene type long conjugated polymers 失效
    生产聚乙炔或多并苯型长共轭聚合物的方法

    公开(公告)号：US5248526A

    公开(公告)日：1993-09-28

    申请号：US926381

    申请日：1992-08-10

    Applicant: Kazufumi Ogawa

    Inventor： Kazufumi Ogawa

    IPC: B05D1/18 ,  B05D1/20 ,  G02F1/361 ,  H01B1/12

    CPC classification number: B82Y30/00 ,  B05D1/185 ,  B05D1/202 ,  B82Y10/00 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3618 ,  H01B1/125

    Abstract: This invention relates to production of a super long conjugated polymer to be used for a molecular device, etc. According to this invention, an acetylene derivative is previously oriented and formed into a monomolecular film on the surface of a substrate and its acetylenic group is polymerized by a catalyst or by irradiation of an energy beam while keeping the orientation. Since the respective molecules are oriented and aligned on the substrate surface, the polymerization reaction readily proceeds, and after the polymerization the resulting polyacetylene molecules are prevented from the breakage of conjugated bonds caused by thermal agitation or twisting of the polyacetylene molecules. Accordingly, a polyacetylene or polyacene type polymer having long conjugated bonds can be obtained easily.

    Abstract translation: 本发明涉及用于分子装置等的超长共轭聚合物的制备。根据本发明，乙炔衍生物预先在基材表面取向成单分子膜，其炔基聚合 通过催化剂或通过在保持取向的同时照射能量束。 由于各个分子在基材表面上取向和取向，所以聚合反应容易进行，聚合后聚合乙炔分子不会被聚乙炔分子的热搅拌或扭曲引起的共轭键断裂。 因此，可以容易地获得具有长的共轭键的聚乙炔或多并苯型聚合物。

    Copolymeric and amphiphilic polyimide precursor, process for preparing the same and thin film
    47.
    发明授权
    Copolymeric and amphiphilic polyimide precursor, process for preparing the same and thin film 失效
    共聚和两亲性聚酰亚胺前体，制备相同薄膜的方法

    公开(公告)号：US5171829A

    公开(公告)日：1992-12-15

    申请号：US642255

    申请日：1991-01-16

    Applicant: Masakazu Uekita ,  Hiroshi Awaji

    Inventor： Masakazu Uekita ,  Hiroshi Awaji

    IPC: B05D1/20 ,  C08G73/10 ,  C08G73/14

    CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C08G73/10 ,  C08G73/1007 ,  C08G73/1067 ,  C08G73/14 ,  Y10T428/31504 ,  Y10T428/31721

    Abstract: A copolymeric amphiphilic polyimide precursor having the recurring unit of the formula (1): ##STR1## wherein R.sup.1 is a tetravalent group having at least 2 carbon atoms, R.sup.2 is a bivalent group having at least 2 carbon atoms, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are hydrogen atom or a monovalent group having 1 to 30 carbon atoms selected from the group consisting of an aliphatic group, an alicyclic group, an aromatic group, a group in which an aliphatic group is combined with an aromatic group, or an alicyclic group, and their groups substituted by a halogen atom, nitro group, amino group, cyano group, methoxy group or acetoxyl group, provided that at least one of R.sup.3, R.sup.4, R.sup.5 and R.sup.6 is neither hydrogen atom nor the above-mentioned group which has 1 to 11 carbon atoms; a part of at least one of said R.sup.1 and said R.sup.2 being substituted with a group having a valence different therefrom. The precursor of the present invention can provided thin films by the LB technique, and by ring closure of the obtained LB films, there can be obtained ultrathin films having excellent heat resistance, electric properties, chemical resistance and mechanical properties, and having a thickness of not more than 10,000 .ANG., and if desired, a thickness of 10 to 1,000 .ANG.. Further, according to the process of the invention, polyimide thin films having a wide range of properties can be easily prepared. When a part of the group R.sup.2 is substituted with a trivalent or tetravalent group, the heat resistance can be improved since a ring having better heat resistance than an imide ring is formed.

    Abstract translation: 具有式（1）的重复单元的共聚两亲性聚酰亚胺前体：其中R1是具有至少2个碳原子的四价基团，R2是具有至少2个碳原子的二价基团，R3， R4，R5和R6是氢原子或碳原子数1〜30的选自脂肪族基团，脂环族基团，芳香族基团，脂肪族基团与芳基组合的基团的一价基团， 或脂环族基团，它们的基团被卤素原子，硝基，氨基，氰基，甲氧基或乙酰氧基取代，条件是R 3，R 4，R 5和R 6中的至少一个既不是氢原子也不是上述的， 具有1〜11个碳原子的上述基团; 所述R 1和所述R 2中的至少一个的一部分被具有不同价数的基团取代。 本发明的前体可以通过LB技术提供薄膜，通过闭环获得的LB膜，可以获得具有优异的耐热性，电性能，耐化学性和机械性能的超薄膜，并且具有 不超过10,000安格姆，如果需要，厚度为10至1000安格。 此外，根据本发明的方法，可以容易地制备具有宽范围性质的聚酰亚胺薄膜。 当基团R2的一部分被三价或四价基团取代时，耐热性可以提高，因为具有比酰亚胺环更好的耐热性的环。

    Polyurea and film composed of at least one monomolecular layer of a polyurea
    49.
    发明授权
    Polyurea and film composed of at least one monomolecular layer of a polyurea 失效
    聚氨酯的单分子层组成的聚氨酯和薄膜

    公开(公告)号：US5081212A

    公开(公告)日：1992-01-14

    申请号：US414535

    申请日：1989-09-29

    Applicant: Werner Prass ,  Ude Scheunemann

    Inventor： Werner Prass ,  Ude Scheunemann

    IPC: B05D1/20 ,  B32B27/00 ,  C08G18/32 ,  C08G18/38 ,  C08G18/73 ,  C08G18/76 ,  C08J5/18 ,  C08G18/10

    CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C08G18/324 ,  C08G18/325 ,  C08G18/3821 ,  C08G18/3825 ,  C08G18/73 ,  C08G18/7614 ,  Y10T428/31504

    Abstract: A polyurea of the general formula ##STR1## where X and Y are. independently of one another, a divalent radical whose chain contains in each case at least two carbon atoms, and A and B are, independently of one another, H or (C.sub.1 -C.sub.26)alkyl, and n is an integer greater than 4, which polyurea contains at least one (C.sub.6 -C.sub.26) alkyl group per repeating unit, is prepared by reacting the diamine NHA-X-NHB with roughly the equimolar amount of a diisocyanate OCN-Y-NCO. The polyurea is suitable for preparing ordered monomolecular LB films on a base (film-substrate-system). For this purpose it is dissolved in a volatile organic solvent which is not miscible with water, the solution is spread at the water/air interface, and the layer formed is compressed after the solvent has evaporated and it is transferred to a solid layer base by the Langmuir-Blodgett technique.

    Abstract translation: 其中X和Y是通式为“IMAGE”的聚脲。 彼此独立地是其链中含有至少两个碳原子的二价基团，A和B彼此独立地为H或（C 1 -C 26）烷基，n为大于4的整数，其中 聚脲含有每个重复单元至少一个（C 6 -C 26）烷基，通过使二胺NHA-X-NHB与大约等摩尔量的二异氰酸酯OCN-Y-NCO反应来制备。 聚脲适用于在基底（薄膜 - 基底 - 系统）上制备有序单分子LB薄膜。 为此，将其溶解在与水不混溶的挥发性有机溶剂中，溶液在水/空气界面处扩散，并且在溶剂蒸发后形成的层被压缩，并且通过 Langmuir-Blodgett技术。

    Production of thin films
    50.
    发明授权
    Production of thin films 失效
    生产薄膜

    公开(公告)号：US5035762A

    公开(公告)日：1991-07-30

    申请号：US223017

    申请日：1988-07-22

    Applicant: Gerhard Wegner ,  Arend J. Schouten ,  Gisela Duda ,  Thomas Arndt

    Inventor： Gerhard Wegner ,  Arend J. Schouten ,  Gisela Duda ,  Thomas Arndt

    IPC: B29C41/12 ,  B05C3/00 ,  B05D1/20 ,  B32B27/00 ,  C08J5/18

    CPC classification number: B05D1/202 ,  B82Y30/00 ,  B82Y40/00

    Abstract: Thin films are produced by a process in which organic polymers having long-chain side groups are dissolved in an organic solvent, the solution is spread at the water/air interface by the Langmuir-Blodgett technique and the film is transferred onto a solid base material after evaporation of the organic solvent, and the organic polymers used are those which contain long-chain n-alkyl side groups bonded to the main chain of the polymer via polar groups, and some of these long-chain n-alkyl side groups are replaced by shorter-chain n-alkyl side groups, by branched alkyl side groups having the same or a smaller number of carbon atoms or by equally long or shorter side groups having one or more C-C multiple bonds.This process can be used to produce film elements, for example for optical filters.

    Abstract translation: 通过将具有长链侧基的有机聚合物溶解在有机溶剂中的方法制造薄膜，通过Langmuir-Blodgett技术将溶液在水/空气界面扩散，并将膜转移到固体基材上 有机溶剂蒸发后，使用的有机聚合物是含有通过极性基团键合到聚合物主链的长链正烷基侧基的那些，并且这些长链正烷基侧基中的一些被替换 由短链正烷基侧基，具有相同或少数碳原子的支链烷基侧基或具有一个或多个CC多重键的同等长或短侧基组成。 该过程可以用于制造膜元件，例如用于滤光器。

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