Abstract:
Improved additives for lubricants and motor fuels are provided by borating the reaction product obtained upon reacting a petroleum sulfonic acid with a polyamine. Lubricating oil compositions and motor fuels containing said additives are also provided.
Abstract:
The triamide, tri(N-alkylamides) and tri(N-alkanolamides) of 2-oxabutane-1,3,4-tricarboxylic acid are novel compounds variously having utility in the fields of (a) corrosion prevention, being particularly useful as anti-corrosion agents in lubricants; (b) sizing of textiles; and (c) lubrication, being particularly useful as lubricants in cutting oils, in textile sizing, in the manufacture of cord, rope, twine, and the like, and as general lubricating compounds.
Abstract:
A process is disclosed for preparing novel compounds represented by the formula ##EQU1## wherein R is a C.sub.10 -C.sub.100 alkylene group, R' is a C.sub.1 -C.sub.5 alkylene group, n is an integer of 1 to 4, X is NH.sub.2, NHR", or NR"R", and Y is NH.sub.2, NHR", NR"R", or halogen, wherein, R" is an alkyl or alkylene polyamino group. The process comprises:1. reacting thiophosphoryl chloride with a monoamine (e.g., diethylamine) to give a reaction product comprising about 60 to about 100 mole percent phosphorochloridodiamidothioate and about 0 to about 40 mole percent phosphoroamidodichloridothioate;2. reacting the reaction product of step (1) with an alkylene polyamine to give a phosphorotriamidothioate;3. reacting the phosphorotriamidothioate of step (2) with an alkenyl succinic anhydride or acid; and4. treating the reaction product of step (3) with a basic material to give the desired product. The product of the process is useful as an additive in lubricating oils.
Abstract:
This invention concerns the preparation of stabilized polydimethylsiloxane-polyalkylene glycol block copolymers complexed with alkyl phenols. The resultant complexes have improved storage stability and are soluble in mineral oils. Solutions of the complexes in mineral oil exhibit better foam-inhibition than do oil dispersions of the uncomplexed polymers. In addition the oil-soluble complexes have improved extreme pressure properties.
Abstract:
Novel metal dialkyldithiophosphates prepared from oxalkylated long, straight-chain alcohols, acids and mercaptans and their incorporation in lubricating oils to enhance the lubricity and other properties thereof; and a method for operation of an automatic transmission incorporating said oils.
Abstract:
New lubricating oil additives are provided comprising the reaction product of a hydroxy compound, such as an alcohol or hydroxyaromatic compound, with an aliphatic chain substituted-carboxylic anhydride, acid, chloride, or ester, which aliphatic chain substituent is substantially saturated and contains at least about 30 carbon atoms, said reaction product being neutralized with an ashless basic compound, so that the final product or additive contains at least about 0.9%, up to about 2.5%, by weight of nitrogen. Lubricating oils, fuel oils, and carburants containing the new additives have excellent detergent, dispersing and anti-rust properties.
Abstract:
An additive mixture for lubricating oils and fuel oils having good antioxidant and anticorrosion properties comprising: (a) 4575 wt.% of an ortho alkyl phenol, (b) 5-20 wt.% of an ortho alkyl phenol disulphide and (c) 15-40 wt.% of an ortho alkyl phenol trisulphide. Optionally the additive may also contain small amounts of the corresponding mono- and tetra-sulphide. Such additives may be made by reacting an alkyl phenol with sulphur in the presence of an organic amine having a pKb of between 2 and 12, e.g. morpholine.
Abstract:
A dual purpose cutting oil is provided which serves as a heavy duty cutting oil and a machine lubricant. The oil comprises a base oil, an extreme pressure agent comprising primarily Bis ( Beta -chlorophenethyl) disulfide and a copper corrosion inhibitor comprising an alkyl derivative of 2,5-di-mercapto 1, 3,4thiadiazole.
Abstract:
A lubricating oil composition, particularly suitable for use in steam turbines or gas turbines, is disclosed. The turbine oil composition comprises a major amount of a mineral or synthetic hydrocarbon base oil and an effective amount of a combination of the following materials: triphenyl phosphite or a trialkylsubstituted phenyl phosphite; diphenylamine or alkylated diphenylamine; phenyl Alpha -naphthylamine, phenyl Beta naphthylamine, alkyl or alkaryl substituted phenyl Alpha naphthylamine, or alkyl or alkaryl substituted phenyl Beta naphthylamine; benzotriazole or alkyl-substituted benzotriazole; partial ester of alkyl or alkenyl succinic anhydride. In a preferred aspect, the turbine oil composition contains additionally an effective amount of a copolymer of N-vinyl-2pyrrolidone and an Alpha -olefin.
Abstract:
A lubricating coating is applied to a metallic surface by treating the surface with an acidic aqueous coating composition comprising a coating-forming lubricant and an oxidizing agent.