公开(公告)号：US4486608A

公开(公告)日：1984-12-04

申请号：US487476

申请日：1983-04-22

Applicant: Zenon Lysenko ,  Richard G. Pews

Inventor： Zenon Lysenko ,  Richard G. Pews

IPC: C07C45/30 ,  C07C45/63 ,  C07C51/58 ,  C07C47/14

CPC classification number: C07C51/58 ,  C07C45/30 ,  C07C45/63

Abstract: A process for making mono- and dichlorinated or brominated aldehydes from aldehydes having at least 3 carbon atoms and hydrogens alpha to the carbonyl group or primary alcohols having at least 3 carbon atoms and hydrogens in the 2-position by direct bromination or chlorination by carrying out the bromination or chlorination in an inert organic solvent with bromine or chlorine and containing a catalyst complex of HX and an N,N-dialkyl or cycloalkylformamide where X is a counterion.

Abstract translation: 通过直接溴化或氯化，通过直接溴化或氯化从具有至少3个碳原子的醛和具有至少3个碳原子的伯醇或2位氢原子的醛制备单和二氯或溴化醛的方法 在惰性有机溶剂中用溴或氯溴化或氯化，并含有HX和N，N-二烷基或环烷基甲酰胺的催化剂络合物，其中X为抗衡离子。

公开(公告)号：US4468354A

公开(公告)日：1984-08-28

申请号：US466451

申请日：1983-02-15

Applicant: Zenon Lysenko ,  Richard G. Pews

Inventor： Zenon Lysenko ,  Richard G. Pews

IPC: C07B61/00 ,  B01J27/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/17 ,  C07C255/56 ,  C07D213/61 ,  C07H7/02 ,  C07H7/033 ,  C07C121/34 ,  C07C121/76

CPC classification number: C07C255/00 ,  C07H7/033

Abstract: A continuous process for preparing 5-oxo-2,4-dichloro-4-alkyl or aryl pentanenitriles, e.g., 5-oxo-2,4-dichloro-4-methylpentanenitrile-1 by reacting an .alpha.,.alpha.-dichloroaldehyde with an acrylonitrile in a coil reactor.

Abstract translation: 通过使α，α-二氯醛与丙烯腈反应制备5-氧代-2,4-二氯-4-烷基或芳基戊亚胺的连续方法，例如5-氧代-2,4-二氯-4-甲基戊腈-1 在线圈反应器中。

公开(公告)号：US20130096251A1

公开(公告)日：2013-04-18

申请号：US13700961

申请日：2011-06-21

Applicant: Paul J. Popa ,  Gary E. Spilman ,  Zenon Lysenko ,  William A. Koonce ,  David A. Bobb ,  Martin C. Beebe ,  Thomas C. Thyne

Inventor： Paul J. Popa ,  Gary E. Spilman ,  Zenon Lysenko ,  William A. Koonce ,  David A. Bobb ,  Martin C. Beebe ,  Thomas C. Thyne

IPC: C08G18/83 ,  C08G18/12

CPC classification number: C08G18/837 ,  C08G18/10 ,  C08G18/12 ,  C08G18/289 ,  C08G18/4891 ,  C08G18/7621 ,  C09D175/04 ,  C09J175/04

Abstract: Embodiments of the invention relate to crosslinkable silyl group-containing polymers and methods of producing them. In one embodiment a method of producing a silyl polymer is provided. The method includes reacting at least one natural oil based polyol with at least one isocyanate to form at least one prepolymer having at least one NCO group. The at least one natural oil based polyol includes the reaction product of hydroxymethylated fatty acids or esters thereof and at least one polyol initiator. The prepolymer having at least one NCO group is reacted with at least one amino functional alkoxy silane to form the silyl polymer, such that the silyl polymer includes at least one crosslinkable silyl group, at least one urethane group, and at least one urea group in each molecule.

Abstract translation: 本发明的实施方案涉及可交联的含甲硅烷基的聚合物及其制备方法。 在一个实施方案中，提供了产生甲硅烷基聚合物的方法。 所述方法包括使至少一种天然油基多元醇与至少一种异氰酸酯反应以形成至少一种具有至少一个NCO基团的预聚物。 所述至少一种天然油基多元醇包括羟甲基化脂肪酸或其酯与至少一种多元醇引发剂的反应产物。 具有至少一个NCO基团的预聚物与至少一个氨基官能的烷氧基硅烷反应以形成甲硅烷基聚合物，使得甲硅烷基聚合物包括至少一个可交联甲硅烷基，至少一个氨基甲酸酯基和至少一个脲基 每个分子。

公开(公告)号：US20110031102A1

公开(公告)日：2011-02-10

申请号：US12667884

申请日：2008-06-20

Applicant: George J. Frycek ,  Shawn D. Feist ,  Timothy C. Frank ,  Zenon Lysenko ,  Joe D. Phillips ,  Bruce W. Pynnonen

Inventor： George J. Frycek ,  Shawn D. Feist ,  Timothy C. Frank ,  Zenon Lysenko ,  Joe D. Phillips ,  Bruce W. Pynnonen

IPC: B01D3/10 ,  B01D1/22 ,  B01D15/08 ,  B01D15/18

CPC classification number: B01D1/22 ,  B01D3/10 ,  B01D15/1821 ,  C07C67/56 ,  C11C3/00 ,  C11C3/12 ,  C07C69/675 ,  C07C69/24

Abstract: Effect separation of a composition of matter that includes at least two seed or plant oil derivatives into at least one desired product stream using at least two separation operations, which are independently selected from among several potential separation operations, in conjunction with at least one recycle stream from a separation operation.

Abstract translation: 使用至少两个分离操作将包含至少两种种子或植物油衍生物的物质组合物分离成至少一种所需的产物流，所述至少两种分离操作独立地选自几种潜在的分离操作，连同至少一种循环流 从分离操作。

公开(公告)号：US20100298486A1

公开(公告)日：2010-11-25

申请号：US12439956

申请日：2007-09-11

Applicant: Zenon Lysenko ,  Amaia Montoya-Goni ,  David Schrader ,  Alan K. Schrock ,  Gregory Chambard

Inventor： Zenon Lysenko ,  Amaia Montoya-Goni ,  David Schrader ,  Alan K. Schrock ,  Gregory Chambard

IPC: C08L51/04 ,  C08L25/02 ,  C08L53/00 ,  C08L55/02

CPC classification number: C08L53/02 ,  C08K5/103 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

Abstract: Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.

Abstract translation: 单亚乙烯基芳族聚合物，例如通用聚苯乙烯或高抗冲聚苯乙烯，用非官能化的非矿物油（例如植物油如卡诺拉油，棉籽油等）增塑。 单亚乙烯基芳族聚合物和油的混合物通常且优选不含任何显着量的官能化非矿物油，并且其通常包含至少0.1重量％的非官能化非矿物油，单独或与矿物油组合，基于 聚合物的重量。 非矿物油的碘值小于120，羟基数小于20。

公开(公告)号：US07247684B2

公开(公告)日：2007-07-24

申请号：US10489465

申请日：2002-04-11

Applicant: Leonardo C. Lopez ,  Jimmy D. Earls ,  Jerry E. White ,  Zenon Lysenko ,  Marvin L. Dettloff

Inventor： Leonardo C. Lopez ,  Jimmy D. Earls ,  Jerry E. White ,  Zenon Lysenko ,  Marvin L. Dettloff

IPC: B32B27/38 ,  C08L63/02 ,  C08L63/08

CPC classification number: C08L63/00 ,  C08G59/5006 ,  C08G59/56 ,  C08L27/00 ,  Y10T428/31678 ,  Y10T428/31681 ,  C08L2666/02

Abstract: The present invention provides network polymers obtained by curing compositions that comprise an ester with at least two terminal epoxy groups. Preferred esters include those represented by the formula (1), wherein each R1 independently represents a substituted or unsubstituted homoaliphatic or heteroaliphatic group; A represents a substituted or unsubstituted homoalkylene, hetemalkylene, arylene, or heteroarylene segment; and n represents an integer equal to or greater than 2.

Abstract translation: 本发明提供了通过固化包含具有至少两个末端环氧基团的酯的组合物而获得的网状聚合物。 优选的酯包括由式（1）表示的酯，其中每个R 1独立地表示取代或未取代的脂族或杂脂肪族基团; A表示取代或未取代的均亚烷基，亚甲氧基，亚芳基或杂亚芳基链段; n表示2以上的整数。

公开(公告)号：US20060293400A1

公开(公告)日：2006-12-28

申请号：US10554633

申请日：2004-04-23

Applicant: Eugene Wiltz Jr ,  Zenon Lysenko ,  Fabio Aguirre

Inventor： Eugene Wiltz Jr ,  Zenon Lysenko ,  Fabio Aguirre

IPC: C08G18/00

CPC classification number: C08G18/4288 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4244 ,  C08G18/632 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

Abstract: Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The polyester is prepared in a multi-step process from animal or vegetable fats, by recovering the constitutent fatty acids, hydroformylating carbon-carbon double bonds in the fatty acids and reducing to form hydroxymethyl groups, and then forming a polyester by reaction with an initiator compound.

Abstract translation: 柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。 高当量多元醇的至少一部分是含有羟甲基的聚酯。 通过回收组分脂肪酸，在脂肪酸中加氢甲酰化碳 - 碳双键并还原形成羟甲基，然后通过与引发剂反应形成聚酯，从动物或植物脂肪的多步法制备聚酯 复合。

公开(公告)号：US07097770B2

公开(公告)日：2006-08-29

申请号：US10471875

申请日：2002-03-21

Applicant: Zenon Lysenko ,  Sanjeev Katti ,  Richard Stringfield ,  Thomas Gregory ,  George J. Quarderer, Jr.

Inventor： Zenon Lysenko ,  Sanjeev Katti ,  Richard Stringfield ,  Thomas Gregory ,  George J. Quarderer, Jr.

IPC: B01D15/08 ,  C11B7/00

CPC classification number: C11B7/0008 ,  C11B7/0058

Abstract: A solid bed adsorptive process for separating a seed oil into two substantially pure triglyceride fractions. The process involves contacting a seed oil, such as castor oil, preferably as a concentrate, with an adsorbent in a bed, the adsorbent having a particle size greater than about 40 microns, and thereafter contacting the adsorbent with a desorbent material, preferably under minimal flow conditions, to obtain a raffinate output stream containing predominantly a second triglyceride and an extract output stream containing predominantly a first triglyceride. Purified fatty acid triglyceride esters obtainable from castor, vernonia, and lesquerella plant oils provide renewable, non-petroleum-based sources of chemical feedstocks.

Abstract translation: 用于将种子油分离成两个基本上纯的甘油三酯馏分的固体床吸附方法。 该方法包括使诸如蓖麻油（优选浓缩物）的种子油与床中的吸附剂接触，吸附剂具有大于约40微米的粒度，然后使吸附剂与解吸材料接触，优选地在最小程度上 流动条件，以获得主要含有第二甘油三酯和主要含有第一甘油三酸酯的提取物输出流的萃余液输出流。 从蓖麻，弗兰诺瓦和莱斯特雷拉植物油获得的纯化脂肪酸甘油三酯可提供可再生的非石油基化学原料来源。

公开(公告)号：US06222044B1

公开(公告)日：2001-04-24

申请号：US08661237

申请日：1996-06-10

Applicant: Zenon Lysenko

Inventor： Zenon Lysenko

IPC: C07D26354

CPC classification number: C07D263/57 ,  C07D235/18 ,  C07D277/66

Abstract: 2-(aryl)-benz(ox, thi, imid)azoles are prepared by reacting an aromatic aldehyde with hydroxylamine to form an aromatic aldehyde oxime, halogenating the oxime to form an aromatic hydroxamoyl halide, and then reacting this halide with certain aromatic amine compounds. The products may be nitrated and then reduced to form the corresponding diamines, which are useful in making PIBX polymers.

Abstract translation: 通过使芳族醛与羟胺反应以形成芳族醛肟，卤化肟以形成芳族羟肟基卤化物，然后使该卤化物与某些芳族胺反应制备2-（芳基） - 苯并（，硫，酰亚胺） 化合物。 可以将产物硝化，然后还原形成相应的二胺，其可用于制备PIBX聚合物。

公开(公告)号：US5710290A

公开(公告)日：1998-01-20

申请号：US734291

申请日：1996-10-21

Applicant: Zenon Lysenko ,  Clark H. Cummins ,  Ramki Subramanian ,  Richard F. Fibiger

Inventor： Zenon Lysenko ,  Clark H. Cummins ,  Ramki Subramanian ,  Richard F. Fibiger

IPC: C07C291/06 ,  C07D303/46 ,  C07D303/38 ,  C07C13/10 ,  C07C13/18

CPC classification number: C07D303/46 ,  C07C291/06 ,  C07C2101/14

Abstract: A suitably functionalized cycloaliphatic nitrile oxide can be used to convert unsaturated sites to alcohol or epoxy sites. The cycloaliphatic nitrile oxide may be useful in applications such as the preparation of polycarbonates, polyurethanes, or crosslinked polybutadiene, or poly(styrene-butadiene). The cycloaliphatic nitrile oxide is represented by the formula: ##STR1## wherein R' and each R are independently hydrogen, C.sub.1 -C.sub.12 alkyl, or halo; X and X' are independently hydrogen, halo, hydroxyl, or together with the carbon atoms to which they are attached form an epoxy group, with the proviso that at least one of X and X' is not hydrogen; and n is 1 or 2.

Abstract translation: 可以使用适当官能化的环脂族氧化腈将不饱和位点转化成醇或环氧化物位点。 环脂族氧化腈可用于制备聚碳酸酯，聚氨酯或交联聚丁二烯或聚（苯乙烯 - 丁二烯）等应用。 环脂族氧化腈由下式表示：其中R'和每个R独立地是氢，C 1 -C 12烷基或卤素; X和X'独立地是氢，卤素，羟基或与它们所连接的碳原子一起形成环氧基，条件是X和X'中的至少一个不是氢; n为1或2。