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公开(公告)号:US11912871B2
公开(公告)日:2024-02-27
申请号:US17251843
申请日:2018-07-12
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Baoqing Zheng , Yan Wu , Jia Tang , James C. Bohling , Juan Zhao , Yujiang Wang
IPC: C08L83/10 , C08F2/26 , C08F220/06 , C08F220/14 , C08F220/18 , C08F230/02 , C08G77/00 , C08G77/16 , C08G77/20 , C08G77/44 , C08K5/37 , C08L25/14 , C09D5/08
CPC classification number: C08L83/10 , C08F2/26 , C08F220/06 , C08F220/14 , C08F220/1804 , C08F230/02 , C08G77/16 , C08G77/20 , C08G77/44 , C08G77/80 , C08K5/37 , C08L25/14 , C09D5/08 , C08L2201/50 , C08L2201/52
Abstract: An aqueous dispersion comprising a silicone-acrylic polymer with reduced coagulum, a process of preparing the aqueous dispersion, and an aqueous coating composition comprising the aqueous dispersion and providing coatings with improved corrosion resistance.
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公开(公告)号:US20230399445A1
公开(公告)日:2023-12-14
申请号:US18332838
申请日:2023-06-12
Applicant: SOLENIS TECHNOLOGIES CAYMAN, L.P.
Inventor: Nathalie Bruzzano , Christian Boekelo , Markus Bröcher
IPC: C08F220/56 , C08F220/34 , C08F2/28 , C08F226/02 , C08L33/14 , C08L33/26
CPC classification number: C08F220/56 , C08F220/34 , C08F2/28 , C08F226/02 , C08L33/14 , C08L33/26 , C08L2201/50
Abstract: Methods for manufacturing a polymer dispersion, polymer dispersions, and their use are provided herein. The methods of manufacturing the polymer dispersion comprise the steps of providing a reaction mixture in an aqueous medium comprising a polymeric dispersant and a monomer composition comprising radically polymerizable monomers, and subjecting the monomer composition in the reaction mixture to a radical polymerization to synthesize a dispersed polymer so as to form the polymer dispersion, wherein the ratio of the polymeric dispersant to the dispersed polymer in the polymer dispersion is in a specified narrow range. These polymer dispersions are designated as water-in-water (w/w) polymer dispersions.
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公开(公告)号:US20230312970A1
公开(公告)日:2023-10-05
申请号:US18206220
申请日:2023-06-06
Applicant: NIPPON PAINT AUTOMOTIVE COATINGS CO., LTD.
Inventor: Kazuki SEKINE , Hiromi FUJIMOTO , Mika MATSUSHIMA , Masatoshi OHTONARI , Sayaka SAITO , Takuma OKADA , Mari NAKAMOTO
IPC: C09D133/08 , C08F220/18 , B05D7/00 , C08F2/06 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/20 , C08K5/3492 , C08L33/12 , C09D133/12 , C09D167/00 , C09D175/04
CPC classification number: C09D133/08 , C08F220/1804 , C08F220/1808 , B05D7/572 , C08F2/06 , C08F212/08 , C08F220/06 , C08F220/14 , C08F220/20 , C08K5/34922 , C08L33/12 , C09D133/12 , C09D167/00 , C09D175/04 , B05D2420/01 , B05D2420/02 , B05D2420/03 , C08L2201/50 , C08L2207/53
Abstract: The object of the present invention is to provide an aqueous coating composition which exhibits a small viscosity change and can form a coating film having a superior coating film appearance even when the amount of the solvent contained in the aqueous coating composition is reduced due to changes in the coating environment.
The present invention provides an aqueous coating composition comprising an acrylic resin dispersion (A) and a melamine resin (B), wherein the acrylic resin dispersion (A) has a core/shell structure, the acrylic resin dispersion (A) is a dispersion of a solution-polymerization product of a core part preparation monomer (a-1) and a shell part preparation monomer (a-2), wherein the shell part preparation monomer (a-2) comprises an acid group-containing polymerizable monomer, the mass ratio of the core part to the shell part of the acrylic resin dispersion (A) is in the range of core part/shell part=30/70 to 70/30, the shell part of the acrylic resin dispersion (A) has an acid group, and the neutralization rate of the acid groups in the shell part is 50% or more, the weight-average molecular weight of the acrylic resin dispersion (A) is in the range of 10,000 to 70,000, the core part preparation monomer (a-1) has an acid value of 10 mg KOH/g or less, and the shell part preparation monomer (a-2) has an acid value of 10 mg KOH/g or more and 70 mg KOH/g or less, the whole monomer mixture comprising the core part preparation monomer (a-1) and the shell part preparation monomer (a-2) has an acid value of 10 mg KOH/g or more and 30 mg KOH/g or less, the glass transition temperature of the acrylic resin dispersion (A) is in the range of −10 to 60° C., and the melamine resin (B) comprises a hydrophobic melamine resin.-
公开(公告)号:US20230257574A1
公开(公告)日:2023-08-17
申请号:US18005143
申请日:2021-07-13
Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.
Inventor: Toshinari MIZUHASHI , Naoki HASHIMOTO
IPC: C08L33/14
CPC classification number: C08L33/14 , C08L2205/03 , C08L2205/025 , C08L2201/50
Abstract: The present invention provides an ethylene/glycidyl acrylate copolymer aqueous dispersion composition ensuring an obtained film (e.g., coating film) with excellent adhesion, and high stability of the film itself.
Specifically, the present invention provides an ethylene/glycidyl acrylate copolymer aqueous dispersion composition, comprising:
(A) an ethylene/glycidyl acrylate copolymer,
(B1) an ethylene oxide/propylene oxide copolymer,
(B2) a polyoxyalkylene-based non-ionic surfactant,
(C) an alkali-soluble acrylic resin emulsion, and
(D) a basic substance,
wherein (B1) and (B2) are present in a total amount of 5 to 15 parts by mass, and (C) is present in an amount of 0.1 to 50 parts by mass per 100 parts by mass of (A), and
(D) is present in an amount of 0.01 to 0.2 parts by mass per part by mass of (C).-
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公开(公告)号:US20230257514A1
公开(公告)日:2023-08-17
申请号:US18189250
申请日:2023-03-24
Inventor: Sang-Youl KIM , Jong-Ho SO
CPC classification number: C08G61/08 , C08L65/00 , C08L2201/50 , C08L2203/16 , C08G2261/418 , C08G2261/3324
Abstract: The present disclosure relates to a cyclic olefin polymer having an epoxy functional group prepared by ring-opening metathesis polymerization and method of preparing the same.
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公开(公告)号:US20180162983A1
公开(公告)日:2018-06-14
申请号:US15576589
申请日:2016-05-10
Applicant: DIC Corporation
Inventor: Ryuichi MATSUOKA , Hiroyoshi KANNARI , Sadamu NAGAHAMA
CPC classification number: C08G18/4252 , C08G18/12 , C08G18/3231 , C08G18/4238 , C08G18/4283 , C08G18/48 , C08G18/65 , C08G18/755 , C08G18/758 , C08K3/20 , C08L75/04 , C08L2201/50 , C08G18/30
Abstract: The present invention provides an aqueous urethane resin composition containing (A) a urethane resin, (B) an organic solvent having a boiling point of 150 to 350° C., and (C) an aqueous medium, the aqueous urethane resin composition being characterized in that the organic solvent (B) has a Hansen solubility parameter in which a dispersion member (δd) is 15.5 MPa0.5 or more and less than 20 MPa0.5, a polar member (δp) is 4.5 MPa0.5 or more and less than 12 MPa0.5, and a hydrogen-bonding member (δh) is 3 MPa0.5 or more and less than 10.5 MPa0.5. The aqueous urethane resin composition has excellent film formability, corrosion resistance, chemical resistance, and substrate adhesiveness, and is capable of forming a low-toxic coating film.
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公开(公告)号:US09884968B2
公开(公告)日:2018-02-06
申请号:US14356061
申请日:2012-10-04
Applicant: COATEX
Inventor: Denis Ruhlmann , Jean-Marc Suau
IPC: C09D7/00 , C09D133/08 , C09D133/10 , C08F2/24 , C08K5/04 , C09J133/08 , C09J133/10
CPC classification number: C09D7/43 , C08F2/24 , C08L2201/50 , C09D133/08 , C09D133/10 , C09J133/08 , C09J133/10
Abstract: The present invention relates to new acrylic associative thickening agents which, when polymerized in the presence of particular polyglycerols, ultimately result in an increase of the open time of the paint or of the thick coating in which they are incorporated. By so doing, painters and applicators will have more time to work the paint layers gradually or to correct imperfections such as paint droplets, traces of brushes and filling-knives.
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公开(公告)号:US20170226243A1
公开(公告)日:2017-08-10
申请号:US15581229
申请日:2017-04-28
Inventor: Jason Shih-Hao Chen , Michael Richard Kessler , Michael Dennis Zenner
IPC: C08F122/20 , C09J135/02
CPC classification number: C08F122/20 , C07D493/04 , C08G18/3218 , C08G18/771 , C08L75/08 , C08L2201/50 , C09J4/00 , C09J135/02
Abstract: The present invention relates to tackifier compounds and methods of using the same. In various embodiments, the present invention provides a tackifier compound including independently substituted or unsubstituted fused rings A and B each independently chosen from (C5-C10)cycloalkyl and (C2-C10)heterocyclyl. Fused ring A is substituted with (R1)1-8 and fused ring B is substituted with —(OC(O)R′C(O)R2)1-8. At each occurrence R′ is independently chosen from (C2-C10)alkanylene, (C2-C10)alkenylene, (C2-C10)alkynylene, (C5-C20(arylene), and (C1-C20)heteroarylene, wherein R′ is unsubstituted or substituted. At each occurrence R′ is independently selected from —OH, —OR3, and —OC(O)R′C(O)R2. At each occurrence R2 is independently chosen from —OH, —OR3, —NH2, —NHR3, and —NR32. At each occurrence R3 is independently chosen from (C1-C10)alkanyl, (C2-C10)alkenyl, (C2-C10)alkynyl, C5-C20(aryl), and (C1-C20)heteroaryl, wherein R3 is unsubstituted or substituted.
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公开(公告)号:US20170096504A1
公开(公告)日:2017-04-06
申请号:US15316024
申请日:2015-06-04
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Yoshinori NANBA , Dai FUKAMI , Takuya YAMABE , Taketo KATO , Makoto ONO , Takahiro TAIRA , Hirotoshi YOSHIDA , Taku YAMANAKA
IPC: C08F114/26 , C08L27/18
CPC classification number: C08F114/26 , C08F2/24 , C08F14/00 , C08F14/26 , C08L27/18 , C08L2201/50 , C08F2/26
Abstract: The present invention provides a method for producing a fluoropolymer aqueous dispersion having a significantly small particle size and excellent dispersion stability. The present invention relates to a method for producing an aqueous dispersion containing at least one fluoropolymer selected from the group consisting of polytetrafluoroethylene and melt-fabricable fluororesins excluding polytetrafluoroethylene. The method includes polymerizing a fluoromonomer in an aqueous medium in the presence of a fluorosurfactant and a polymerization initiator. The fluorosurfactant has a concentration in the aqueous medium of not lower than 0.8 times the critical micelle concentration of the fluorosurfactant.
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公开(公告)号:US20170066914A1
公开(公告)日:2017-03-09
申请号:US15211453
申请日:2016-07-15
Applicant: WHITFORD CORPORATION
Inventor: Leonard W. Harvey , Michael Coates , Julie K. Wright
IPC: C08L27/18 , C09D127/18 , C08J3/00 , C09D5/03
CPC classification number: C08L27/18 , C08J3/005 , C08J3/12 , C08J2327/18 , C08L27/12 , C08L27/24 , C08L29/10 , C08L2201/50 , C08L2205/02 , C08L2205/025 , C09D5/03 , C09D127/12 , C09D127/18 , C09D129/10 , Y10T428/2982 , C08L2666/04
Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (□m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processable fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (□m). Blending of the dispersions facilitates interaction of the LPTFE and MPF on a submicron level to facilitate intimate blending such that, when the blended fluoropolymer composition is dried, a crystal structure representing a true alloy of the fluoropolymers is formed, having melt characteristics that differ from those of the individual fluoropolymers. The blended fluoropolymer composition may be used to provide a coating having improved impermeability, stain resistance, abrasion resistance, smoothness, and higher contact angles.
Abstract translation: 提供混合的含氟聚合物组合物。 在一个实施方案中,将第一含氟聚合物的液体分散体与第二含氟聚合物的液体分散体共混。 第一含氟聚合物可以是聚四氟乙烯(PTFE),例如已经通过分散体或乳液聚合方法聚合并且未被聚集,照射或热降解的低分子量PTFE(LPTFE)。 LPTFE可以是水分散体的形式,其平均粒度小于1.0微米(□m),LPTFE的第一熔融温度(Tm)为332℃或更低。 第二含氟聚合物可以是可熔融加工的含氟聚合物(MPF),例如甲基氟代烷氧基(MFA),氟化乙烯丙烯(FEP)或全氟烷氧基(PFA),例如以水分散体的形式,并且具有平均粒径 小于1.0微米(□m)。 分散体的混合促进了LPTFE和MPF在亚微米级的相互作用,以促进紧密共混,使得当混合的含氟聚合物组合物被干燥时,形成表示含氟聚合物的真正合金的晶体结构,其熔体特性与那些 的各种含氟聚合物。 混合的含氟聚合物组合物可用于提供具有改进的不渗透性,耐污性,耐磨性,光滑度和更高接触角的涂层。
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