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    THIN FILM AND COMPOUND USED IN THE SAME
    61.
    发明申请
    THIN FILM AND COMPOUND USED IN THE SAME 审中-公开
    薄膜及其使用的化合物

    公开(公告)号：US20130001472A1

    公开(公告)日：2013-01-03

    申请号：US13583177

    申请日：2011-03-04

    Applicant: Joji Ohshita ,  Toshihiro Murafuji ,  Yusuke Kuramochi ,  Takashi Kaikoh ,  Hideyuki Higashimura

    Inventor： Joji Ohshita ,  Toshihiro Murafuji ,  Yusuke Kuramochi ,  Takashi Kaikoh ,  Hideyuki Higashimura

    IPC: C07F9/94 ,  C09K11/06 ,  B82Y30/00

    CPC classification number: C07F9/94 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/188 ,  H01L51/0077 ,  H01L51/5016 ,  H05B33/145

    Abstract: To provide a novel material exhibiting excellent light-emitting characteristics using a heavy metal element having relatively abundant reserve.A thin film containing a compound of Formula (1): wherein Ar1 and Ar2 are each independently a C3-30 aromatic ring; R1 and R2 are a substituent; a and b are each independently an integer of 0 to 12, wherein when a is 2 or more, each R1 is optionally different from each other and two R1 are optionally bonded with each other to form a ring structure, and when b is 2 or more, each R2 is optionally different from each other and two R2 are optionally bonded with each other to form a ring structure; A1 is any of direct bond, —O—, —S—, —S(═O)—, —S(═O)2—, —PR3—, —NR4—, and —C(—R5)2—; R3 is a hydrogen atom or a substituent; R4 is a hydrogen atom or a substituent; R5 is a hydrogen atom or a substituent and two R5 are optionally different from each other; E1 is a monovalent group having 50 or less carbon atoms; L1 is a ligand having 50 or less carbon atoms; c is an integer of 0 to 3, wherein when c is 2 or more, each L1 is optionally different from each other; and each combination of a combination of E1 and Ar1 and a combination of E1 and Ar2 optionally forms a bond; and when c is 1 to 3, each combination of a combination of L1 and E1, a combination of L1 and Ar1, a combination of L1 and Ar2, and a combination of L1 and L1 optionally forms a bond.

    Abstract translation: 使用具有相对丰富的储备的重金属元素提供显示出优异的发光特性的新型材料。 含有式（1）化合物的薄膜：其中Ar1和Ar2各自独立地为C3-30芳环; R1和R2是取代基; a和b各自独立地为0〜12的整数，其中当a为2以上时，每个R 1可以彼此不同，并且两个R 1彼此任意地键合形成环结构，当b为2或 更优选地，每个R 2彼此可选地彼此不同，并且两个R 2彼此可选地键合以形成环结构; A1是直接键合，-O - ， - S - ， - S（= O） - ， - S（= O）2 - ， - PR 3 - ， - NR 4 - 和-C（ - R 5） R3是氢原子或取代基; R4是氢原子或取代基; R5是氢原子或取代基，两个R5任选地彼此不同; E1是具有50个或更少碳原子的一价基团; L1是具有50个或更少碳原子的配体; c为0〜3的整数，其中，当c为2以上时，各L1彼此不同; 并且E1和Ar1的组合以及E1和Ar2的组合的每个组合可以任选地形成键; 当c为1〜3时，L1和E1的组合，L1和Ar1的组合，L1和Ar2的组合以及L1和L1的组合的组合可以任意地形成键。

    METHOD FOR PRODUCING AROMATIC COMPOUND POLYMER
    64.
    发明申请
    METHOD FOR PRODUCING AROMATIC COMPOUND POLYMER 审中-公开
    生产芳族化合物聚合物的方法

    公开(公告)号：US20120016147A1

    公开(公告)日：2012-01-19

    申请号：US13242973

    申请日：2011-09-23

    Applicant: Hideyuki HIGASHIMURA ,  Daisuke FUKUSHIMA ,  Kazuei OHUCHI

    Inventor： Hideyuki HIGASHIMURA ,  Daisuke FUKUSHIMA ,  Kazuei OHUCHI

    IPC: C07F9/00

    CPC classification number: C08G61/12 ,  C07C49/92 ,  C07F9/005 ,  C08G61/02 ,  C08G61/10

    Abstract: A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P=Af/Ai  (A) and Eo=(Epa+Epc)/2 [V]  (B)

    Abstract translation: 一种芳族化合物聚合物的制造方法，其特征在于，在氧化剂的存在下，使直接与芳香环连接的2个以上的氢原子的一种以上的芳香族化合物氧化聚合， 的过渡金属络合物或由过渡金属络合物和活化剂制备的催化剂，所述催化剂具有下式（A）定义的参数P为0.50以上，以及由下式（B ）为0.50 [V]以上：P = Af / Ai（A），Eo =（Epa + Epc）/ 2 [V]（B）

    Method for producing aromatic polymer
    65.
    发明授权
    Method for producing aromatic polymer 有权
    芳族聚合物的制备方法

    公开(公告)号：US07999058B2

    公开(公告)日：2011-08-16

    申请号：US12278879

    申请日：2007-02-13

    Applicant: Tsutomu Yokozawa ,  Hideyuki Higashimura

    Inventor： Tsutomu Yokozawa ,  Hideyuki Higashimura

    IPC: C08G64/00 ,  C08G63/02

    CPC classification number: C08G61/10

    Abstract: A method for producing an aromatic polymer includes polycondensing an aromatic compound represented by formula (I) in the presence of a nickel complex containing a phosphine compound represented by formula (II), wherein, Ar denotes an aromatic ring containing organic group, which aromatic ring may contain an oxygen atom and/or a nitrogen atom; R denotes a monovalent group containing a hydrocarbon group; k is an integer of 1 or more; X denotes an halogen atom, a nitro group or a group represented by —SO3Q, wherein Q denotes a monovalent hydrocarbon group; Y denotes O, S, an imino group, an ethenylene group, or an ethynylene group; n denotes 0 or 1; and M denotes H, —B(OQ1)2, —Si(Q2)3, —Sn(Q3)3 or —Z1(Z2)m, wherein Q1 denotes H or a monovalent hydrocarbon group; Q2 and Q3 denote a monovalent hydrocarbon group; Z1 denotes a metal atom or a metal ion; Z2 denotes a counter ion; and m is an integer of 0 or higher; wherein, R1 denotes a monovalent hydrocarbon group, and R2 denotes a divalent hydrocarbon group.

    Abstract translation: 一种芳族聚合物的制造方法，其特征在于，在含有式（II）表示的膦化合物的镍络合物的存在下，使由式（I）表示的芳香族化合物缩聚，其中，Ar表示含有有机基团的芳香环，该芳香环 可以含有氧原子和/或氮原子; R表示含有烃基的一价基团; k为1以上的整数， X表示卤原子，硝基或-SO 3 Q表示的基团，其中Q表示一价烃基; Y表示O，S，亚氨基，亚乙烯基或亚乙炔基; n表示0或1; M表示H，-B（OQ1）2，-Si（Q2）3，-Sn（Q3）3或-Z1（Z2）m，其中Q1表示H或一价烃基; Q2和Q3表示一价烃基; Z1表示金属原子或金属离子; Z2表示抗衡离子; m为0以上的整数。 其中，R1表示一价烃基，R2表示二价烃基。

    COMPOSITION COMPRISING PHOSPHORESCENT COMPOUND AND LIGHT EMITTING DEVICE USING THE COMPOSITION
    66.
    发明申请
    COMPOSITION COMPRISING PHOSPHORESCENT COMPOUND AND LIGHT EMITTING DEVICE USING THE COMPOSITION 有权
    包含磷化合物的组合物和使用组合物的发光装置

    公开(公告)号：US20110127467A1

    公开(公告)日：2011-06-02

    申请号：US13056259

    申请日：2009-07-28

    Applicant: Nobuhiko Akino ,  Kenta Tanaka ,  Hideyuki Higashimura

    Inventor： Nobuhiko Akino ,  Kenta Tanaka ,  Hideyuki Higashimura

    IPC: C09K11/06 ,  C07D239/24

    CPC classification number: C07D239/26 ,  C08G2261/3221 ,  C08G2261/5242 ,  C08K5/3462 ,  C08L65/00 ,  C09K11/06 ,  C09K2211/1044 ,  H01L51/0067 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

    Abstract: A composition comprising a phosphorescent compound, and a compound having a structure containing three or more repeating units having a dipole moment dimension of 1.0 Debye or more connected in series, wherein, based on the total number of dimer structures composed of any two repeating units connected in series contained in the above-described structure, the proportion of the number of dimer structures in which the dimension D2 of the dipole moment of the dimer structure, the dimension D1a of the dipole moment of the first repeating unit constituting the dimer structure and the dimension D1b of the dipole moment of the second repeating unit constituting the dimer structure satisfy a relation represented by the following formula (A): D1a

    Abstract translation: 包含磷光化合物的组合物和具有包含三个或更多个偶极矩尺寸为1.0德拜或更多的重复单元的结构的化合物，其中基于由连接的任何两个重复单元组成的二聚体结构的总数 串联包含在上述结构中，二聚体结构的偶极矩的尺寸D2，构成二聚体结构的第一重复单元的偶极矩的尺寸D1a和二聚体结构的二聚体结构的数量的比例 构成二聚体结构的第二重复单元的偶极矩的尺寸D1b满足由下式（A）表示的关系：D1a

    CYCLIC COMPOUND, ITS METAL COMPLEX AND MODIFIED METAL COMPLEX
    67.
    发明申请
    CYCLIC COMPOUND, ITS METAL COMPLEX AND MODIFIED METAL COMPLEX 有权
    周期化合物，金属复合物和改性金属络合物

    公开(公告)号：US20110015059A1

    公开(公告)日：2011-01-20

    申请号：US12811025

    申请日：2008-09-05

    Applicant: Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Yusuke Ishii

    Inventor： Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Yusuke Ishii

    IPC: B01J31/22 ,  C07D471/22 ,  C07D487/22 ,  C07F15/06 ,  C07F19/00 ,  C07F15/04 ,  C07F1/08 ,  C08F26/06

    CPC classification number: H01M4/8652 ,  C07D207/335 ,  C07D471/04 ,  C07D471/22 ,  C07D487/22 ,  H01G9/2018 ,  H01L51/0083 ,  H01L51/009 ,  H01M4/9008 ,  H01M4/9075 ,  H01M4/9091 ,  H01M4/923 ,  H01M4/925 ,  H01M4/928 ,  H01M8/0289 ,  H01M8/1016 ,  Y02E10/542 ,  Y02E60/521

    Abstract: A compound represented by formula (1): wherein Y1 to Y4 each independently represent any one of the following groups: in which Rα represents a hydrogen atom or a monovalent hydrocarbon group; P1 to P4 each independently represent a group of atoms necessary for forming a heterocyclic ring together with each of Y1 to Y4 and the two carbon atoms adjacent to each of Y1 to Y4, respectively; P5 and P6 each independently represent a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z1 bonds or Z2 bonds and the two carbon atoms adjacent to the carbon atom to which Z1 bonds or Z2 bonds; P1 and P2, P2 and P6, P6 and P4, P4 and P3, P3 and P5, and P5 and P1 may further combine with each other to form a ring; Q1 and Q2 each independently represent a connecting group or a direct binding; and Z1 and Z2 each independently represent any one of the following groups; —NRβ2, —ORβ, —SRβ, —PRβ2 in which Rβ represents a hydrogen atom or a monovalent hydrocarbon group, and when plural Rβs are present, these plural Rβs may be the same or different from each other.

    Abstract translation: 由式（1）表示的化合物：其中Y 1至Y 4各自独立地表示以下基团中的任一个：其中Rα表示氢原子或一价烃基; P1〜P4各自独立地表示与Y 1〜Y 4中的每一个以及Y1〜Y4中的每个相邻的2个碳原子一起形成杂环所需的原子团。 P5和P6各自独立地表示与Z1键或Z2键以及与Z1键或Z2键相邻的碳原子相邻的两个碳原子一起形成环状骨架所必需的一组原子; P1和P2，P2和P6，P6和P4，P4和P3，P3和P5，P5和P1可以进一步组合形成环; Q1和Q2各自独立地表示连接基团或直接结合; Z1和Z2各自独立地表示以下基团中的任何一个; -NR＆bgr; 2，-OR＆bgr; -SR＆bgr; -PR＆bgr; 2其中R＆bgr; 表示氢原子或一价烃基，当存在多个R b时，这些多个R a可相同或不同。

    LAYERED STRUCTURE
    68.
    发明申请
    LAYERED STRUCTURE 有权
    层状结构

    公开(公告)号：US20110006294A1

    公开(公告)日：2011-01-13

    申请号：US12921108

    申请日：2009-03-05

    Applicant: Masanobu Tanaka ,  Kenta Tanaka ,  Shohgo Yamauchi ,  Hideyuki Higashimura

    Inventor： Masanobu Tanaka ,  Kenta Tanaka ,  Shohgo Yamauchi ,  Hideyuki Higashimura

    IPC: H01L51/54 ,  C08G63/00

    CPC classification number: H01L51/0039 ,  C08G61/02 ,  C08G61/12 ,  C08G61/122 ,  C08G2261/124 ,  C08G2261/1426 ,  C08G2261/3142 ,  C08G2261/316 ,  C08G2261/3221 ,  C08G2261/5222 ,  C08G2261/80 ,  H01L51/5048 ,  Y02E10/549 ,  Y10S428/917

    Abstract: Disclosed is a layered structure including a first electrode and a second electrode, a light-emitting layer or a charge separation layer between the first electrode and the second electrode, and a layer containing a conjugated polymer compound between the light-emitting layer or the charge separation layer and the first electrode, wherein the conjugated polymer compound contains a repeating unit selected from the group consisting of a repeating unit represented by formula (1): wherein Ar1 represents a divalent aromatic group, R1 represents a substituent group having a group represented by formula (2), Ar1 may have a substituent group other than R1, and n1 represents an integer of 1 or more; -(R2)c1-(Q1)n2-Y1(M1)a1(Z1)b1  (2) wherein R2 represents a divalent aromatic group which may have a substituent group, Q1 represents a divalent organic group which may have a substituent group, Y1 represents a carbocation, an ammonium cation, a phosphonyl cation or a sulfonyl cation, M1 represents F−, Cl−, Br−, I−, OH−, RaSO3−, RaCOO−, ClO−, ClO2−, ClO3−, ClO4−, SCN−, CN−, NO3−, SO42−, HSO4−, PO43−, HPO42−, H2PO4−, BF4− or PF6−, Z1 represents a metal ion or an ammonium ion which may have a substituent group, c1 represents 0 or 1, n2 represents an integer of 0 or more, provided that n2 is 0 when c1 is 0, a1 represents an integer of 1 or more, b1 represents an integer of 0 or more, a1 and b1 are selected so that the charge of the substituent group represented by formula (2) is 0, Ra represents an alkyl group having 1 to 30 carbon atoms, which may have a substituent group, or an aryl group having 6 to 50 carbon atoms, which may have a substituent group.

    Abstract translation: 公开了一种层状结构，其包括第一电极和第二电极，在第一电极和第二电极之间的发光层或电荷分离层，以及在发光层或电荷之间含有共轭高分子化合物的层 分离层和第一电极，其中共轭高分子化合物含有选自由式（1）表示的重复单元的重复单元：其中Ar1表示二价芳族基团，R1表示具有由 式（2）中，Ar 1可以具有除了R1以外的取代基，n1表示1以上的整数。 - （R2）c1-（Q1）n2-Y1（M1）a1（Z1）b1（2）其中R2表示可以具有取代基的二价芳族基团，Q1表示可以具有取代基的二价有机基团， Y1表示碳阳离子，铵阳离子，膦酰基阳离子或磺酰基阳离子，M1表示F-，Cl-，Br-，I-，OH-，RaSO 3 - ，RaCOO-，ClO-，ClO 2 - ，ClO 3 - ，ClO 4 - ，SCN-，CN-，NO3-，SO42-，HSO4-，PO43-，HPO42-，H2PO4-，BF4-或PF6-，Z1表示可具有取代基的金属离子或铵离子，c1表示 0或1，n2表示0以上的整数，条件是当c1为0时，n2为0，a1表示1以上的整数，b1表示0以上的整数，a1和b1选择为电荷 由式（2）表示的取代基为0，R a表示可以具有取代基的碳原子数1〜30的烷基或碳原子数6〜50的芳基，可以具有取代基 ent组。

    POLYMERIC ADSORPTION FILMS AND PROCESSES FOR PRODUCING THESE
    69.
    发明申请
    POLYMERIC ADSORPTION FILMS AND PROCESSES FOR PRODUCING THESE 审中-公开
    聚合吸附膜及其生产工艺

    公开(公告)号：US20100133476A1

    公开(公告)日：2010-06-03

    申请号：US12411599

    申请日：2009-03-26

    Applicant: Kenta TANAKA ,  Hideyuki Higashimura ,  Toshihiko Tanaka ,  Tomohisa Temma ,  Daisuke Fukushima

    Inventor： Kenta TANAKA ,  Hideyuki Higashimura ,  Toshihiko Tanaka ,  Tomohisa Temma ,  Daisuke Fukushima

    IPC: H01B1/12

    CPC classification number: C08G61/00 ,  C08G61/12 ,  C08G2261/126 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08L65/00 ,  H01L51/0036 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/4253

    Abstract: The present invention provides a polymeric adsorption film comprising a polymer containing two or more charge-transport blocks and a substrate, wherein any of the charge-transport blocks is preferentially adhered to a surface of the substrate; a polymeric adsorption film comprising a polymer containing two or more charge-transport blocks and a substrate, wherein any of the charge-transport blocks different from the charge-transport block preferentially adhered to a surface of the substrate is preferentially exposed; or a polymeric adsorption film comprising a polymer and a substrate, wherein the polymer contains two or more charge-transport blocks and any charge-transport block selected from the charge-transport blocks is adhered to a surface of the substrate more preferentially than the other charge-transport blocks.

    Abstract translation: 本发明提供一种聚合物吸附膜，其包含含有两个或更多个电荷输送嵌段和基材的聚合物，其中任何电荷传输嵌段优先粘附于基材的表面; 包含含有两个或更多个电荷输送嵌段的聚合物和基材的聚合物吸附膜，其中与电荷传输嵌段不同的电荷传输嵌段优先粘附到基材表面的任何电荷传输嵌段优先暴露; 或包含聚合物和基底的聚合物吸附膜，其中所述聚合物含有两个或更多个电荷输送嵌段，并且从所述电荷传输嵌段中选择的任何电荷传输嵌段比其它电荷更优先地粘附到所述衬底的表面 运输块。

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