Abstract:
C-NITROSO COMPOUNDS, ESPECIALLY NITROSOBENZENE, ARE STABILIZED BY THE ADDITION OF COMPOUNDS SUCH AS SALTS OR CHELATES OF HEAVY METALS, ESPECIALLY MANGANESE, COPPER OR COBALT.
Abstract:
A process has been provided for preparing perhalo nitroso alkanes from a halocarbon compound of the formula RCX2H wherein X is fluorine, chlorine, or bromine and R is a halogen or a perhalo radical and wherein the halogens substituents are fluorine, chlorine, or bromine. The process is carried out by reacting the halocarbon with nitrosyl chloride in a vapor phase at a pressure of one atmosphere or less and at a temperature from 160* C. and lower while irradiating the reaction mixture with radiant energy at the characteristic wavelength displayed by nitrosyl chloride.
ARE PRODUCED BY REACTING METHYL NITRIETE AND PERFLUOROGLUTARIC ANHYDRIDE OR PERFLUOROSUCCINIC ANHYDRIDE AND THEN DECARBOXYLANTING THE RESULATNT PRODUCT. THE COMPOUNDS, WHICH CAN BE HYDROLYZED TO PRODUCE THE CORRESPONDING NITROSO-SUBSTITUTED FLUORCARBON ACIDS, ARE USED AS COMONOMERS IN NITRROSO RUBBERS.