Process for preparing nitroso halocarbons
    62.
    发明授权
    Process for preparing nitroso halocarbons 失效
    制备NITROSO HALOCARBONS的方法

    公开(公告)号:US3616359A

    公开(公告)日:1971-10-26

    申请号:US3616359D

    申请日:1968-08-20

    CPC classification number: C07C201/00 Y10S204/903

    Abstract: A process has been provided for preparing perhalo nitroso alkanes from a halocarbon compound of the formula RCX2H wherein X is fluorine, chlorine, or bromine and R is a halogen or a perhalo radical and wherein the halogens substituents are fluorine, chlorine, or bromine. The process is carried out by reacting the halocarbon with nitrosyl chloride in a vapor phase at a pressure of one atmosphere or less and at a temperature from 160* C. and lower while irradiating the reaction mixture with radiant energy at the characteristic wavelength displayed by nitrosyl chloride.

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