Abstract:
Cellulose is dissolved in an ionic liquid without derivatization, and is regenerated in a range of structural forms without requiring the use of harmful or volatile organic solvents. Cellulose solubility and the solution properties can be controlled by the selection of the ionic liquid constituents, with small cations and halide or pseudohalide anions favoring solution.
Abstract:
A regenerated cellulose-encapsulated active substance and a method for encapsulating an active substance in a regenerated cellulose matrix are disclosed. The distribution of the active substance is preferably substantially homogeneous within the matrix of regenerated cellulose. The regenerated cellulose (i) has about the same molecular weight as the original cellulose from which it is prepared (ii) is substantially free of added substituent groups relative to the starting cellulose and is also substantially free of entrapped ionic liquid degradation products.
Abstract:
Invasive medical catheters with distal end assemblies having a protective surface coating bonded thereto are constructed by applying a hydrophilic primer to at least a portion of a tubular polymer body. The primer coating chemically bonds to the polymer substrate by developing covalent bonding or cross linking with the substrate. A plurality of printed electrode elements are then formed on the polymer body, e.g., by a pad printing process. Once the primer coating is bonded to the polymer body, the assembly is coated with a regenerated cellulose layer, e.g., by a viscose process well known in the art. The primer coating, already bonded to the catheter body, is then bonded with the regenerated cellulose at an elevated temperature. After curing, the polymer body, primer coating and regenerated cellulose layer become a single composite material, thereby preventing the regenerated cellulose coating from any movement relative to the polymer body, and providing a secure protective layer over the electrodes.
Abstract:
A method for producing cellulose particles whereby a cellulose solution is dispersed in a regenerant or nonsolvent and the cellulose is regenerated or precipitated in dispersed form into cellulose particles.
Abstract:
A process for the production of shaped structures of cellulose, in particular fibers of cellulose, by shaping and subsequent regeneration of water-soluble cellulose derivatives is described. The process employs water-soluble alcohols, water-soluble ketones or, in particular, water or mixtures thereof as solvents for the shaping and carrying out the shaping by a dry shaping process.
Abstract:
The present invention is to provide a modified cellulose regenerated fiber having a practically endurable tenacity, and being excellent in dye-affinity, and having anti-funguses and deodorizing properties. The present invention comprises preliminarily molding chitosan or acetylated chitosan into a fine particle, mixing the fine particle body with cellulose viscose prior to spinning, and spinning the mixture, at the inclusion regenerated fiber.
Abstract:
An edible body composed of a cellulose having a crystal form of cellulose II, which is regenerated from an aqueous solution of an alkali metal hydroxide, and at least one guest component selected from polypeptides and edible polysaccharides. The cellulose II or a homogeneous mixture of the cellulose II and polysaccharide is present in the form of a sea component or a continuous phase in an amount of at least 10% based on the edible body. The edible body is made by adding at least one guest component selected from polypeptides, polysaccharides and living body constituents composed mainly thereof to an alkali solution in which up to 50 parts by weight of an undissolved cellulose is swollen and dispersed per 100 parts by weight of a dissolved cellulose, directly or after dissolution in an aqueous solution of an alkali, to form a dope in which at least 50% by weight of the total guest component is dissolved, extruding the dope through an extruder, coagulating the extrudate, and neutralizing, water-washing and, if necessary, drying the extrudate.
Abstract:
A caramel-containing, liquid smoke impregnated, cellulosic article, e.g. casing, with the caramel uniformly distributed and immobilized, without chemical bonding, in the cellulose so as to be substantially nonextractable in water and steam and method of producing said article.
Abstract:
A shaped article, especially a tubing, is disclosed which comprises a plasticized cellulose hydrate composition of high mechanical strength which is obtained by treating a plasticized cellulose composition obtained by treating cellulose hydrate with a plasticity-enhancing amount of at least one plasticizing alkyl-derivative which comprises an alkyl containing from about 8 to about 24 carbon atoms and which is selected from the group consisting of alkylamido-bis-dimethylene-triazinone-tetra-methylol, alkylamino-bis-dimethylene-triazinone-tetra-methylol and a substantially water insoluble ester of an aliphatic monocarboxylic acid containing from about 9 to about 25 carbon atoms and a polyalcohol, such as glycerol or polyethylene glycol, with a synthetic polymer containing recurring oxyalkylene units and at least one, preferably at least two, terminal N-methylolcarbamate groups, and water and/or plasticizer.Such shaped articles can be prepared by mixing a viscose solution with a liquid containing the plasticizing alkyl derivative, introducing the resulting mixture into a precipitating bath, washing the precipitated shaped body in the gel state, treating it with an acidic solution of the synthetic polymer and drying it in the heat. Tube shaped articles are especially suited as sausage casings.
Abstract:
A process for producing fire retardant phosphonitrilate polymers by reacting phosphonitrilic halide with a hydroxyl compound such as an aliphatic or aromatic alcohol at not more than about 40.degree.C in the presence of an acid acceptor, such as pyridine, under conditions such that a relatively low concentration of the hydroxyl compound is present during the initial 1/2 to 3 hours of the reaction and the reaction conditions are maintained at from 20.degree.-50.degree.C for a period of 1/2 to 120 hours and, optionally, further heating the reaction mixture to a temperature of 40.degree.-80.degree.C for 1/2 to 81/2 hours. The phosphonitrilate polymers are suitable for fire retarding cellulosic materials such as regenerated cellulose, rayon and the like.