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    Hydrocarbon conversion with an acidic multimetallic catalytic composite
    72.
    发明授权
    Hydrocarbon conversion with an acidic multimetallic catalytic composite 失效
    用酸性多金属催化复合材料进行烃转化

    公开(公告)号：US4097368A

    公开(公告)日：1978-06-27

    申请号：US734473

    申请日：1976-10-18

    Applicant: John C. Hayes

    Inventor： John C. Hayes

    IPC: B01J23/89 ,  C10G35/09 ,  C10G35/08 ,  B01J11/08 ,  C07C5/28 ,  C10G13/02

    CPC classification number: B01J23/89 ,  B01J23/8966 ,  C10G35/09 ,  Y10S585/94

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a nickel component, a cobalt component, and a halogen component with a porous carrier material. A preferred modifying component for the disclosed catalytic composite is a Group IVA metallic component. The platinum gold, nickel, cobalt and halogen components are present in the multimetallic catalyst in amounts, respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 2.5 wt. % nickel, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal and nickel are present therein in the elemental metallic state, and substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

    Abstract translation: 通过在碳氢化合物转化条件下使它们与含有催化有效量的铂族组分，镍组分，钴组分和卤素组分的组合的多元载体材料的酸性多金属催化复合物接触来转化碳氢化合物。 所公开的催化复合材料的优选改性组分是IVA族金属组分。 铂金，镍，钴和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约2.5重量％ ％镍，约0.05至约5wt。 ％钴，和约0.1至约3.5wt。 ％卤素。 此外，这些金属组分在仔细控制的氧化态下均匀分散在整个多孔载体材料中，使得基本上所有的铂族金属和镍以元素金属状态存在，并且基本上所有的催化可用的钴组分存在于 元素金属状态或在碳氢化合物转化条件下或在这些状态的混合物中可还原成元素金属状态的状态。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

    Hydrocarbon conversion with a sulfided acidic multimetallic catalytic composite
    73.
    发明授权
    Hydrocarbon conversion with a sulfided acidic multimetallic catalytic composite 失效

    公开(公告)号：US3986948A

    公开(公告)日：1976-10-19

    申请号：US568543

    申请日：1975-04-16

    Applicant: Richard E. Rausch

    Inventor： Richard E. Rausch

    IPC: B01J23/62 ,  B01J37/22 ,  C10G35/09 ,  B01J11/08 ,  C10G35/08

    CPC classification number: B01J23/626 ,  B01J37/22 ,  C10G35/09

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a sulfided acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a tin component, a halogen component, and a sulfur component with a porous carrier material. The platinum or palladium component, rhodium component, tin component, halogen component, and sulfur component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium metal, about 0.01 to about 2 wt. % rhodium, about 0.01 to about 5 wt. % tin, about 0.1 to about 3.5 wt. % halogen, and about 0.01 to about 1 wt. % sulfur. Moreover, the metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium component and the rhodium component are present therein in a sulfided state or in a mixture of the sulfided state and the elemental metallic state and such that substantially all of the tin component is present therein in an oxidation state above the elemental metal and in a particle size less than 100 Angstroms in maximum dimension. The sulfiding of the catalytic composite is performed prior to any contact of the composite with hydrocarbon and after substantially all of the platinum or palladium and rhodium components are reduced to the elemental metallic state by treatment with a sulfiding gas at conditions selected to incorporate about 0.01 to about 1 wt. % sulfur. The resulting sulfided catalyst has the capability of diminishing undesired demethylation and other hydrogenolysis reactions during initial operation of the process and markedly increasing the over-all stability of the process.

    Catalysis
    74.
    发明授权
    Catalysis 失效
    催化

    公开(公告)号：US3909452A

    公开(公告)日：1975-09-30

    申请号：US26236372

    申请日：1972-06-13

    Applicant: JOHNSON MATTHEY CO LTD

    Inventor： ACRES GARY JAMES KEITH

    IPC: B01D53/86 ,  B01J23/46 ,  B01J23/54 ,  B01J23/89 ,  B01J35/04 ,  C01B3/40 ,  F02B1/04 ,  B01J11/40 ,  B01J11/06 ,  B01J11/08

    CPC classification number: B01J35/04 ,  B01D53/86 ,  B01J23/464 ,  B01J23/54 ,  B01J23/8933 ,  C01B3/40 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  F02B1/04 ,  Y02P20/52

    Abstract: This invention relates to catalysts for use in the oxidation of organic compounds, for example methane, ethane, propylene and carbon monoxide, as well as for the production of methane by the steam reforming of naptha and naptha distillates. The catalyst includes an inert material on which there is applied an intermediate coating of at least one oxide selected from the group consisting of the oxides of titanium, zirconium, hafnium and thorium and a final or surface coating of a mixture or alloy of platinum, rhodium and optionally a base metal in which rhodium constitutes from 1-50 weight % and the base metal, if present, constitutes from 0.01 to 25 weight % of the total metal content.

    Abstract translation: 本发明涉及用于氧化有机化合物的催化剂，例如甲烷，乙烷，丙烯和一氧化碳，以及通过萘甲酸和萘甲酸馏分的蒸汽重整来生产甲烷。 催化剂包括惰性材料，在其上施加至少一种选自钛，锆，铪和钍的氧化物的至少一种氧化物的中间涂层，以及铂，铑的混合物或合金的最终或表面涂层 和任选的其中铑构成1-50重量％的贱金属，如果存在贱金属，则其占总金属含量的0.01至25重量％。

    Method of manufacturing a hydrodesulfurization catalyst
    77.
    发明授权
    Method of manufacturing a hydrodesulfurization catalyst 失效
    加氢脱硫催化剂的制造方法

    公开(公告)号：US3873470A

    公开(公告)日：1975-03-25

    申请号：US35825773

    申请日：1973-05-07

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： CONWAY JOHN E ,  PARKER ROBIN J

    IPC: B01J23/64 ,  B01J23/85 ,  C10G45/08 ,  B01J11/08 ,  B01J11/22

    CPC classification number: B01J23/64 ,  B01J23/85 ,  C10G45/08

    Abstract: An improved hydrodesulfurization catalyst characterized by the method of manufacture. The improvement is attributed to certain novel oxidizing procedures. Residual fuel oils are desulfurized in contact with the catalyst which comprises a Group VIB and Group VIII metal component preferably on an alumina support.

    Abstract translation: 一种改进的加氢脱硫催化剂，其特征在于制备方法。 改进归因于某些新的氧化程序。 残余燃料油与催化剂接触脱硫，该催化剂优选在氧化铝载体上包含VIB族和VIII族金属组分。

    Process for preparing a platinum-rhenium catalyst on an alumina support
    79.
    发明授权
    Process for preparing a platinum-rhenium catalyst on an alumina support 失效
    制备氧化铝载体上的铑 - 铑催化剂的方法

    公开(公告)号：US3846343A

    公开(公告)日：1974-11-05

    申请号：US24973972

    申请日：1972-05-02

    Applicant: ERICKSON H ,  MOOI J ,  KEITH C ,  HINDIN S

    Inventor： ERICKSON H ,  HINDIN S ,  KEITH C ,  MOOI J

    IPC: B01J23/656 ,  B01J37/22 ,  C10G35/09 ,  B01J11/08

    CPC classification number: B01J23/6567 ,  B01J37/22 ,  C10G35/09

    Abstract: Rhenium and platinum series metal-containing, calcined catalysts are prepared by I. DRYING AN AQUEOUS SLURRY OF HYDRATED ALUMINA TO OBTAIN A MIXTURE WHICH CAN BE FORMED INTO MACROSIZE PARTICLES; II. FORMING THE MIXTURE INTO MACROSIZE PARTICLES; III. CALCINING THE PARTICLES EITHER AT VERY HIGH TEMPERATURES OR IN THE PRESENCE OF WATER VAPOR, OR BOTH, SO AS TO REDUCE THE SURFACE AREA OF THE PARTICLES; IV. IMPREGNATING THE PARTICLES WITH AQUEOUS SOLUTION OF PLATINUM SERIES METAL COMPOUND AND AQUEOUS SOLUTION OF RHENIUM COMPOUND; AND V. RECALCINING THE IMPREGNATED PARTICLES UNDER GENERALLY LESS SEVERE CONDITIONS THAN IN (III) ABOVE.

    Abstract translation: 铼和含铂系金属的煅烧催化剂是通过I制备的。水解氧化铝的水溶液干燥以获得可形成大分子颗粒的混合物; 二， 将混合物成型成大粒子; 三， 在非常高的温度下或在水蒸气存在下或以下两种方式计算颗粒物，以减少颗粒的表面积; 四， 用铂系金属化合物的水溶液和铑化合物的水溶液引入颗粒; 和V.在（III）以内的一般条件下，重新排除所引用的颗粒。

    Catalyst for the spontaneous decomposition of monopropellant hydrazine
    80.
    发明授权
    Catalyst for the spontaneous decomposition of monopropellant hydrazine 失效
    用于MONOPROPELLANT HYDRAZINE自发分解的催化剂

    公开(公告)号：US3846339A

    公开(公告)日：1974-11-05

    申请号：US3248670

    申请日：1970-04-13

    Applicant: TRW INC

    Inventor： BLUMENTHAL J ,  GUTH E

    IPC: B01J23/36 ,  B01J23/656 ,  B01J23/68 ,  B01J23/84 ,  C06D5/04 ,  B01J11/08 ,  B01J11/22

    CPC classification number: B01J23/36 ,  B01J23/6567 ,  B01J23/688 ,  B01J23/84 ,  C06D5/04

    Abstract: This invention relates to a low cost spontaneous decomposition catalyst for hydrazine or mixtures containing hydrazine-hydrazine nitrate propellant fuels, which permits a low temperature ignition of the fuels and retains its activity after exposure to the propellant flame environment. The catalyst is produced by coating rhenium metal or a rhenium-molybdenum mixture on a support body such as alumina. Iron, nickel, copper, silver, gold, iridium, or ruthenium may be included as co-catalyst metals.

    Abstract translation: 本发明涉及用于肼的低成本自发分解催化剂或含有肼 - 肼硝酸盐推进剂燃料的混合物，其允许燃料的低温点火并且在暴露于推进剂火焰环境之后保持其活性。 催化剂是通过将铼金属或铼 - 钼混合物涂覆在载体如氧化铝上来制备的。 可以包括铁，镍，铜，银，金，铱或钌作为助催化剂金属。

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