公开(公告)号：US09505712B2

公开(公告)日：2016-11-29

申请号：US14398425

申请日：2013-05-02

Applicant: STAMICARBON B.V.

Inventor： Johan Albert Arno Van Den Tillaart ,  Jozef Hubert Meessen

IPC: C07C273/04 ,  B01J10/00 ,  B01J19/00

CPC classification number: C07C273/04 ,  B01J10/00 ,  B01J19/0013 ,  B01J2219/00051 ,  Y02P20/142

Abstract: Method for the production of urea from ammonia and carbon dioxide in a urea plant containing a high-pressure synthesis section with a horizontal pool condenser, wherein the method comprises exchanging heat from a high pressure process medium received in a shell section of the pool condenser to a medium pressure urea containing solution received in a first heat exchanging section provided in the pool condenser to at least decompose ammonium carbamate into NH3 and CO2, wherein the method further comprises exchanging heat from the high pressure process medium to a low pressure steam condensate received in a second heat exchanging section provided in the pool condenser to produce low pressure steam. The invention also relates to an apparatus for the production of urea from ammonia and carbon dioxide.

Abstract translation: 在含有具有水平冷凝器的高压合成部分的尿素装置中由氨和二氧化碳生产尿素的方法，其中所述方法包括将从所述池冷凝器的壳部分中接收的高压处理介质的热交换到 容纳在所述池冷凝器中的第一热交换部分中的中压含尿素溶液以至少将氨基甲酸铵分解成NH 3和CO 2，其中所述方法还包括将热量从所述高压处理介质交换到低压蒸汽冷凝物 设置在池冷凝器中以产生低压蒸汽的第二热交换部分。 本发明还涉及一种用于从氨和二氧化碳生产尿素的设备。

公开(公告)号：US20160184758A1

公开(公告)日：2016-06-30

申请号：US14902831

申请日：2014-07-04

Applicant: STAMICARBON B.V.

Inventor： Petrus Catharina Gerlach SOONS ,  Wilfried Marc Renaat DIRKX

IPC: B01D47/10

CPC classification number: B01D47/10 ,  B01D47/06 ,  C07C273/02

Abstract: Disclosed is a method for the removal of urea dust from the off- gas of a finishing section (1) of a urea production plant, the method comprises subjecting the off-gas to quenching with water (06) so as to produce quenched off-gas, and subjecting the quenched off-gas to scrubbing using at least one venturi scrubber (11). As a result, a lower pressure drop over the scrubber is attained, and a more efficient growth of urea particles, facilitating the removal thereof.

Abstract translation: 公开了一种从尿素生产设备的精加工部分（1）的废气中除去尿素灰尘的方法，该方法包括使废气用水淬火（06），以产生骤冷的， 气体，并使用至少一个文丘里洗涤器（11）对骤冷的废气进行洗涤。 因此，可以获得比洗涤器更低的压降，更有效地生长尿素颗粒，便于其去除。

公开(公告)号：US20150322000A1

公开(公告)日：2015-11-12

申请号：US14655330

申请日：2013-12-27

Applicant: STAMICARBON B.V.

Inventor： Fredericus Henricus Maria BUITINK ,  Luc Louis Maria DIELTJENS

IPC: C07C273/04 ,  B01J19/24

CPC classification number: C07C273/04 ,  B01J19/02 ,  B01J19/24 ,  B01J19/245 ,  B01J2219/00006 ,  B01J2219/00024 ,  B01J2219/00103 ,  B01J2219/00765 ,  B01J2219/0286 ,  B01J2219/24 ,  C07C275/02

Abstract: Disclosed is a urea plant comprising an additional reactor. With reference to the regular components of a urea plant, including a recovery section and a high pressure carbamate condenser, the additional reactor is positioned between the recovery section and the high pressure carbamate condenser. The invention also relates to a process for the synthesis of urea, comprising an additional reaction step converting, at an earlier stage than conventional, recovered carbamate into urea.

Abstract translation: 公开了一种包含另外的反应器的尿素装置。 参考包括回收部分和高压氨基甲酸酯冷凝器的尿素装置的常规部件，附加反应器位于回收部分和高压氨基甲酸酯冷凝器之间。 本发明还涉及一种用于合成尿素的方法，其包括另外的反应步骤，其比在常规方法中将回收的氨基甲酸酯转化成尿素的步骤更好。

公开(公告)号：US20150048277A1

公开(公告)日：2015-02-19

申请号：US14386327

申请日：2013-03-26

Applicant: Stamicarbon B.V.

Inventor： Paola Volpi ,  Barbara Morico ,  Lorena Mosca ,  Cristina Guazzotti ,  Fabio Prosperi ,  Gaetano Iaquaniello

IPC: C01B3/38 ,  B01J7/00

CPC classification number: C01B3/38 ,  B01J7/00 ,  B01J8/0257 ,  B01J2208/00221 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2219/18 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1235

Abstract: A reformer furnace (1), comprising: at least one triple conduit assembly (200), including a flue gas conduit (220) enclosing a reaction conduit (240) enclosing a product gas conduit (260), wherein: the reaction conduit (240) extends between a lower end (244) defining a reaction gas inlet (245), and a closed upper end (242); the product gas conduit (260) extends between an upper end (262) defining a product gas inlet (263), and a lower end (264) defining a product gas outlet (265); the flue gas conduit (220) extends between an upper end (222) defining a flue gas inlet (223), and a lower end (224) defining a flue gas outlet (225); and an annulus (250) between the reaction conduit (240) and the product gas conduit (260) comprises a catalyst (252); a combustion chamber (100) that encloses an approximate upper half (226, 246, 266) of the at least one triple conduit assembly (200) while an approximate lower half (228, 248, 268) thereof resides outside of and below the combustion chamber, and that includes at least one burner (110), disposed inside of the combustion chamber and outside of the flue gas conduit (220), such that the approximate upper half (226) of the flue gas conduit substantially shields the reaction conduit (240) from direct burner flame heat radiation and impingement.

Abstract translation: 一种重整炉（1），包括：至少一个三重管道组件（200），包括封闭产品气体管道（260）的反应管道（240）的烟道气导管（220），其中：反应管道（240） ）在限定反应气体入口（245）的下端（244）和封闭的上端（242）之间延伸; 产品气体管道（260）在限定产品气体入口（263）的上端（262）和限定产品气体出口（265）的下端（264）之间延伸; 所述烟道气管道（220）在限定烟道气入口（223）的上端（222）和限定出烟气出口（225）的下端（224）之间延伸; 并且所述反应管道（240）和所述产物气体管道（260）之间的环（250）包括催化剂（252）; 封闭所述至少一个三重导管组件（200）的近似上半部（226,246,266）的燃烧室（100），同时其近似下半部（228,248,268）位于燃烧室外面和下方 并且其包括设置在燃烧室内部和烟道气导管（220）外部的至少一个燃烧器（110），使得烟道气管道的大致上半部（226）基本上屏蔽反应管道 240）从直接燃烧器火焰的热辐射和冲击。

公开(公告)号：US20140249343A1

公开(公告)日：2014-09-04

申请号：US14118214

申请日：2012-06-28

Applicant: UNIVERSITÄT STUTTGART ,  STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： Yvonne Traa ,  Daniel Geiss

IPC: C07C2/66

CPC classification number: C07C2/66 ,  B01J29/068 ,  B01J29/44 ,  B01J37/08 ,  B01J37/18 ,  B01J2229/186 ,  C07C2/76 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/65 ,  C07C2529/67 ,  C07C2529/69 ,  C07C2529/85 ,  C07C2531/22 ,  C07C15/02 ,  C07C15/27

Abstract: Disclosed is a process for the direct alkylation of aromatic compounds with alkanes. To this end a judicious catalyst combination is provided. The composition comprises palladium as a catalytically active metal, and zinc as a promoter, or a metal such as tin having a comparable promoting action. The metals are contained in a zeolite support, or a similar support of a metal organic framework type or a silico alumino phosphate type.

Abstract translation: 公开了用烷烃直接烷基化芳族化合物的方法。 为此，提供了明智的催化剂组合。 组合物包含作为催化活性金属的钯，作为助催化剂的锌，或具有可比较的促进作用的金属如锡。 金属包含在沸石载体中，或类似的金属有机骨架型或硅铝型磷酸盐载体。

公开(公告)号：US20140134096A1

公开(公告)日：2014-05-15

申请号：US14115831

申请日：2012-05-07

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： Fabio Angelini ,  Lucia Barbato

IPC: C01B17/04 ,  C01B3/04

CPC classification number: C01B17/0495 ,  B01D53/8612 ,  B01D2251/102 ,  B01D2256/16 ,  B01J8/00 ,  C01B3/02 ,  C01B3/04 ,  C01B17/0404 ,  C01B17/0408 ,  C01B17/0426 ,  Y02E60/364 ,  Y02P20/129

Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with reduced, and preferably zero, emissions. The method comprises the catalytic oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The process is conducted in a reaction chamber comprising a bifunctional catalyst material, so as to favor both the partial oxidation of H2S and the dissociation thereof.

Abstract translation: 公开了一种从含H 2 S的气流同时生产氢和硫的方法，具有减少的，优选为零的排放。 该方法包括H2S的催化氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 该方法在包含双官能催化剂材料的反应室中进行，以有利于H2S的部分氧化和其解离。

公开(公告)号：US20140105814A1

公开(公告)日：2014-04-17

申请号：US14118201

申请日：2012-06-15

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： Gaetano Iaquaniello ,  Barbara Cucchiella ,  Elena Antonetti

IPC: C01B3/12 ,  B01J7/00

CPC classification number: C01B3/505 ,  B01J7/00 ,  B01J19/245 ,  B01J2219/24 ,  C01B3/12 ,  C01B3/34 ,  C01B3/36 ,  C01B3/38 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/0294 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0894 ,  C01B2203/1047

Abstract: The present invention relates to a method for hydrogen production and to a method of hydrogen and/or carbon dioxide production from syngas. The method comprises the steps of: (i) providing a gas stream comprising hydrogen and carbon monoxide, (ii) separating at least part of hydrogen from the stream yielding a hydrogen-depleted stream, (iii) subjecting the hydrogen-depleted stream to a water-gas shift reaction, and (iv) separating hydrogen from the stream resulting from step (iii). The method according to the invention improves the conversion of carbon monoxide in the water gas shift reaction and allows to increase the hydrogen production by 10-15% and to increase the overall energy efficiency of the system by 5-7%. The invention further relates to a plant for hydrogen and/or carbon dioxide production suitable for the method of the invention.

Abstract translation: 本发明涉及一种氢气生产方法和一种从合成气生产氢气和/或二氧化碳的方法。 该方法包括以下步骤：（i）提供包含氢气和一氧化碳的气流，（ii）从流中分离至少部分氢气，产生贫氢气流，（iii）将贫氢气流 水煤气变换反应，和（iv）从步骤（iii）产生的物流中分离氢气。 根据本发明的方法改善了水煤气变换反应中一氧化碳的转化，并允许将氢气产量提高10-15％，并将系统的整体能量效率提高5-7％。 本发明还涉及适用于本发明方法的氢和/或二氧化碳生产设备。

公开(公告)号：US20250108350A1

公开(公告)日：2025-04-03

申请号：US18850970

申请日：2023-03-28

Applicant: STAMICARBON B.V.

Inventor： Paul Maria Gerardus Clemens Petrus Hubertus JORISSEN ,  Alexander Aleida Antonius SCHEERDER ,  Kirk Anguah OFEI ,  Alessandro BRUN ,  Michael SIMML

IPC: B01J3/02 ,  B01J3/03 ,  C05C9/00 ,  C07C273/04

Abstract: The disclosure pertains in certain embodiments to a plant and to urea production in a plant comprising a valve body comprising an inner body part and an outer body part.

公开(公告)号：US12209061B2

公开(公告)日：2025-01-28

申请号：US17368924

申请日：2021-07-07

Applicant: STAMICARBON B.V.

Inventor： Joey Dobree ,  Johannes Henricus Mennen

IPC: C07C273/04 ,  B01D3/00 ,  B01J19/00 ,  C01C1/18 ,  C05C1/00 ,  C05C9/00 ,  C05G5/23 ,  C07C273/02 ,  C07C273/10 ,  C07C273/14 ,  C07C275/02

Abstract: Disclosed is a method for the integrated production of two different urea products. One is an aqueous urea solution suitable for use in NOx abatement (generally indicated as Diesel Exhaust Fluid DEF). The other is a solution used as a fertilizer, viz. Urea Ammonium Nitrate (UAN). The production of DEF and UAN are integrated as follows: ammonia recovered from the production of urea is used as a feed to the production of ammonium nitrate. At least part of an aqueous urea stream from urea production, is mixed with ammonium nitrate so as to obtain UAN.

公开(公告)号：US12186725B2

公开(公告)日：2025-01-07

申请号：US18578192

申请日：2023-05-12

Applicant: Stamicarbon B.V.

Inventor： Rahul Patil ,  Lambertus Wilhelmus Gevers ,  Markus Theodorus Marie Michaël Wagemans

IPC: B01J19/00 ,  B01J4/00 ,  C07C273/04

Abstract: The disclosure pertains to a high pressure carbamate condensation apparatus for a urea plant, a urea plant, and a urea production method. The apparatus comprises a first U-shaped tube bundle arranged around a second U-shaped tube bundle.