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    Self Limiting Catalyst Composition and Propylene Polymerization Process
    81.
    发明申请
    Self Limiting Catalyst Composition and Propylene Polymerization Process 有权
    自限催化剂组合物和丙烯聚合方法

    公开(公告)号：US20100317510A1

    公开(公告)日：2010-12-16

    申请号：US12850170

    申请日：2010-08-04

    Applicant: Linfeng Chen ,  Richard E. Campbell, JR.

    Inventor： Linfeng Chen ,  Richard E. Campbell, JR.

    IPC: C08F4/60 ,  C08F4/602

    CPC classification number: C08F10/00 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/04 ,  B01J31/143 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6496 ,  C08F4/6495 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/18

    Abstract: A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent (SCA) comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent (ALA) compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl(poly)(oxyalkyl)-(poly)ester derivatives thereof; or inertly substituted derivatives of the foregoing.

    Abstract translation: 一种用于丙烯聚合的催化剂组合物，其包含一种或多种齐格勒 - 纳塔前催化剂组合物，其包含一种或多种过渡金属化合物和一种或多种芳族二羧酸内电子给体的酯; 一种或多种含铝助催化剂; 包含至少一种含有至少一个与硅原子键合的C 1-10烷氧基的含硅化合物的选择性控制剂（SCA）和一种或多种包含一种或多种脂族或脂环族羧酸的活性限制剂（ALA）化合物; 烷基 - ，环烷基 - 或烷基（聚）（烷氧基） - （聚）酯衍生物; 或惰性取代的衍生物。

    Procatalyst Composition Including Silyl Ester Internal Donor and Method
    86.
    发明申请
    Procatalyst Composition Including Silyl Ester Internal Donor and Method 有权
    主要成分包括硅烷内酯和方法

    公开(公告)号：US20100130709A1

    公开(公告)日：2010-05-27

    申请号：US12622889

    申请日：2009-11-20

    Applicant: Linfeng Chen ,  Tak W. Leung ,  Tao Tao

    Inventor： Linfeng Chen ,  Tak W. Leung ,  Tao Tao

    IPC: B01J31/02 ,  C07F7/08 ,  C08F2/00

    CPC classification number: C08F10/06 ,  C07F7/081 ,  C08F110/06 ,  C08F4/654 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18

    Abstract: The present disclosure provides silyl esters and silyl diol esters suitable as internal electron donors in procatalysts for polymer production. Disclosed are procatalyst compositions formed from a procatalyst precursor and an internal electron donor that is a silyl ester or a silyl diol ester. The procatalyst compositions can be used with a cocatalyst and optionally an external electron donor and/or an activity limiting agent to form a Ziegler-Nana catalyst composition. The present catalyst compositions exhibit high catalyst activity and form olefin-based polymers with broad molecular weight distribution, favorable flexural modulus, and high isotacticity.

    Abstract translation: 本公开内容提供了用作聚合物生产的前催化剂中适合作为内电子供体的甲硅烷基酯和甲硅烷基二醇酯。 公开了由前催化剂前体和作为甲硅烷基酯或甲硅烷基二醇酯的内部电子给体形成的前催化剂组合物。 主催化剂组合物可以与助催化剂和任选的外电子给体和/或活性限制剂一起使用以形成齐格勒 - 纳娜催化剂组合物。 本催化剂组合物表现出高的催化剂活性并形成具有宽分子量分布，有利的弯曲模量和高全同立构规整的烯烃基聚合物。

    Catalyst composition for ethylene polymerization
    88.
    发明授权
    Catalyst composition for ethylene polymerization 有权
    用于乙烯聚合的催化剂组合物

    公开(公告)号：US07393910B2

    公开(公告)日：2008-07-01

    申请号：US10569245

    申请日：2004-08-18

    Applicant: Richard E. Campbell, Jr. ,  Linfeng Chen ,  Roger B. Painter ,  Robert N. Reib ,  Michael W. Tilston

    Inventor： Richard E. Campbell, Jr. ,  Linfeng Chen ,  Roger B. Painter ,  Robert N. Reib ,  Michael W. Tilston

    IPC: C08F110/02

    CPC classification number: C08F110/02 ,  C08F2/002 ,  C08F2/40 ,  C08F4/6494 ,  C08F4/6543 ,  C08F2/38

    Abstract: A process for the polymerization of olefin monomers comprising contacting ethylene or a mixture of ethylene and one or more C4-8 α olefins with a catalyst composition comprising one or more Group 3-10 transition metal containing, Ziegler-Natta, procatalyst compounds; one or more alkylaluminum cocatalyts; and one or more polymerization control agents, said process being characterized in that at least one such polymerization control agent is an alkyl or aryl, ester of an aliphatic or aromatic (poly)carboxylic acid optionally containing one or more substituents comprising a Group 13, 14, 15, or 16 heteroatom.

    Abstract translation: 一种烯烃单体的聚合方法，包括使乙烯或乙烯与一种或多种C 4-8α-烯烃的混合物与包含一种或多种含有齐格勒的3-10族过渡金属的催化剂组合物接触 -Natta，前催化剂化合物; 一种或多种烷基铝共催化剂; 和一种或多种聚合控制剂，所述方法的特征在于至少一种这样的聚合控制剂是烷基或芳基，任选地含有一个或多个取代基的脂族或芳族（多）羧酸的酯，所述取代基包括第13,14 ，15或16个杂原子。

    Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process
    89.
    发明申请
    Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process 失效
    用单羧酸酯内给体和丙烯聚合方法自催化催化剂组成

    公开(公告)号：US20070032376A1

    公开(公告)日：2007-02-08

    申请号：US10568981

    申请日：2004-08-18

    Applicant: Linfeng Chen

    Inventor： Linfeng Chen

    IPC: B01J31/00

    CPC classification number: C08F110/06 ,  C08F10/00 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/18

    Abstract: A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more monoesters of aromatic carboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 98.0 to 99.9 mol percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 2.0 to 0.1 mol percent of one or more alkoxysilane compounds.

    Abstract translation: 一种用于丙烯聚合的催化剂组合物，其包含一种或多种齐格勒 - 纳塔前催化剂组合物，其包含一种或多种过渡金属化合物和一种或多种芳族羧酸内电子给体的单酯; 一种或多种含铝助催化剂; 和两种或更多种不同选择性控制剂的混合物，所述SCA混合物包含98.0至99.9mol％的一种或多种芳族单羧酸或其取代衍生物的一种或多种酯，以及2.0至0.1mol％的一种或多种 烷氧基硅烷化合物。

    Self limiting catalyst composition and propylene polymerization process
    90.
    发明申请
    Self limiting catalyst composition and propylene polymerization process 有权
    自限催化剂组合物和丙烯聚合方法

    公开(公告)号：US20070027275A1

    公开(公告)日：2007-02-01

    申请号：US10568930

    申请日：2004-09-17

    Applicant: Linfeng Chen ,  Richard Campbell

    Inventor： Linfeng Chen ,  Richard Campbell

    IPC: C08G85/00 ,  B01J31/00

    CPC classification number: C08F10/00 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/04 ,  B01J31/143 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6496 ,  C08F4/6495 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/18

    Abstract: A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent (SCA) comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent (ALA) compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl(poly)(oxyalkyl)-(poly)ester derivatives thereof; or inertly substituted derivatives of the foregoing.

    Abstract translation: 一种用于丙烯聚合的催化剂组合物，其包含一种或多种齐格勒 - 纳塔前催化剂组合物，其包含一种或多种过渡金属化合物和一种或多种芳族二羧酸内电子给体的酯; 一种或多种含铝助催化剂; 包含至少一种含有至少一个与硅原子键合的C 1-10烷氧基的含硅化合物的选择性控制剂（SCA），以及一种或多种包含一种或多种的活性限制剂（ALA）化合物 或更多的脂族或脂环族羧酸; 烷基 - ，环烷基 - 或烷基（聚）（烷氧基） - （聚）酯衍生物; 或惰性取代的衍生物。

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