公开(公告)号：US20140171527A1

公开(公告)日：2014-06-19

申请号：US14189134

申请日：2014-02-25

Applicant: Honeywell International Inc.

Inventor： Bin Yu ,  Mary C. Bogdan ,  Clifford B. Gittere ,  Michael Ross ,  Ronald S. Grossman ,  David J. Williams

IPC: C08G18/06

CPC classification number: C08J9/146 ,  C08G18/163 ,  C08G18/1808 ,  C08G18/1816 ,  C08G18/222 ,  C08G18/227 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/482 ,  C08G18/5021 ,  C08G18/7664 ,  C08G2101/00 ,  C08J9/02 ,  C08J9/144 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst.

Abstract translation: 本发明提供聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 更具体地说，本发明涉及闭孔，聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 泡沫的特征在于细小的均匀的细胞结构和很少或没有泡沫崩溃。 泡沫体是用多元醇预混物组合物生产的，该组合物包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和单独使用或与胺催化剂组合使用的抗沉降金属基催化剂的组合。

公开(公告)号：US20140155506A1

公开(公告)日：2014-06-05

申请号：US14234457

申请日：2012-07-23

Applicant: Yusuke Maruoka ,  Atsushi Miyata ,  Kazuhiko Okubo ,  Tsukuru Izukawa ,  Toru Hiraide ,  Shinsuke Matsumoto

Inventor： Yusuke Maruoka ,  Atsushi Miyata ,  Kazuhiko Okubo ,  Tsukuru Izukawa ,  Toru Hiraide ,  Shinsuke Matsumoto

IPC: C08G18/32 ,  C08G18/08

CPC classification number: C08G18/3203 ,  C08G18/14 ,  C08G18/3206 ,  C08G18/3271 ,  C08G18/4072 ,  C08G18/4841 ,  C08G18/632 ,  C08G18/667 ,  C08G18/6677 ,  C08G18/7621 ,  C08G18/7664 ,  C08G65/2675 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08J9/0023 ,  C08J9/0028 ,  C08J9/0033 ,  C08J9/0038 ,  C08J9/0061 ,  C08J9/02 ,  C08J9/122 ,  C08J9/38 ,  C08J2201/022 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2205/05 ,  C08J2205/06 ,  C08J2375/08 ,  C08J2425/12 ,  C08J2433/20 ,  C08L71/02

Abstract: The present invention relates to a preparation for a polyurethane foam and a polymer polyol preparation for a polyurethane foam, each of which exhibits high coloration and discoloration inhibition properties over a long period of time when stored, and to a composition for a polyurethane foam, which is excellent in storage stability and is preferable as a resin premix. The composition for a polyurethane foam of the present invention is characterized by comprising (i) at least one polyol selected from a polyoxyalkylene polyol and a polymer polyol wherein polymer fine particles obtained by polymerizing a compound having an unsaturated bond are dispersed in the polyoxyalkylene polyol, (ii) a compound having a P═N bond, (iii) an antioxidant having a hydroxyphenyl group, (iv) at least one acid selected from the group consisting of an acyclic aliphatic monocarboxylic acid of 2 to 25 carbon atoms, a hydroxycarboxylic acid of 2 to 25 carbon atoms, a polycarboxylic acid of 20 to 60 carbon atoms, a specific aromatic monocarboxylic acid, a sulfonic acid and an acid having a sulfuric acid ester group, or its salt, (v) a catalyst for polyurethane foam production and (vi) a blowing agent.

Abstract translation: 本发明涉及一种聚氨酯泡沫塑料的制备方法和聚氨酯泡沫塑料的聚合物多元醇制剂，它们各自在储存时长时间表现出高的着色和变色抑制性能，而且涉及聚氨酯泡沫塑料组合物， 储存稳定性优异，优选作为树脂预混物。 本发明的聚氨酯泡沫塑料组合物的特征在于：（i）至少一种选自聚氧化烯多元醇和聚合物多元醇的多元醇，其中通过聚合具有不饱和键的化合物获得的聚合物细颗粒分散在聚氧化烯多元醇中， （ii）具有P = N键的化合物，（iii）具有羟基苯基的抗氧化剂，（iv）至少一种选自2〜25个碳原子的无环脂族一元羧酸的酸，羟基羧酸 2〜25个碳原子的多元羧酸，20〜60个碳原子的多元羧酸，特定的芳香族单羧酸，磺酸，具有硫酸酯基的酸或其盐，（v）聚氨酯泡沫体的制造用催化剂， （vi）发泡剂。

公开(公告)号：US20140100299A1

公开(公告)日：2014-04-10

申请号：US13646785

申请日：2012-10-08

Applicant: FOMO PRODUCTS, INC.

Inventor： Anthony J. Taylor

IPC: C08J9/14

CPC classification number: C08J9/144 ,  B29C44/18 ,  C08G18/4018 ,  C08G18/482 ,  C08G2101/0025 ,  C08G2105/02 ,  C08J9/146 ,  C08J2201/022 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/18 ,  C08J2375/04 ,  E04B1/7604 ,  E04B2002/0293

Abstract: The invention described herein generally pertains to the use of low boiling point, low vapor pressure blowing agents with froth polyurethane or polyisocyanurate foams to achieve superior cavity filling than when using conventional higher vapor pressure or more ozone-depleting blowing agents.

Abstract translation: 本文描述的本发明通常涉及使用具有泡沫聚氨酯或聚异氰脲酸酯泡沫的低沸点低蒸气压发泡剂，以获得比使用常规较高蒸气压或更多的消耗臭氧的发泡剂时更好的空腔填充。

公开(公告)号：US20140051776A1

公开(公告)日：2014-02-20

申请号：US14004475

申请日：2012-03-06

Applicant: Benjamin Bin Chen ,  Joseph S. Costa ,  Laurent Abbas ,  Haiming Liu ,  Sri R. Seshadri ,  William D. Honnick

Inventor： Benjamin Bin Chen ,  Joseph S. Costa ,  Laurent Abbas ,  Haiming Liu ,  Sri R. Seshadri ,  William D. Honnick

IPC: C08J9/14 ,  C08J9/12

CPC classification number: C08J9/147 ,  C08G18/1808 ,  C08G18/4018 ,  C08G2101/0025 ,  C08J9/0052 ,  C08J9/02 ,  C08J9/127 ,  C08J9/144 ,  C08J9/149 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04 ,  C08L71/02

Abstract: A polyol pre-mix composition includes a blowing agent having a halogenated hydroolefin, a polyol, a surfactant, a catalyst composition, and a metal salt. The metal salt may be, for example, a carboxylate, acetylacetonate, alcoholate of a metal selected from the group consisting of Zn, Co, Ca, and Mg. The metal salt may be, for example, a carboxylate and/or alcoholate of a C1-C21 straight chain or branched aliphatic monocarboxylic acid or monoalcohol, such as magnesium formate, zinc octoate, calcium octoate, cobalt octoate, and magnesium octoate, and mixtures thereof. The metal acetylacetonate may be, for example, zinc acetylacetonate, cobalt acetylacetonate, magnesium acetylacetonate, or calcium acetylacetonate. A two-part system for producing a thermosetting foam blend includes (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) the polyol pre-mix composition. A method for producing a thermosetting foam blend includes combining: (a) a polyisocyanate; and (b) the polyol pre-mix composition.

Abstract translation: 多元醇预混合组合物包括具有卤化氢烯烃，多元醇，表面活性剂，催化剂组合物和金属盐的发泡剂。 金属盐可以是例如选自Zn，Co，Ca和Mg的金属的羧酸盐，乙酰丙酮化物，醇盐。 金属盐可以是例如C1-C21直链或支链脂族单羧酸或一元醇的羧酸盐和/或醇盐，例如甲酸镁，辛酸锌，辛酸钙，辛酸钙和辛酸镁，以及混合物 其中。 乙酰丙酮酸金属可以是例如乙酰丙酮酸锌，乙酰丙酮酸钴，乙酰丙酮镁或乙酰丙酮酸钙。 用于生产热固性泡沫共混物的两部分系统包括（a）多异氰酸酯和任选的一种或多种异氰酸酯相容的原料; 和（b）多元醇预混合组合物。 一种制备热固性泡沫共混物的方法包括：（a）多异氰酸酯; 和（b）多元醇预混合组合物。

公开(公告)号：US08518477B2

公开(公告)日：2013-08-27

申请号：US13307710

申请日：2011-11-30

Applicant: Dario Cavalli

Inventor： Dario Cavalli

IPC: B05D5/10

CPC classification number: C09J5/08 ,  C08J9/08 ,  C08J2201/022 ,  C08J2207/02 ,  C09J2403/00 ,  C09J2429/00 ,  C09J2431/00

Abstract: A process to apply a foamable water-based adhesive comprises combining, in a pressure-tight container having an outlet valve, a) a first aqueous polymer having a pH-value above 6 and containing a dissolved or dispersed salt that can liberate a gas, and b) a second aqueous polymer comprising an acid and having a pH-value lower than 5, and combined aqueous releasing the combined aqueous polymers from the pressure-tight container through the outlet valve onto a substrate, whereby gas bubbles are formed in the aqueous polymers leaving the valve, thus foaming the water-based adhesive.

Abstract translation: 施用可发泡水性粘合剂的方法包括在具有出口阀的耐压容器中组合a）pH值高于6并含有可释放气体的溶解或分散的盐的第一含水聚合物， 和b）包含酸并且pH值低于5的第二含水聚合物，并且将合并的含水聚合物从压力容器通过出口阀释放到基底上，由此在水溶液中形成气泡 离开阀门的聚合物，从而使水性粘合剂发泡。

公开(公告)号：US20120135140A1

公开(公告)日：2012-05-31

申请号：US13307710

申请日：2011-11-30

Applicant: Dario Cavalli

Inventor： Dario Cavalli

IPC: B05D5/10 ,  C08L31/04

CPC classification number: C09J5/08 ,  C08J9/08 ,  C08J2201/022 ,  C08J2207/02 ,  C09J2403/00 ,  C09J2429/00 ,  C09J2431/00

Abstract: A process to apply a foamable water-based adhesive comprises combining, in a pressure-tight container having an outlet valve, a) a first aqueous polymer having a pH-value above 6 and containing a dissolved or dispersed salt that can liberate a gas, and b) a second aqueous polymer comprising an acid and having a pH-value lower than 5, and combined aqueous releasing the combined aqueous polymers from the pressure-tight container through the outlet valve onto a substrate, whereby gas bubbles are formed in the aqueous polymers leaving the valve, thus foaming the water-based adhesive.

Abstract translation: 施用可发泡水性粘合剂的方法包括在具有出口阀的耐压容器中组合a）pH值高于6并含有可释放气体的溶解或分散的盐的第一含水聚合物， 和b）包含酸并且pH值低于5的第二含水聚合物，并且将合并的含水聚合物从压力容器通过出口阀释放到基底上，由此在水溶液中形成气泡 离开阀门的聚合物，从而使水性粘合剂发泡。

公开(公告)号：US20080161432A1

公开(公告)日：2008-07-03

申请号：US11893435

申请日：2007-08-16

Applicant: Michelle L. Korwin-Edson ,  Robert J. O'Leary ,  Robert E. Quinn ,  Fatemeh Olang

Inventor： Michelle L. Korwin-Edson ,  Robert J. O'Leary ,  Robert E. Quinn ,  Fatemeh Olang

IPC: C08J9/30

CPC classification number: C08J9/127 ,  C08J9/08 ,  C08J9/228 ,  C08J2201/022 ,  C08J2201/026 ,  C08J2203/12 ,  C08J2333/00 ,  C08J2351/08 ,  C08L51/003 ,  C08L51/04 ,  C08L53/02 ,  E04B1/6801 ,  E04B1/74 ,  E04B2001/742 ,  E04C5/07 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/02

Abstract: Foams for filling cavities and crevasses and for forming foamed products are provided. The latex foam may include an A-side containing a functionalized latex and a B-side that contains a crosslinking agent and optionally a non-functionalized latex. The A- and/or B-side contain a blowing agent package or components forming the blowing agent package. The blowing agent package may be the combination of two or more chemicals that when mixed together form a gas or a chemical compound that, when activated by heat or light, forms a gas. In an alternate embodiment, the latex foam includes a functionalized latex, an acid, and an encapsulated crosslinking agent and base. Alternatively, the spray latex foam may include a functionalized latex, a crosslinking agent, and an encapsulated dry acid and dry base. The encapsulating agent may be a protective, non-reactive shell that can be broken or melted at the time of application.

公开(公告)号：US20030166735A1

公开(公告)日：2003-09-04

申请号：US10336111

申请日：2003-03-04

Inventor： Jan L.R. Clatty

IPC: C08G018/00

CPC classification number: C08G18/6696 ,  C08G18/36 ,  C08G18/4816 ,  C08G2101/0025 ,  C08J9/00 ,  C08J2201/022 ,  C08J2205/052 ,  C08J2205/10 ,  C08J2375/04

Abstract: Rigid, closed-cell polyurethane foams are produced by a RIM process by reacting an organic polyisocyanate with an isocyanate-reactive mixture in which a significant amount of a bio-based polyol is present. The foams produced by this process are characterized by improved heat sag and heat distortion temperature.

Abstract translation: 通过RIM方法通过使有机多异氰酸酯与存在大量生物基多元醇的异氰酸酯反应性混合物反应来制备刚性的闭孔聚氨酯泡沫。 由该方法生产的泡沫的特征在于改善了热下垂和热变形温度。

公开(公告)号：US20240327592A1

公开(公告)日：2024-10-03

申请号：US18739159

申请日：2024-06-10

Applicant: Holcim Technology Ltd

Inventor： John B. LETTS ,  Chunhua YAO ,  Michael J. HUBBARD

IPC: C08J9/14 ,  B29C44/12 ,  B29K75/00 ,  B29K105/04 ,  B29L31/10 ,  B32B5/18 ,  B32B5/20 ,  B32B5/32 ,  B32B7/12 ,  B32B9/04 ,  B32B11/04 ,  B32B13/04 ,  B32B15/04 ,  B32B21/04 ,  B32B25/04 ,  B32B27/06 ,  B32B27/30 ,  B32B27/32 ,  C08G18/08 ,  E04B1/80 ,  E04C2/20 ,  E04C2/296 ,  E04D3/35 ,  E04D11/02

CPC classification number: C08J9/141 ,  B32B5/18 ,  B32B5/20 ,  B32B5/32 ,  B32B7/12 ,  B32B9/04 ,  B32B9/043 ,  B32B9/045 ,  B32B11/048 ,  B32B13/045 ,  B32B15/046 ,  B32B21/047 ,  B32B25/045 ,  B32B27/065 ,  B32B27/304 ,  B32B27/32 ,  C08G18/08 ,  C08J9/149 ,  E04B1/80 ,  E04C2/205 ,  E04C2/296 ,  E04D3/352 ,  E04D11/02 ,  B29C44/12 ,  B29K2075/00 ,  B29K2105/046 ,  B29K2995/0015 ,  B29L2031/10 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2266/0214 ,  B32B2266/0278 ,  B32B2307/304 ,  B32B2307/3065 ,  B32B2307/71 ,  B32B2307/72 ,  B32B2419/00 ,  B32B2419/06 ,  C08G2110/0025 ,  C08J2201/022 ,  C08J2203/14 ,  C08J2203/182 ,  C08J2205/052 ,  C08J2207/00 ,  C08J2375/04

Abstract: A process for producing a polyurethane or polyisocyanurate construction board, the process comprising of providing an A-side reactant stream that includes an isocyanate-containing compound; providing a B-side reactant stream that includes a polyol, where the B-side reactant steam includes a blowing agent mixture including isopentane and a blowing agent additive that has a Hansen Solubility Parameter (δt) that is greater than 15 MPa0.5; and mixing the A-side reactant stream with the B-side reactant stream to produce a reaction mixture.

公开(公告)号：US20240294721A1

公开(公告)日：2024-09-05

申请号：US18647320

申请日：2024-04-26

Applicant: DDP SPECIATLY ELECTRONIC MATERIALS US, LLC

Inventor： MEGAN MARIE THOMAS ,  KYOUNG MOO KOH ,  MARK ALAN RICKARD

IPC: C08J9/14 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/76 ,  C08G101/00 ,  C08J9/12 ,  C09D5/02 ,  C09D175/08

CPC classification number: C08J9/144 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/48 ,  C08G18/7671 ,  C08J9/122 ,  C08J9/127 ,  C08J9/146 ,  C09D5/021 ,  C09D175/08 ,  C08G2101/00 ,  C08J2201/02 ,  C08J2201/022 ,  C08J2203/06 ,  C08J2203/162 ,  C08J2203/164 ,  C08J2207/04 ,  C08J2375/04 ,  C08J2375/08

Abstract: Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50° C.