公开(公告)号：US20150119481A1

公开(公告)日：2015-04-30

申请号：US14403409

申请日：2013-05-13

Applicant: SAMSUNG FINE CHEMICALS CO., LTD

Inventor： Jong Pil Chun ,  Hee Soo Kim ,  Soo Youn Choi ,  Ye Jin Kim ,  Ki Chull Yun ,  Min Kyoung Kim

IPC: C08J9/14 ,  C08J9/00 ,  A43B13/04

CPC classification number: C08J9/142 ,  A43B13/04 ,  C08J9/0061 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2201/03 ,  C08J2203/02 ,  C08J2203/04 ,  C08J2323/08 ,  C08J2331/04 ,  C08J2400/16 ,  C08J2467/06 ,  C08L23/0853 ,  C08L31/04 ,  C08L67/00 ,  C08L67/06

Abstract: There are provided a resin composition for foaming including a biodegradable resin and a foamed article made thereof. The resin composition for foaming according to the present invention includes an ethylene-vinyl acetate resin, a biodegradable polyester resin containing a monomer of a double bond compound, a cross-linking agent, a co-crosslinking agent, a filler, and a foaming agent. In the resin composition, the double bond in the biodegradable polyester resin can be chemically cross-linked to the ethylene-vinyl acetate resin by a cross-linking agent, so that a compatibility with the ethylene-vinyl acetate resin can be improved, processability (mold releasability) during a mixing and melting process can be improved, and a foaming property and a mechanical property of a foamed article can be remarkably improved.

Abstract translation: 提供了一种用于发泡的树脂组合物，其包括可生物降解的树脂和由其制成的泡沫制品。 本发明的发泡用树脂组合物包括乙烯 - 乙酸乙烯酯树脂，含有双键化合物的单体的可生物降解的聚酯树脂，交联剂，共交联剂，填料和发泡剂 。 在树脂组合物中，生物降解性聚酯树脂中的双键可以通过交联剂与乙烯 - 乙酸乙烯酯树脂进行化学交联，从而可以提高与乙烯 - 乙酸乙烯酯树脂的相容性，加工性（ 可以提高混合熔融过程中的脱模性，并且可以显着提高泡沫制品的起泡性和机械性能。

公开(公告)号：US09006301B2

公开(公告)日：2015-04-14

申请号：US13447688

申请日：2012-04-16

Applicant: Stephen Leeming ,  Mark Dixon ,  Andrew Overend

Inventor： Stephen Leeming ,  Mark Dixon ,  Andrew Overend

IPC: C08J9/06 ,  C08F114/06 ,  C08J9/08 ,  C08J9/10

CPC classification number: C08J9/08 ,  C08J9/06 ,  C08J9/10 ,  C08J9/103 ,  C08J9/105 ,  C08J2201/03 ,  C08J2327/06

Abstract: A formulation for foaming a thermoplastic polymer, for example PVC, comprises a carrier, exothermic and endothermic chemical blowing agents and 1 wt %, preferably less than 0.2 wt % of water. The liquid formulation can readily be used for foaming PVC and other thermoplastics.

Abstract translation: 用于使热塑性聚合物（例如PVC）发泡的配方包括载体，放热和吸热化学发泡剂和1重量％，优选小于0.2重量％的水。 液体制剂可以容易地用于发泡PVC和其他热塑性塑料。

公开(公告)号：US20150072131A1

公开(公告)日：2015-03-12

申请号：US14543375

申请日：2014-11-17

Applicant: Mary Ruth LEHRTER ,  Adam PACELLI

Inventor： Mary Ruth LEHRTER ,  Adam PACELLI

IPC: C08J5/18

CPC classification number: B29C47/0057 ,  B29C47/0021 ,  B29C47/0026 ,  B29C47/20 ,  B29C47/883 ,  B29C47/8835 ,  B29C55/143 ,  B29C67/20 ,  B29C2947/92647 ,  B29C2947/92704 ,  B29K2023/065 ,  B29K2509/00 ,  B29K2995/005 ,  B29K2995/0053 ,  B29L2023/001 ,  C08J5/18 ,  C08J9/228 ,  C08J2201/03 ,  C08J2205/044 ,  C08J2323/06

Abstract: A micro-voided film comprising high density polyethylene having a molecular weight of at least about 200,000, and low aspect ratio filler having a mean particle size from about 1 to about 25 microns. The film has a thickness of from about 10 to about 75 microns and a void fraction of from about 0.60 to about 0.75. The micro-voided film is made by a process comprising extruding the composition into a film having a thickness of from about 50 to about 300 microns, and orienting the extruded film using a high stalk, blown film process. The process produces a stabilized high stalk for increasing the production rate of blown, high molecular weight polyethylene, while increasing the film's physical and mechanical properties. The high stalk can be stabilized by application of high velocity, low volume flow rate of air over the interior and exterior surfaces of the extruded film.

Abstract translation: 包含分子量至少为约200,000的高密度聚乙烯和平均粒径为约1至约25微米的低纵横比填料的微孔隙膜。 该膜具有约10至约75微米的厚度和约0.60至约0.75的空隙率。 微孔膜通过包括将组合物挤出成厚度为约50至约300微米的膜并使用高柄吹塑膜方法取向挤出膜的方法制备。 该方法产生稳定的高茎，以提高吹塑高分子量聚乙烯的生产速率，同时增加膜的物理和机械性能。 通过在挤压薄膜的内表面和外表面上施加高速，低体积流速的空气可以稳定高秆。

公开(公告)号：US08962706B2

公开(公告)日：2015-02-24

申请号：US13230158

申请日：2011-09-12

Applicant: Adam R. Pawloski ,  Jeffrey J. Cernohous ,  Kent Kaske ,  Garrett Van Gorden

Inventor： Adam R. Pawloski ,  Jeffrey J. Cernohous ,  Kent Kaske ,  Garrett Van Gorden

IPC: C08J9/00 ,  C08J9/232 ,  B29C44/34 ,  B29B9/06 ,  B29C47/00 ,  B29K25/00 ,  B29K67/00 ,  B29C47/92

CPC classification number: C08J9/232 ,  B29B9/06 ,  B29C44/3461 ,  B29C47/0011 ,  B29C47/0042 ,  B29C47/0066 ,  B29C47/92 ,  B29K2025/06 ,  B29K2067/046 ,  B29K2995/0056 ,  B29K2995/006 ,  C08J2201/03 ,  C08J2203/184 ,  C08J2205/052 ,  C08J2367/04

Abstract: The present invention enables the secondary expansion of lightweight foamed beads. The foamed beads are produced using a compound comprising a compostable or biobased polyester and a physical blowing agent as well as a chemical blowing agent. Secondary expansion can be used either to lower the density of the foamed bead further or to enable expansion of the beads during molding to promote fusion. The foam beads can be produced using conventional melt processing techniques, such as single and twin-screw extrusion processes.

Abstract translation: 本发明使得轻质泡沫珠的二次膨胀。 使用包含可堆肥或生物基聚酯和物理发泡剂以及化学发泡剂的化合物制备发泡珠粒。 可以使用二次膨胀来进一步降低发泡颗粒的密度，或者可以在模塑过程中使珠粒膨胀以促进融合。 泡沫珠可以使用常规的熔融加工技术制造，例如单螺杆和双螺杆挤出方法。

公开(公告)号：US20150045524A1

公开(公告)日：2015-02-12

申请号：US14522743

申请日：2014-10-24

Applicant: W. L. Gore & Associates, Inc.

Inventor： Ping Xu ,  Jack J. Hegenbarth ,  Xin Kang Chen

IPC: C08F14/26

CPC classification number: C08F14/26 ,  B29C55/005 ,  B29K2027/18 ,  B29K2105/04 ,  C08F214/26 ,  C08F214/262 ,  C08J9/141 ,  C08J9/228 ,  C08J9/40 ,  C08J9/405 ,  C08J2201/03 ,  C08J2327/18 ,  C08F2/22

Abstract: A functional TFE copolymer fine powder is described, wherein the TFE copolymer is a polymer of TFE and at least one functional comonomer, and wherein the TFE copolymer has functional groups that are pendant to the polymer chain. The functional TFE copolymer fine powder resin is paste extrudable and expandable. Methods for making the functional TFE copolymer are also described. The expanded functional TFE copolymer material may be post-reacted after expansion.

Abstract translation: 描述了一种功能性TFE共聚物细粉末，其中TFE共聚物是TFE和至少一种官能共聚单体的聚合物，并且其中TFE共聚物具有垂直于聚合物链的官能团。 功能性TFE共聚物细粉末树脂是可挤出和可膨胀的糊状物。 还描述了制备功能性TFE共聚物的方法。 膨胀的功能性TFE共聚物材料可以在膨胀后进行后反应。

公开(公告)号：US20150011665A1

公开(公告)日：2015-01-08

申请号：US14495340

申请日：2014-09-24

Applicant: FINA TECHNOLOGY, INC.

Inventor： Jose M. Sosa ,  David W. Knoeppel

IPC: C08J9/28 ,  C08J9/12 ,  C08J9/00

CPC classification number: C08J9/28 ,  B29C44/08 ,  C08J9/0066 ,  C08J9/122 ,  C08J9/125 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/10 ,  C08J2203/182 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2205/048 ,  C08J2325/04 ,  C08J2325/06

Abstract: Cellular and multi-cellular polystyrene and polystyrenic foams and methods of forming such foams are disclosed. The foams include an expanded polystyrene formed from expansion of an expandable polystyrene including an adsorbent comprising alumina, wherein the multi-cellular polystyrene exhibits a multi-cellular size distribution. The process for forming a foamed article includes providing a formed styrenic polymer and contacting the formed styrenic polymer with a first blowing agent and an adsorbent comprising alumina to form extrusion polystyrene. The process further includes forming the extrusion styrenic polymer into an expanded styrenic polymer and forming the expanded styrenic polymer into a foamed article.

Abstract translation: 公开了细胞和多细胞聚苯乙烯和聚苯乙烯泡沫以及形成这种泡沫的方法。 泡沫包括由可膨胀聚苯乙烯膨胀形成的发泡聚苯乙烯，其包括包含氧化铝的吸附剂，其中多孔聚苯乙烯表现出多孔尺寸分布。 形成发泡制品的方法包括提供形成的苯乙烯类聚合物并使所形成的苯乙烯类聚合物与第一发泡剂和包含氧化铝的吸附剂接触以形成挤出聚苯乙烯。 该方法还包括将挤出苯乙烯聚合物形成膨胀的苯乙烯聚合物，并将膨胀的苯乙烯聚合物形成发泡制品。

公开(公告)号：US20150011664A1

公开(公告)日：2015-01-08

申请号：US14462835

申请日：2014-08-19

Applicant: Joseph Wycech

Inventor： Joseph Wycech

IPC: C08J5/12 ,  B29B9/06 ,  B29C47/00 ,  C08J9/14

CPC classification number: B29C48/022 ,  B29B9/06 ,  B29B9/12 ,  B29B2009/125 ,  B29B2009/163 ,  B29C48/0011 ,  B29K2033/04 ,  B29K2055/00 ,  B29K2995/006 ,  C08J9/0061 ,  C08J9/16 ,  C08J9/236 ,  C08J9/32 ,  C08J2201/03 ,  C08J2203/22 ,  C08J2300/16 ,  C08J2303/02 ,  C08J2303/04 ,  C08J2303/12 ,  C08J2347/00 ,  C08J2357/06 ,  C08J2409/00 ,  C08L3/02

Abstract: An example starch-based material for forming a biodegradable component includes a mixture of a starch and an expansion additive. The starch has an amylose content of less than about 70% by weight. The expansion additive enhances the expansion and physical properties of the starch. A method of preparing a starch-based material is also disclosed and an alternate starch-based material for forming a biodegradable component is also disclosed.

Abstract translation: 用于形成可生物降解的组分的淀粉基材料的实例包括淀粉和膨胀添加剂的混合物。 淀粉的直链淀粉含量小于约70重量％。 膨胀添加剂增强了淀粉的膨胀和物理性能。 还公开了一种制备淀粉基材料的方法，还公开了用于形成可生物降解成分的替代的淀粉基材料。

公开(公告)号：US20150004394A1

公开(公告)日：2015-01-01

申请号：US14373040

申请日：2013-02-22

Applicant: JAPAN POLYPROPYLENE CORPORATION

Inventor： Sachio Hotta ,  Kazuo Asuka ,  Shinichi Kitade ,  Kuninori Takahashi ,  Iku Kouzai ,  Takao Tayano

IPC: C08J5/18 ,  B32B27/20 ,  B32B5/18 ,  B32B27/32 ,  B29C45/00 ,  C08L53/00 ,  B29C47/06 ,  B29C47/00 ,  B29C49/00 ,  B29C51/00 ,  B32B27/06 ,  C08L23/12

CPC classification number: C08J5/18 ,  B29C45/0001 ,  B29C47/0042 ,  B29C47/0054 ,  B29C47/04 ,  B29C47/065 ,  B29C49/0005 ,  B29C51/002 ,  B29K2023/12 ,  B29K2023/14 ,  B29K2105/0085 ,  B29K2105/04 ,  B32B5/18 ,  B32B27/065 ,  B32B27/20 ,  B32B27/32 ,  B32B2250/02 ,  B32B2305/022 ,  B32B2307/304 ,  B32B2307/306 ,  B32B2307/558 ,  B32B2439/00 ,  B32B2605/00 ,  C08F297/08 ,  C08J9/0061 ,  C08J2201/03 ,  C08J2323/12 ,  C08J2323/14 ,  C08J2353/00 ,  C08J2423/12 ,  C08J2453/00 ,  C08L23/12 ,  C08L23/16 ,  C08L53/00 ,  C08L2203/14 ,  C08L2203/30 ,  C08L2205/03 ,  Y10T428/249992

Abstract: Provided is a polypropylene-based resin composition which gives uniform and fine cells and from which a foamed sheet and thermoform excellent in appearance, thermoformability, impact resistance, lightness, stiffness, heat resistance, heat insulating properties, oil resistance and the like can be produced. A polypropylene-based resin composition comprising (X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which block copolymer comprises (Y-1) a propylene (co)polymer and (Y-2) a propylene-ethylene copolymer, said resin (X) having properties (X-i) to (X-iv) and said block copolymer (Y) having properties (Y-i) to (Y-v), and the like.

公开(公告)号：US20140371335A1

公开(公告)日：2014-12-18

申请号：US14473212

申请日：2014-08-29

Applicant: POLIMERI EUROPA S.p.A.

Inventor： Riccardo FELISARI ,  Dario GHIDONI ,  Antonio PONTICIELLO ,  Alessandro CASALINI

IPC: C08J9/16 ,  C08J9/00

CPC classification number: C08J9/16 ,  C08J9/0066 ,  C08J9/008 ,  C08J2201/03 ,  C08J2203/14 ,  C08J2325/04 ,  C08J2325/06 ,  C08K3/04 ,  C08K3/22 ,  C08K3/30 ,  C08K3/346 ,  C08L25/04

Abstract: Expandable granulates, having compositions based on vinyl-aromatic polymers, including: a) 65-99.8% by weight of a copolymer obtained by polymerizing 85-100% by weight of one or more vinyl-aromatic monomers and 0-15% by weight of an α-alkylstyrene in which the alkyl group contains from 1 to 4 carbon atoms; b) 0.01-20% by weight, calculated with respect to the polymer (a), of a carbon black having an average diameter ranging from 10 to 1000 nm and a surface area ranging from 5 to 200 m2/g; c) 0.01-5% by weight, calculated with respect to the polymer (a), of c1) oxides and sulfates and lamellar dichalcogenides of metals; or c2) oxides and sulfates of metals, or c3) lamellar dichalcogenides of metals; or c4) oxides of metals; or c5) sulfates and lamellar dichalcogenides of metals; or c6) sulfates of metals; d) at least one of the following additives d1) and d2): d1) 0.01-5% by weight, calculated with respect to the polymer (a), of graphite having an average diameter ranging from 0.5 to 50 μm; d2) 0.01-5% by weight, calculated with respect to the polymer (a), of inorganic derivatives of silicon of the lamellar type; e) 0-5% by weight, calculated with respect to the polymer (a), of a nucleating agent; and f) 1-6% by weight, calculated with respect to 100 parts of the total of (a)-(e), of one or more expanding agents.

Abstract translation: 具有基于乙烯基芳族聚合物的组合物的可膨胀颗粒包括：a）65-99.8重量％的通过将85-100重量％的一种或多种乙烯基芳族单体和0-15重量％ 其中烷基含有1至4个碳原子的α-烷基苯乙烯; b）相对于聚合物（a）计算的平均直径为10〜1000nm，表面积为5〜200m 2 / g的炭黑为0.01-20重量％ c）0.01-5重量％，相对于聚合物（a）计算，c1）金属的氧化物和硫酸盐和层状二硫属元素; 或c2）金属的氧化物和硫酸盐，或c3）金属的层状二硫属化物; 或c4）金属氧化物; 或c5）金属的硫酸盐和层状二硫属元素; 或c6）金属硫酸盐; d）以下添加剂d1）和d2）中的至少一种：d1）0.01-5重量％，相对于聚合物（a）计算，平均直径为0.5〜50μm的石墨; d2）0.01-5重量％，相对于聚合物（a）计算的层状硅的无机衍生物; e）成核剂相对于聚合物（a）计为0-5重量％ 和f）1-6重量％，相对于100重量份（a） - （e）的一种或多种发泡剂计算。

公开(公告)号：US20140364522A1

公开(公告)日：2014-12-11

申请号：US14366803

申请日：2012-12-13

Applicant: Styron Europe GmbH

Inventor： Gilbert Bouquet ,  Ulrich Reifert ,  Nicolaas M.A. Hermans

IPC: C08F112/08 ,  C08J9/228 ,  C08J9/16

CPC classification number: C08F112/08 ,  C08F2/001 ,  C08F2/38 ,  C08F12/08 ,  C08J9/16 ,  C08J9/18 ,  C08J9/228 ,  C08J2201/03 ,  C08J2325/06

Abstract: Provided is a process for preparing polystyrene having a weight average molecular weight (Mw) in the range of 120,000- 160,000 gmol, a polydispersity in the range of 4-6 and a melt flow rate of at least 40 g/10 minutes by feeding styrene into a reaction system through which the styrene passes as a component of a reaction mixture as it is polymerized, the reaction system including an initial reaction zone (100) and a downstream reaction zone (200), comprising the steps of: polymerizing styrene in the initial reaction zone to form polystyrene having a Mw of greater than 300,000 gmol and a polydispersity in the range 1,5-2.5, 10-30 wt. % of the styrene fed to the initial reaction zone being polymerized there,—and polymerizing styrene remaining in the reaction mixture in the downstream reaction zone, a chain transfer agent being mixed with the reaction mixture at the commencement of this reaction zone and optionally at one or more additional locations within this reaction zone. The polystyrene may be used to manufacture expandable polystyrene beads or polystyrene foam board.

Abstract translation: 本发明提供一种制备聚苯乙烯的方法，其重均分子量（Mw）为120,000-160000gmol，多分散性为4-6，熔体流动速率为至少40g / 10分钟，通过加入苯乙烯 进入反应体系，苯乙烯在聚合时作为反应混合物的组分通过，反应体系包括初始反应区（100）和下游反应区（200），包括以下步骤：在苯乙烯中聚合苯乙烯 初始反应区以形成Mw大于300,000gmol的聚苯乙烯，多分散性在1.5-2.5,10-30wt。 进料到初始反应区的苯乙烯的％％在那里聚合，并且在下游反应区中聚合保留在反应混合物中的苯乙烯，链转移剂在该反应区开始时与反应混合物混合，任选地在一个 或在该反应区内更多的附加位置。 聚苯乙烯可用于制造可发泡聚苯乙烯珠或聚苯乙烯泡沫板。