Method for treating highly concentrated resin-desorption liquid generated from wastewater deep purification
    1.
    发明授权
    Method for treating highly concentrated resin-desorption liquid generated from wastewater deep purification 有权
    用于处理由废水深度净化产生的高浓度树脂脱附液的方法

    公开(公告)号:US09540268B2

    公开(公告)日:2017-01-10

    申请号:US13988512

    申请日:2011-08-12

    Abstract: A method for treating highly concentrated resin-desorption liquid generated from wastewater deep purification, including channeling the highly concentrated desorption liquid generated from anion exchange resin treatment through a nanofiltration membrane, the liquid being separated into nanofiltration permeate that can be reused as the desorption agent and highly concentrated nanofiltration retentate; adding a coagulating agent to the highly concentrated nanofiltration retentate to generate coagulation-precipitation; subjecting the supernatant formed after the coagulation-precipitation process to Fenton oxidation or ozone oxidation; after the reaction, adding to the liquid an alkali solution for further coagulation-precipitation; then channeling the liquid so treated back to the biochemical system of biochemical effluent treatment for further biodegradation is provided. The recycled treatment of the highly concentrated desorption liquid consequently reduces the treatment cost and prevents secondary pollution by realizing innocuous treatment and reclamation of resin-desorption liquid as well as reduction of its total volume.

    Abstract translation: 一种用于处理由废水深度净化产生的高浓度树脂解吸液的方法,包括将通过阴离子交换树脂处理产生的高浓度解吸液引导通过纳滤膜,将该液体分离成能够再次用作解吸剂的纳滤渗透物, 高度浓缩的纳滤滤液; 向高度浓缩的纳滤滤液中加入凝结剂,产生凝结沉淀; 在凝结沉淀过程后形成的上清液进行芬顿氧化或臭氧氧化; 反应后,向液体中加入碱溶液进行进一步凝结沉淀; 然后提供如此处理的液体回到生物化学废水处理生化系统进一步生物降解。 高浓度解吸液的再循环处理因此降低了处理成本,并且通过实现树脂解吸液的无害化处理和回收以及其总体积的降低来防止二次污染。

    Magnetic, acrylic strongly basic anion exchange microsphere resin and the manufacturing method thereof
    2.
    发明授权
    Magnetic, acrylic strongly basic anion exchange microsphere resin and the manufacturing method thereof 有权
    磁性,丙烯酸强碱性阴离子交换微球树脂及其制造方法

    公开(公告)号:US09183972B2

    公开(公告)日:2015-11-10

    申请号:US13146433

    申请日:2010-07-05

    Abstract: This invention relates to the field of resin, particularly to a magnetic, acrylic strongly basic anion exchange microsphere resin and its manufacturing method. Its basic structure is as follow: wherein its matrix contains magnetic grains and A is a group containing quaternary ammonium salts; the manufacturing method is: taking acrylic compounds as the monomer and mixing it with the crosslinking agent and porogenic agent to form an oil phase; evenly mixing the oil phase with magnetic grains and then conducting suspension polymerization; aminating and alkylating the polymerized magnetic grains so as to form the quaternary ammonium salts, namely the magnetic, acrylic strongly basic anion exchange microsphere resin. The exchange capacity of this resin is higher than that of any magnetic strongly basic anion exchange microsphere resin available either on both Chinese and overseas markets or in literature; it is able to take the place of the traditional strongly basic anion exchange resin in separating and removing soluble organics, particularly precursors of disinfection by-products, and various anions such as nitrates and phosphates.

    Abstract translation: 本发明涉及树脂领域,特别涉及磁性丙烯酸强碱性阴离子交换微球树脂及其制造方法。 其基本结构如下:其中基质含有磁性颗粒,A为含有季铵盐的基团; 制造方法是:以丙烯酸类化合物为单体,并与交联剂和致孔剂混合形成油相; 将油相与磁性颗粒均匀混合,然后进行悬浮聚合; 对聚合的磁性颗粒进行胺化和烷基化以形成季铵盐,即磁性,丙烯酸强碱性阴离子交换微球体树脂。 该树脂的交换能力高于中国和海外市场或文献中可获得的任何磁性强碱性阴离子交换微球树脂; 可以代替传统的强碱性阴离子交换树脂来分离和除去可溶性有机物,特别是消毒副产物的前体,以及各种阴离子如硝酸盐和磷酸盐。

    MAGNETIC, ACRYLIC STRONGLY BASIC ANION EXCHANGE MICROSPHERE RESIN AND THE MANUFACTURING METHOD THEREOF
    3.
    发明申请
    MAGNETIC, ACRYLIC STRONGLY BASIC ANION EXCHANGE MICROSPHERE RESIN AND THE MANUFACTURING METHOD THEREOF 有权
    磁性,亚克力强碱性阴离子交换微晶树脂及其制造方法

    公开(公告)号:US20130341554A1

    公开(公告)日:2013-12-26

    申请号:US13146433

    申请日:2010-07-06

    Abstract: This invention relates to the field of resin, particularly to a magnetic, acrylic strongly basic anion exchange microsphere resin and its manufacturing method. Its basic structure is as follow: wherein its matrix contains magnetic grains and A is a group containing quaternary ammonium salts; the manufacturing method is: taking acrylic compounds as the monomer and mixing it with the cros slinking agent and porogenic agent to form an oil phase; evenly mixing the oil phase with magnetic grains and then conducting suspension polymerization; aminating and alkylating the polymerized magnetic grains so as to form the quaternary ammonium salts, namely the magnetic, acrylic strongly basic anion exchange microsphere resin. The exchange capacity of this resin is higher than that of any magnetic strongly basic anion exchange microsphere resin available either on both Chinese and overseas markets or in literature; it is able to take the place of the traditional strongly basic anion exchange resin in separating and removing soluble organics, particularly precursors of disinfection by-products, and various anions such as nitrates and phosphates.

    Abstract translation: 本发明涉及树脂领域,特别涉及磁性丙烯酸强碱性阴离子交换微球树脂及其制造方法。 其基本结构如下:其中基质含有磁性颗粒,A为含有季铵盐的基团; 制造方法是:以丙烯酸类化合物为单体,并与交联剂和致孔剂混合形成油相; 将油相与磁性颗粒均匀混合,然后进行悬浮聚合; 对聚合的磁性颗粒进行胺化和烷基化以形成季铵盐,即磁性,丙烯酸强碱性阴离子交换微球体树脂。 该树脂的交换能力高于中国和海外市场或文献中可获得的任何磁性强碱性阴离子交换微球树脂; 可以代替传统的强碱性阴离子交换树脂来分离和除去可溶性有机物,特别是消毒副产物的前体,以及各种阴离子如硝酸盐和磷酸盐。

    Mechanically agitated, inner circulation reactor for resin ion exchange and adsorption
    5.
    发明授权
    Mechanically agitated, inner circulation reactor for resin ion exchange and adsorption 有权
    机械搅拌,内循环反应器进行树脂离子交换和吸附

    公开(公告)号:US08864987B2

    公开(公告)日:2014-10-21

    申请号:US14117194

    申请日:2011-11-10

    Abstract: Disclosed is an internal circulation resin ion exchange adsorption reactor with a mechanical stirrer. The upper part ⅔˜⅘ of the reactor main body is an open cylinder and the lower part ⅕˜⅓ is a cone-shaped body with a slope of 30°±10°. A bell-jar shaped reaction slot with a turbine water stirrer inside is located in the center of the reactor main body. The reactor main body is equipped with a cylindrical guide plate. A water collection weir, an inclined tube separator and an annular resin collection hopper are located between the shell of the reactor main body and the guide plate. The reactor is equipped with a water inlet pipe and a water outlet pipe. A resin removal pipe is connected with the annular resin collection hopper and a resin desorption slot respectively, and a regenerated resin reflux pipe is connected to the bell-jar shaped reaction slot.

    Abstract translation: 公开了具有机械搅拌器的内循环树脂离子交换吸附反应器。 反应器主体的上部为开放式气缸,下部为⅕〜1/3,为锥形体,斜度为30°±10°。 在反应器主体的中心位于具有涡轮机水搅拌器的钟形反应槽。 反应器主体装有圆柱形导板。 集水堰,倾斜管分离器和环形树脂收集料斗位于反应堆主体的外壳和导向板之间。 反应器配有进水管和出水管。 树脂去除管分别与环形树脂收集料斗和树脂解吸槽连接,并且再生树脂回流管连接到钟形反应槽。

    MECHANICALLY AGITATED, INNER CIRCULATION REACTOR FOR RESIN ION EXCHANGE AND ADSORPTION
    6.
    发明申请
    MECHANICALLY AGITATED, INNER CIRCULATION REACTOR FOR RESIN ION EXCHANGE AND ADSORPTION 有权
    用于树脂离子交换和吸附的内部循环反应器机械搅拌

    公开(公告)号:US20140209527A1

    公开(公告)日:2014-07-31

    申请号:US14117194

    申请日:2011-11-10

    Abstract: Disclosed is an internal circulation resin ion exchange adsorption reactor with a mechanical stirrer. The upper part ⅔˜⅘ of the reactor main body is an open cylinder and the lower part 1/5˜⅓ is a cone-shaped body with a slope of 30°±10°. A bell-jar shaped reaction slot with a turbine water stirrer inside is located in the center of the reactor main body. The reactor main body is equipped with a cylindrical guide plate. A water collection weir, an inclined tube separator and an annular resin collection hopper are located between the shell of the reactor main body and the guide plate. The reactor is equipped with a water inlet pipe and a water outlet pipe. A resin removal pipe is connected with the annular resin collection hopper and a resin desorption slot respectively, and a regenerated resin reflux pipe is connected to the bell-jar shaped reaction slot.

    Abstract translation: 公开了具有机械搅拌器的内循环树脂离子交换吸附反应器。 反应堆主体的上部为开放式气缸,下部为1/5〜1/3,为倾斜度为30°±10°的锥形体。 在反应器主体的中心位于具有涡轮机水搅拌器的钟形反应槽。 反应器主体装有圆柱形导板。 集水堰,倾斜管分离器和环形树脂收集料斗位于反应堆主体的外壳和导向板之间。 反应器配有进水管和出水管。 树脂去除管分别与环形树脂收集料斗和树脂解吸槽连接,再生树脂回流管连接到钟形反应槽。

    Method for preparation of active carbon by pyrolysis of organics

    公开(公告)号:US09650254B2

    公开(公告)日:2017-05-16

    申请号:US14115625

    申请日:2011-04-01

    Abstract: A method of production of active carbon by pyrolysis of organic materials, includes pyrolysis unit, reforming unit, drying unit, purification unit, gas storage unit and high temperature regenerative combustion unit. Organic materials are subjected to pyrolysis reaction in pyrolysis unit to produce combustible gas, tar and char. Combustible gas is reformed through reforming unit then enters into the drying unit for drying organic materials. One part of the purified combustible gas is combusted in the direction of combustion channel in the high temperature regenerative combustion unit, and the combustion heat is produced. At the same time, another part of combustible gas exchanges heat in the direction of heat exchanger channel in the regenerative combustion unit. Then it is used as pyrolysis activation medium entering into the pyrolysis unit in process of pyrolysis and activation reaction. The char is activated by the combustible gas in the pyrolysis unit then forms activated carbon. The sensible heat of the combustible pyrolysis gas is fully released through drying unit. A part of the combustible gas is combusted to produce heat as the required energy source of pyrolysis process. The combustible gas is used as pyrolysis medium and activator in the generation process of active carbon.

    CONTINUOUSLY FLOWING, INNER CIRCULATORY, QUASI-FLUIDIZED-BED REACTOR FOR RESIN ION EXCHANGE AND ADSORPTION
    9.
    发明申请
    CONTINUOUSLY FLOWING, INNER CIRCULATORY, QUASI-FLUIDIZED-BED REACTOR FOR RESIN ION EXCHANGE AND ADSORPTION 有权
    连续流动,内循环,树脂离子交换和吸附剂的流态化反应器

    公开(公告)号:US20140131261A1

    公开(公告)日:2014-05-15

    申请号:US14117486

    申请日:2011-11-10

    Abstract: A continuously flowing, inner circulatory, quasi-fluidized-bed reactor for resin ion exchange and adsorption. The reactor comprises a main body casing, an inclined pipe separator, an outlet weir, an inlet pipe, an outlet pipe, a reducing fluidization tank, a guide plate, a resin regeneration tank, a resin discharge pipe, and a return pipe for regenerated resin and a distributing ejector. The reactor is particularly suitable for advanced treatment of supply water, wastewater, biochemical effluent and reclaimed water by using (magnetic) powder resin.

    Abstract translation: 一种连续流动的内循环,准流化床反应器,用于树脂离子交换和吸附。 反应器包括主体壳体,倾斜管道分离器,出口堰,入口管,出口管,还原流化槽,引导板,树脂再生槽,树脂排出管和用于再生的回流管 树脂和分配喷射器。 该反应器特别适用于使用(磁性)粉末树脂对供水,废水,生化废水和再生水进行高级处理。

    METHOD FOR TREATING HIGHLY CONCENTRATED RESIN-DESORPTION LIQUID GENERATED FROM WASTEWATER DEEP PURIFICATION
    10.
    发明申请
    METHOD FOR TREATING HIGHLY CONCENTRATED RESIN-DESORPTION LIQUID GENERATED FROM WASTEWATER DEEP PURIFICATION 有权
    用于处理由废水深度净化产生的高浓度树脂分解液的方法

    公开(公告)号:US20130240450A1

    公开(公告)日:2013-09-19

    申请号:US13988512

    申请日:2011-08-12

    Abstract: A method for treating highly concentrated resin-desorption liquid generated from wastewater deep purification, including channeling the highly concentrated desorption liquid generated from anion exchange resin treatment through a nanofiltration membrane, the liquid being separated into nanofiltration permeate that can be reused as the desorption agent and highly concentrated nanofiltration retentate; adding a coagulating agent to the highly concentrated nanofiltration retentate to generate coagulation-precipitation; subjecting the supernatant formed after the coagulation-precipitation process to Fenton oxidation or ozone oxidation; after the reaction, adding to the liquid an alkali solution for further coagulation-precipitation; then channeling the liquid so treated back to the biochemical system of biochemical effluent treatment for further biodegradation is provided. The recycled treatment of the highly concentrated desorption liquid consequently reduces the treatment cost and prevents secondary pollution by realizing innocuous treatment and reclamation of resin-desorption liquid as well as reduction of its total volume.

    Abstract translation: 一种用于处理由废水深度净化产生的高浓度树脂解吸液的方法,包括将通过阴离子交换树脂处理产生的高浓度解吸液引导通过纳滤膜,将该液体分离成能够再次用作解吸剂的纳滤渗透物, 高度浓缩的纳滤滤液; 向高度浓缩的纳滤滤液中加入凝结剂,产生凝结沉淀; 在凝结沉淀过程后形成的上清液进行芬顿氧化或臭氧氧化; 反应后,向液体中加入碱溶液进行进一步凝结沉淀; 然后提供如此处理的液体回到生物化学废水处理生化系统进一步生物降解。 高浓度解吸液的再循环处理因此降低了处理成本,并且通过实现树脂解吸液的无害化处理和回收以及其总体积的降低来防止二次污染。

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