公开(公告)号：US20080149501A1

公开(公告)日：2008-06-26

申请号：US11962422

申请日：2007-12-21

Applicant: Martin Heule ,  Erno Pretsch ,  Tamas Vigassy

Inventor： Martin Heule ,  Erno Pretsch ,  Tamas Vigassy

IPC: G01N27/26 ,  B05D5/12 ,  A61L2/00

CPC classification number: G01N27/3335 ,  G01N27/307 ,  G01N27/4035

Abstract: A set (1) comprising at least two ion-selective solid-contact electrodes comprises at least two ion-selective measuring points (6). Each measuring point (6) comprises a metal conductor (3) and/or an inner layer (7) of a conductive polymer and an outer, ion-selective membrane (8). At least two measuring points (6) are selective in each case with respect to a different ion of an analysis solution. One of the solid-contact electrodes can be used as a reference electrode.

Abstract translation: 包括至少两个离子选择性固体接触电极的组（1）包括至少两个离子选择性测量点（6）。 每个测量点（6）包括导电聚合物和外部离子选择性膜（8）的金属导体（3）和/或内层（7）。 在每种情况下，至少两个测量点（6）相对于分析溶液的不同离子是选择性的。 固体接触电极之一可以用作参考电极。

公开(公告)号：US3957607A

公开(公告)日：1976-05-18

申请号：US352634

申请日：1973-04-19

Applicant: Wilhelm Simon ,  Erno Pretsch

Inventor： Wilhelm Simon ,  Erno Pretsch

IPC: B01J31/22 ,  C02F3/12 ,  C02F3/30 ,  C07C233/02 ,  C07D207/26 ,  C07D207/27 ,  C07D273/00 ,  C12N11/00 ,  G01N27/26 ,  G01N27/30 ,  B01D13/02

CPC classification number: B01J31/1805 ,  B01D69/141 ,  B01J31/2204 ,  C02F3/1215 ,  C02F3/1257 ,  C02F3/30 ,  C07D207/27 ,  C07D273/00 ,  B01D61/44 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/23 ,  B01J2531/25 ,  Y02W10/15

Abstract: New lipide soluble complexes of cations like metal ions and ammonium ions are prepared by reacting an uncharged complex forming substance with the corresponding ions. Preferred uncharged complex forming substances are also new. The new lipide soluble complexes of cations have a wide field of application and those complexes, that is, the complex forming compounds can be used in membranes for the determination of the concentration of cations, like the ion sensitive members of measuring electrodes, or for the performance of an electro dialysis. Metal cations are generally insoluble in organic solvents and due to their solubility in organic solvents the new lipide soluble complexes of cations can be used in many fields of application, e.g. as catalysts for reactions which are performed in organic solvents.

Abstract translation: 通过使不带电荷的络合物形成物质与相应的离子反应来制备阳离子如金属离子和铵离子的新的脂溶性络合物。 优选的不带电荷的复合物形成物质也是新的。 阳离子的新型脂溶性络合物具有广泛的应用领域，并且这些络合物，即复合物形成化合物可用于膜中用于测定阳离子的浓度，例如测量电极的离子敏感元件，或用于 电透析的性能。 金属阳离子通常不溶于有机溶剂，并且由于它们在有机溶剂中的溶解度，阳离子的新的脂溶性可溶性络合物可用于许多应用领域，例如， 作为在有机溶剂中进行反应的催化剂。

公开(公告)号：US6126801A

公开(公告)日：2000-10-03

申请号：US121383

申请日：1998-07-23

Applicant: Tomasz Sokalski ,  Erno Pretsch

Inventor： Tomasz Sokalski ,  Erno Pretsch

IPC: G01N27/26 ,  G01N27/333

CPC classification number: G01N27/3335

Abstract: A new type of ion-selective solvent polymeric or liquid membrane electrode is constructed which allows to extend the measuring range at the lower end by at least six (6) orders of magnitudes. The new method can be used with membranes based on a neutral ionophore, a charged ionophore, or an ion-exchanger. Low detection limits are achieved by maintaining a very low and constant concentration of the primary ion and a sufficiently high concentration of an interfering ion in the internal reference solution. The low and constant concentration of the primary ion is either adjusted with the help of a solution of a hydrophilic ion buffer such as ethylenediamine tetraacetic acid or by adding an excess of a salt of an ion which forms a sparingly soluble salt with the primary ion, such as NaI for the primary ion Ag.sup.+. With the new technique, ion-selective electrodes can be used, for the first time, for environmental monitoring of heavy metal ions such as Pb.sup.2+ and Cd.sup.2+ at the submicromolar level.

Abstract translation: 构建了一种新型的离子选择性溶剂聚合物或液膜电极，其允许将下端的测量范围扩展至少六（6）个量级。 该新方法可用于基于中性离子载体，带电离子载体或离子交换剂的膜。 通过保持非常低和恒定浓度的一次离子和足够高浓度的干扰离子在内部参比溶液中来实现低检测限。 通过亲水离子缓冲液如乙二胺四乙酸的溶液或通过加入过量的与初级离子形成微溶盐的离子盐，调节初级离子的低和恒定浓度， 例如初级离子Ag +的NaI。 采用这种新技术，离子选择性电极首次可用于亚微米级重金属离子（如Pb2 +和Cd2 +）的环境监测。

公开(公告)号：US5037968A

公开(公告)日：1991-08-06

申请号：US166868

申请日：1988-03-11

Applicant: Wilhelm Simon ,  Erno Pretsch

Inventor： Wilhelm Simon ,  Erno Pretsch

IPC: G01N21/78 ,  C07C45/00 ,  C07C49/80 ,  C07C50/02 ,  C07C67/00 ,  C07C69/003 ,  C07C69/017 ,  C07C201/00 ,  C07C205/45 ,  C07C241/00 ,  C07C245/06 ,  C07C245/08 ,  C09B29/34 ,  C09K19/06 ,  G01N21/75 ,  G01N27/30 ,  G01N27/333 ,  G01N33/52 ,  G01N33/84

CPC classification number: G01N33/84 ,  C07C245/08 ,  C07C49/80 ,  C07C50/02 ,  C09K19/24 ,  G01N33/52

Abstract: Keto compounds in which to the carbon atom in the neighboring position to the keto compounds there is bonded at least one strongly electron attracting substituent and/or in which there is conjugating with the carbon-oxygen-double bond of the keto group a .pi.-electron system have the ability of interacting selectively with the anions of oxa acids yielding adducts, chelates or complexes.Provided that in the corresponding keto compounds the keto group is a part of a chromophore, then the shifting of the absorption in the visible range or the ultraviolet range of the wave lengths is observed, compared with the corresponding absorption of the free keto compound.The corresponding keto compounds are used for the determination of the anions of the oxa acids and they e.g. can be the ion sensitive component of a corresponding ions sensitive part for the determination of said anions. Several of said keto compounds can be also used as color indicator for the anions of the oxa acids.

Abstract translation: 与酮基化合物相邻位置的碳原子键合至少一个强电子吸引取代基和/或其中与酮基的碳 - 氧 - 双键共轭的酮基化合物是π电子 系统具有选择性地与产生加合物，螯合物或复合物的氧酸阴离子相互作用的能力。 假设在相应的酮基化合物中，酮基是发色团的一部分，则与相应的游离酮化合物的吸收相比，观察到在可见光范围内的吸收的移动或波长的紫外范围。 相应的酮化合物用于测定恶唑酸的阴离子。 可以是用于确定所述阴离子的相应离子敏感部分的离子敏感组分。 几种所述酮化合物也可以用作氧酸的阴离子的颜色指示剂。