公开(公告)号：US09149792B2

公开(公告)日：2015-10-06

申请号：US14122536

申请日：2012-05-21

Applicant: Tong Zhou ,  Gang Zhao ,  Fujiang Hong ,  Wenjun Mao ,  Qunyang Gao ,  Bingyi Li

Inventor： Tong Zhou ,  Gang Zhao ,  Fujiang Hong ,  Wenjun Mao ,  Qunyang Gao ,  Bingyi Li

IPC: B01J20/06 ,  B01J20/08 ,  B01J20/30 ,  B01D53/50 ,  B01J20/28 ,  B01J20/10 ,  C01G49/02 ,  B01J20/02 ,  B01J20/32

CPC classification number: B01J20/3078 ,  B01D53/508 ,  B01D2253/102 ,  B01D2253/1124 ,  B01D2253/304 ,  B01D2255/20738 ,  B01J20/0229 ,  B01J20/06 ,  B01J20/08 ,  B01J20/106 ,  B01J20/28004 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/32 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3236 ,  B01J20/324 ,  B01J20/3293 ,  C01G49/02

Abstract: The present invention provides a process for preparing ball-type desulfurizer with high sulfur capacity, comprising the following steps: placing initial balls in a rolling equipment; wetting the surface of the initial balls with an aqueous solution of an organic binder; then alternately adding non-crystalline iron oxide hydroxide and the aqueous solution of the organic binder to gradually form small balls of non-crystalline iron oxide hydroxide with high sulfur capacity and different diameters; and adjusting the shape of the small balls and then roasting or naturally drying the small balls. In the desulfurizer prepared by this method, the initial balls constitutes 0.98 wt %-9.03 wt % of the desulfurizer, the non-crystalline iron oxide hydroxide constitutes 90.29 wt %-98.62 wt % of the desulfurizer, and the organic binder constitutes 0.58 wt %-0.89 wt % of the desulfurizer. The present invention solves the problems that the desulfurizer with high sulfur capacity in the prior art has a high binder content and poor water resistance and diffusion performance, and provides a process for preparing a desulfurizer with high sulfur capacity, wherein a desulfurizer with high sulfur capacity and low binder content, good water resistance, good diffusion performance can be prepared.

Abstract translation: 本发明提供了一种制备具有高硫容量的球型脱硫剂的方法，包括以下步骤：将初始球放置在轧制设备中; 用有机粘合剂的水溶液润湿初始球的表面; 然后交替加入非晶态铁氧化物氢氧化物和有机粘合剂水溶液逐渐形成具有高硫容量和不同直径的非结晶铁氧化物氢氧化物的小球; 并调整小球的形状，然后焙烧或自然干燥小球。 在通过该方法制备的脱硫剂中，初始球构成脱硫剂的0.98重量％〜0.03重量％，非结晶性氧化铁氢氧化物构成脱硫剂的90.29重量％-98.62重量％，有机粘合剂占0.58重量％ -0.89重量％的脱硫剂。 本发明解决现有技术中具有高硫容量的脱硫剂具有高粘合剂含量和差的耐水性和扩散性能的问题，并且提供了具有高硫容量的脱硫剂的制备方法，其中具有高硫容量的脱硫剂 粘合剂含量低，耐水性好，扩散性能好。