Polyalkylene ethers as plasticizers and flow aids in
poly(1,4-cyclohexanedimethylene terephthalate) resins
    1.
    发明授权
    Polyalkylene ethers as plasticizers and flow aids in poly(1,4-cyclohexanedimethylene terephthalate) resins 失效
    聚亚烷基醚作为增塑剂和聚对苯二甲酸1,4-环己烷二亚甲基酯树脂中的流动助剂

    公开(公告)号:US5624987A

    公开(公告)日:1997-04-29

    申请号:US528971

    申请日:1995-09-15

    CPC classification number: C08L67/02

    Abstract: This invention relates to a polyester composition comprising a blend of:(A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250.degree. C., comprising:(a) one or more dicarboxylic acids, and(b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and(B) 0.5 to 25 weight % of one or more polyalkylene ethers,wherein the weight percentages of all components in said blend total 100 weight %.

    Abstract translation: 本发明涉及一种聚酯组合物,其包含以下混合物:(A)99.5至75重量%的特性粘度为0.1至1.2dL / g且熔点超过250℃的共聚酯,其包含:( a)一种或多种二羧酸,和(b)包含至少80摩尔%1,4-环己烷二甲醇的二元醇组分; 和(B)0.5至25重量%的一种或多种聚亚烷基醚,其中所述共混物中所有组分的重量百分比总计为100重量%。

    Process of making fused, oriented-grain polymeric materials
    2.
    发明授权
    Process of making fused, oriented-grain polymeric materials 失效
    制备融合的定向晶粒聚合材料的方法

    公开(公告)号:US4879081A

    公开(公告)日:1989-11-07

    申请号:US219629

    申请日:1988-07-15

    Applicant: Gerald T. Keep

    Inventor: Gerald T. Keep

    Abstract: A process for producing a thermoplastic material including the steps of molecularly orienting a thermoplastic material, grinding the oriented material to a particle size between about 0.01 to 10 mm and fusing the ground particulate material to substantially mutually adhere the particles thereby producing a sintered thermoplastic material. The fused product includes discrete fused particles of one or more anisotropically oriented thermoplastic polymers and exhibits isotropic increases in flexural modulus.

    Abstract translation: 一种制造热塑性材料的方法,包括以下步骤:将热塑性材料分子取向,将定向材料研磨至约0.01至约10mm的粒度,并将研磨的颗粒材料熔融成基本上相互粘附颗粒,从而制得烧结的热塑性材料。 熔融产物包括一种或多种各向异性取向的热塑性聚合物的分散的熔融颗粒,并且具有各向同性的弯曲模量增加。

    Reinforced polyesters, article thereof and method of making low warpage
articles
    3.
    发明授权
    Reinforced polyesters, article thereof and method of making low warpage articles 失效
    增强聚酯,其制品及低翘曲制品的制造方法

    公开(公告)号:US4874809A

    公开(公告)日:1989-10-17

    申请号:US148242

    申请日:1988-01-25

    Applicant: Gerald T. Keep

    Inventor: Gerald T. Keep

    CPC classification number: C08K3/34 C08L67/02 H05K1/0366 H05K1/0373

    Abstract: A glass fiber and mica-reinforced polyester composition useful in the production of shaped articles of low warpage is provided by blending(a) about 55% to about 99%, based on total polyester weight, of poly(ethylene terephthalate),(b) about 1% to about 45%, based on total polyester weight, of poly(cyclohexane-dimethylene terephthalate),(c) about 5% to about 50%, based on the total weight of the composition, of glass fibers, and(d) about 5% to about 50%, based on the total weight of the composition, of micathe total glass fiber and mica weight being less than 75% based on the total weight of the composition.

    Abstract translation: 通过混合(a)基于总聚酯重量计约55%至约99%的聚(对苯二甲酸乙二醇酯),(b),聚对苯二甲酸乙二醇酯, 基于总聚酯重量,约1%至约45%的聚(环己烷 - 二亚甲基对苯二甲酸酯),(c)约5%至约50%,基于组合物的总重量,玻璃纤维和(d )约5%至约50%,基于组合物的总重量,云母的总玻璃纤维和云母重量小于组合物总重量的75%。

    Non-volatile plasticizers and flow aids for polyesters

    公开(公告)号:USH1987H1

    公开(公告)日:2001-08-07

    申请号:US09296333

    申请日:1999-04-22

    Abstract: The use of a specified molecular weight range of poly(alkylene ether)s, such as poly(ethylene glycol) (PEG), poly(tetramethylene glycol) (PTMG), and poly(propylene glycol) (PPG), and end-capped poly(alkylene ether)s, as plasticizers for polyesters such as poly(ethylene terephthalate) (PET), poly(propylene terephthalate) (PPT), poly(butylene terephthalate) (PBT), poly(ethylene naphthalate) (PEN), and poly(1,4-cyclohexanedimethylene terephthalate) (PCT), that are non-volatile during drying processes as well as during melt processing. Such poly(alkylene ether)s and end-capped poly(alkylene ether)s decrease the melt viscosity of the polymer matrix and depress the glass transition temperature, and thereby improve the processability of polyesters.

    Process for preparing selectively metallized articles
    5.
    发明授权
    Process for preparing selectively metallized articles 失效
    制备选择性金属化物品的方法

    公开(公告)号:US4978569A

    公开(公告)日:1990-12-18

    申请号:US393427

    申请日:1989-08-14

    Applicant: Gerald T. Keep

    Inventor: Gerald T. Keep

    Abstract: Disclosed is a process for preparing a selectively metallized article, and to the article prepared by this process. The process comprises:1. swelling a polymeric article with dimethylformamide for a length of time of 1 to 5 minutes;2. treating the polymeric article with an aqueous solution of a strong base;3. alternately repeating steps 1 and 2 any number of times;4. etching said polymeric article;5. subjecting polymeric article to electroless copper plating, to obtain said selectively metallized article.

    Abstract translation: 公开了一种制备选择性金属化制品的方法,以及通过该方法制备的制品。 该方法包括:1.用二甲基甲酰胺溶胀聚合物制品1至5分钟的时间; 2.用强碱的水溶液处理聚合物制品; 3.交替重复步骤1和2任意次数; 4.蚀刻所述聚合物; 5.对聚合物进行化学镀铜,以获得所述选择性金属化的制品。

    Polymer blend for molded circuit boards and other selectively conductive
molded devices
    6.
    发明授权
    Polymer blend for molded circuit boards and other selectively conductive molded devices 失效
    用于模制电路板和其它选择性导电模制装置的聚合物共混物

    公开(公告)号:US4985293A

    公开(公告)日:1991-01-15

    申请号:US393426

    申请日:1989-08-14

    Applicant: Gerald T. Keep

    Inventor: Gerald T. Keep

    Abstract: The use of an amorphous polymer blended with a semicrystalline polymer to render the latter susceptible to adhesion promotion for good peel strength after electroless copper plating, while maintaining the advantages of the semicrystalline polymer including high temperature characteristics, ease of molding, and low cost is disclosed. The invention provides an injection-moldable material with the advantages of a semicrystalline thermoplastic but that can be made to accept electroless metal deposits for fabrication of electronic devices. The material is a blend including a high-temperature semicrystalline thermoplasstic polymer with an amorphous polymer that is easily etched and that is preferably compatible with the semicrystalline polymer. A preferred exemplary blend comprises poly(cyclohexylenedimethylene terephthalate) with polyethersulfone and/or polyarylate.

    Abstract translation: 公开了使用与半结晶聚合物共混的无定形聚合物,使得后者在化学镀铜后易于粘附促进以获得良好的剥离强度,同时保持包括高温特性,易于成型和低成本的半结晶聚合物的优点, 。 本发明提供了具有半结晶热塑性材料的优点的可注射成型材料,但是可以制成接受用于制造电子器件的无电金属沉积物。 该材料是包括具有易于蚀刻并且优选与半结晶聚合物相容的无定形聚合物的高温半结晶热塑性聚合物的共混物。 优选的示例性共混物包括与聚醚砜和/或多芳基化合物的聚(环己烯二甲基对苯二甲酸酯)。

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