公开(公告)号：US06906148B2

公开(公告)日：2005-06-14

申请号：US10297541

申请日：2001-05-30

Applicant: Michael Krebs ,  Christoph Lohr ,  Andreas Brenger ,  Ingolf Scheffler

Inventor： Michael Krebs ,  Christoph Lohr ,  Andreas Brenger ,  Ingolf Scheffler

IPC: C08G18/12 ,  C08G18/42 ,  C08G71/04

CPC classification number: C08G18/4277 ,  C08G18/12 ,  C08G2170/20 ,  C08G18/307

Abstract: The present invention relates to compositions comprising reaction products of a polyisocyanate with a polyester block copolymer and a process for the preparation thereof. These are suitable as a moisture-curing hot melt adhesive. The hot melt adhesive composition may optionally also comprise a reaction product of a polyisocyanate with a polyester polyol and/or a reaction product of a polyisocyanate with a polyether polyol. Such polyurethane hot melt adhesive compositions have good creep resistance and interfacial adhesion values on plastics and show very high strength values.

Abstract translation: 本发明涉及包含多异氰酸酯与聚酯嵌段共聚物的反应产物的组合物及其制备方法。 这些适合作为湿固化热熔胶。 热熔粘合剂组合物还可任选地包含多异氰酸酯与聚酯多元醇的反应产物和/或多异氰酸酯与聚醚多元醇的反应产物。 这种聚氨酯热熔粘合剂组合物在塑料上具有良好的抗蠕变性和界面粘合力，并显示非常高的强度值。

公开(公告)号：US5266145A

公开(公告)日：1993-11-30

申请号：US899223

申请日：1992-06-16

Applicant: Edward W. Duck ,  Ingolf Scheffler

Inventor： Edward W. Duck ,  Ingolf Scheffler

IPC: C08G18/12 ,  C08G18/40 ,  C08G18/63 ,  C09J175/04 ,  C09K3/10 ,  C09J167/02

CPC classification number: C09K3/1021 ,  C08G18/12 ,  C08G18/4063 ,  C08G18/4072 ,  C08G18/631 ,  C09J175/04 ,  C08G2190/00 ,  C09K2003/1056 ,  C09K2200/0625

Abstract: One-component, moisture-hardening sealants and adhesives contain telechelic isocyanate prepolymers obtainable by reacting diisocyanates and/or polyisocyanates in stoichiometric excess with polyester polyols, polyether polyols and hydroxy-functional (meth) acrylate prepolymers, as well as conventional plasticizers, the polyester polyols having branches, more particularly formed by alkyl radicals containing no functional groups. The polyester polyols can either be obtained by reacting corresponding branched diols and/or dicarboxylic acids or by subsequent grafting of side groups on to straight-chain polyester polyols. The sealants and adhesives are transparent or translucent, have a high ageing stability and excellent mechanical characteristics.

Abstract translation: 单组分，湿润固化的密封剂和粘合剂含有遥距异氰酸酯预聚物，可通过使化学计量过量的二异氰酸酯和/或多异氰酸酯与聚酯多元醇，聚醚多元醇和羟基官能（甲基）丙烯酸酯预聚物以及常规增塑剂，聚酯多元醇 具有分支，更特别地由不含官能团的烷基形成。 聚酯多元醇可以通过使相应的支链二醇和/或二羧酸反应或通过随后将侧基接枝在直链聚酯多元醇上来获得。 密封剂和粘合剂是透明或半透明的，具有高的老化稳定性和优异的机械特性。

公开(公告)号：US07297756B2

公开(公告)日：2007-11-20

申请号：US10312916

申请日：2001-06-21

Applicant: Bettina Becker ,  Ingolf Scheffler ,  Juergen Wichelhaus ,  Liane Meuten

Inventor： Bettina Becker ,  Ingolf Scheffler ,  Juergen Wichelhaus ,  Liane Meuten

IPC: C08G69/04 ,  C08G69/34 ,  C09J177/08 ,  E02D3/12 ,  C09K17/00

CPC classification number: C09J177/08 ,  C08G69/34

Abstract: Polyamide hot-melt adhesives based on the reaction products of polymeric fatty acids, C14-C18 monocarboxylic acids, C6-C12 dicarboxylic acids and diamines which do not contain any water-extractable, environmentally toxic constituents, which are suitable for sealing cavities in soils, in rock formations, building structures and/or walls, in particular for sealing tunnels, galleries, shafts, channels or caverns, to protect against the penetration of water or the penetration of liquids or gases which contain hazardous substances.

Abstract translation: 基于聚合脂肪酸，C 14-14 -C 18一元羧酸，C 6 -C 13的反应产物的聚酰胺热熔粘合剂 > 12个二羧酸和二胺，其不含任何可水提取的，环境有毒的组分，其适用于密封土壤，岩层，建筑结构和/或壁中的空腔，特别是用于密封隧道，画廊 ，轴，通道或洞穴，以防止水的渗透或含有有害物质的液体或气体的渗透。

公开(公告)号：US5919857A

公开(公告)日：1999-07-06

申请号：US835171

申请日：1997-04-07

Applicant: Klaus Ruch ,  Ingolf Scheffler

Inventor： Klaus Ruch ,  Ingolf Scheffler

IPC: B23K35/36 ,  C08K3/00 ,  C08K5/00 ,  C08L25/00 ,  C08L25/02 ,  C08L25/08 ,  C08L75/00 ,  C08L75/04 ,  C09D125/08 ,  C09J125/00 ,  C09J125/02 ,  C09J125/08 ,  C09J175/00 ,  C09J175/04 ,  C09K3/10 ,  H01L23/10 ,  H01L23/29 ,  H01L23/31

CPC classification number: C08K5/0016 ,  Y10S524/904

Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.

Abstract translation: 基于苯乙烯共聚物，增塑剂和无机填料的增塑溶胶组合物含有作为苯乙烯共聚物的共聚物，其可通过乳液聚合制备并含有a）苯乙烯和/或α-甲基苯乙烯和/或对甲基苯乙烯和b）3至 20重量％（相对于共聚物）甲基丙烯酸和/或丙烯酸和/或衣康酸。 为了增加耐磨性，可以加入其它交联剂或加强剂。 增塑溶胶适用于机动车辆结构，作为下层材料，作为罩衬的粘合剂，作为格栅保护的复合物或点焊膏，以及作为用于容器封闭的密封化合物的包装产品工业 接缝密封或锡罐的法兰接头粘合剂。

公开(公告)号：US20050032974A1

公开(公告)日：2005-02-10

申请号：US10870344

申请日：2004-06-17

Applicant: Michael Krebs ,  Uwe Franken ,  Katja Brosa ,  Ingolf Scheffler

Inventor： Michael Krebs ,  Uwe Franken ,  Katja Brosa ,  Ingolf Scheffler

IPC: C08G18/22 ,  C08G18/12 ,  C08G18/80 ,  C08K3/00 ,  C08L75/00

CPC classification number: C08G18/12 ,  C08G18/809 ,  C08G2170/20 ,  C08G2190/00 ,  C08G18/73

Abstract: Isocyanato-functional silanes prepared by reacting aliphatic or cycloaliphatic polyisocyanates of low volatility with organofunctional silanes containing NCO-reactive groups are useful as adhesion promoters in polyurethane adhesives and sealants.

Abstract translation: 通过使具有低挥发性的脂族或脂环族多异氰酸酯与含有NCO反应性基团的有机官能硅烷反应制备的异氰酸酯官能的硅烷可用作聚氨酯粘合剂和密封剂中的粘合促进剂。

公开(公告)号：US5102969A

公开(公告)日：1992-04-07

申请号：US378735

申请日：1989-07-12

Applicant: Ingolf Scheffler ,  Michael Hirthammer ,  Anton M. Schleicher ,  Jean-Willem Delbeck

Inventor： Ingolf Scheffler ,  Michael Hirthammer ,  Anton M. Schleicher ,  Jean-Willem Delbeck

IPC: B60J1/00 ,  B29C47/02 ,  B29C47/12 ,  C08G18/10 ,  C08G18/22 ,  C09J5/00 ,  C09J7/00 ,  C09J175/00 ,  C09J175/04 ,  C09K3/10 ,  F16J15/14

CPC classification number: C09J9/005 ,  B29C47/0014 ,  B29C47/003 ,  B29C47/026 ,  C08G18/10 ,  C08G18/22 ,  C08G2190/00

Abstract: In a method for the production of a sealing and adhesive strip, particularly for the direct glazing of motor vheicles, using a moisture-hardening single-component polyurethane composition based on telechelic isocyanate prepolymers of aromatic diisocyanates in stoichiometric excess and polyols a composition is employed comprising a) a catalyst for the moisture-hardening and b) a blocked activatable cross-linking agent, and a solvent or solvent mixture is continually injected into the inside of the strip during the extrusion of the strip which liberate the cross-linking agent.For the implementation of the method an extrusion nozzle for the sealing and adhesive strip is used which comprises an injection needle for the solvent opening into the nozzle, the exit opening of which points in the extrusion direction and is located in the region of the center axis of the extrusion die forming the strip.

Abstract translation: 在用于制造密封胶和粘合带的方法中，特别是对于电动机微细直接喷涂，使用基于化学计量过量的芳族二异氰酸酯的遥爪异氰酸酯预聚物和多元醇的湿润硬化单组分聚氨酯组合物，其包含 a）用于湿润硬化的催化剂和b）封闭的可活化交联剂，并且在释放交联剂的条带的挤出期间，将溶剂或溶剂混合物持续注入到带内。 为了实现该方法，使用用于密封和粘合带的挤出喷嘴，其包括用于溶剂打入喷嘴的注射针，其出口开口指向挤出方向并且位于中心轴线的区域 的挤出模头。

公开(公告)号：US07267878B2

公开(公告)日：2007-09-11

申请号：US10703341

申请日：2003-11-07

Applicant: Hartmut Primke ,  Gerald Petry ,  Ingolf Scheffler ,  Juergen Wichelhaus ,  Michael Krebs ,  Michael Rudolph ,  Andrew Nixon ,  Hans-Peter Kohlstadt

Inventor： Hartmut Primke ,  Gerald Petry ,  Ingolf Scheffler ,  Juergen Wichelhaus ,  Michael Krebs ,  Michael Rudolph ,  Andrew Nixon ,  Hans-Peter Kohlstadt

IPC: B32B27/00

CPC classification number: B29B9/10 ,  B29K2105/0097 ,  C08G18/12 ,  C08G18/4018 ,  C08G2170/20 ,  C08J3/12 ,  C08J2367/02 ,  C08L29/00 ,  C09J5/06 ,  C09J175/04 ,  C09J201/02 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/3158 ,  C08G18/307

Abstract: A moisture-curing hot-melt-adhesive composition in granulate, tablet or powder form can be produced by a.) fusing the reactive hot-melt-adhesive composition and heating the melt, subject to exclusion of moisture, b.) extruding this melt through one or more dies onto a cooled surface, subject to exclusion of moisture, c.) cooling the granulate, subject to exclusion of moisture, whereby the composition solidifies, d.) removing the cooled hot-melt-adhesive granulate, e.) filling the granulate into moisture-tight packages, subject to exclusion of moisture. These reactive hot-melt adhesives are pourable and free-flowing and therefore can be used with all conventional application machines for hot-melt adhesives.

Abstract translation: a）通过以下方法制备颗粒状，片状或粉末形式的湿固化热熔粘合剂组合物：a）将反应性热熔粘合剂组合物熔合并加热熔体，排除水分，b）将该熔体挤出 通过一个或多个模具到冷却的表面上，排除水分，c。）冷却颗粒，排除水分，由此组合物固化，d。）去除冷却的热熔胶粘剂颗粒，例如， 将颗粒填充到防潮包装中，排除潮湿。 这些反应性热熔粘合剂是可倾倒和自由流动的，因此可以与所有常规的热熔粘合剂应用机一起使用。

公开(公告)号：US06465104B1

公开(公告)日：2002-10-15

申请号：US09694172

申请日：2000-10-23

Applicant: Michael Krebs ,  Yingjie Li ,  Ingolf Scheffler

Inventor： Michael Krebs ,  Yingjie Li ,  Ingolf Scheffler

IPC: C09J17504

CPC classification number: C08G18/6254 ,  C08G18/12 ,  C08G18/4063 ,  C08G18/6229 ,  C08G2170/20 ,  Y10T428/31551 ,  C08G18/307

Abstract: Hotmelt polyurethane adhesive compositions which are solid at room temperature and capable of being cured by moisture are obtained by combining the reaction product of a polyisocyanate and a low molecular weight polymer derived from ethylenically unsaturated monomers and containing active hydrogen groups such as hydroxyl with an isocyanate-containing polyurethane prepolymer derived from one or more polyols. The low molecular weight polymer component may, for example, be obtained by free radical polymerization of mixtures of unsaturated monocarboxylic acids, alkyl esters of unsaturated monocarboxylic acids, and/or hydroxyalkyl esters of unsaturated monocarboxylic acids.

Abstract translation: 通过将多异氰酸酯和衍生自烯键式不饱和单体的低分子量聚合物的反应产物和含有活性氢基团如羟基的异氰酸酯 - 共聚物混合，得到在室温下固化并能够被水分固化的热熔聚氨酯粘合剂组合物， 衍生自一种或多种多元醇的含聚氨酯预聚物。 低分子量聚合物组分可以例如通过不饱和一元羧酸，不饱和一元羧酸的烷基酯和/或不饱和一元羧酸的羟烷基酯的混合物的自由基聚合获得。

公开(公告)号：US5668209A

公开(公告)日：1997-09-16

申请号：US601542

申请日：1996-02-14

Applicant: Klaus Ruch ,  Ingolf Scheffler

Inventor： Klaus Ruch ,  Ingolf Scheffler

IPC: C08K5/00 ,  C08L25/08

CPC classification number: C08K5/0016 ,  Y10S524/904

Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.

Abstract translation: 基于苯乙烯共聚物，增塑剂和无机填料的增塑溶胶组合物含有作为苯乙烯共聚物的共聚物，其可通过乳液聚合制备并含有a）苯乙烯和/或α-甲基苯乙烯和/或对甲基苯乙烯和b）3至 20重量％（相对于共聚物）甲基丙烯酸和/或丙烯酸和/或衣康酸。 为了增加耐磨性，可以加入其它交联剂或加强剂。 增塑溶胶适用于机动车辆结构，作为下层材料，作为罩衬的粘合剂，作为格栅保护的复合物或点焊膏，以及作为用于容器封闭的密封化合物的包装产品工业 接缝密封或锡罐的法兰接头粘合剂。

公开(公告)号：US5088576A

公开(公告)日：1992-02-18

申请号：US378896

申请日：1989-07-12

Applicant: Hans-Hermann Potthoff ,  Ingolf Scheffler ,  Klaus Ruch ,  Rainer Joesel

Inventor： Hans-Hermann Potthoff ,  Ingolf Scheffler ,  Klaus Ruch ,  Rainer Joesel

IPC: B32B7/02 ,  B32B5/18 ,  B32B27/00 ,  B60N2/00 ,  B60R13/08 ,  G10K11/16 ,  G10K11/168

CPC classification number: G10K11/168 ,  B32B5/18 ,  B60N2/00 ,  B60R13/08

Abstract: A mass and spring system for soundproofing, particularly in vehicles, comprises a bending-soft heavy plastic layer as the mass and a soft layer as the spring, which is applied to the sound radiating surface or wall and which is a gel of 10 to 50% by weight of an organic polymer or silicone polymer and 50 to 90% by weight of a plasticizer compatible therewith, which at room temperature has a modulus of elasticity E'.ltoreq.5.times.10.sup.5 Pa and an internal loss factor d.gtoreq.0.5.

Abstract translation: 用于隔音的质量和弹簧系统，特别是在车辆中，包括作为质量的弯曲软质重塑料层和作为弹簧的软层，其被施加到声辐射表面或壁，并且是10至50的凝胶 重量％的有机聚合物或硅氧烷聚合物和50至90％重量的与其相容的增塑剂，其在室温下具有弹性模量E'5×10 5 Pa和内部损耗因子d> / = 0.5。